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Angewandte 2: Silver Complexes of Dihalogen Molecules

Doppelschlag in der "Angewandten Chemie" Teil 2: In einer Ausgabe der Angewandten wurden gleich zwei Publikationen unserer Forschergruppe veröffentlicht!

Dr. Przemysław J. Malinowski, Dr. Daniel Himmel, Prof. Dr. Ingo Krossing

Abstract

The perfluorohexane-soluble and donor-free silver compound Ag(A) (A=Al(ORF)4; RF=C(CF3)3) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen–silver complexes Ag(Cl2)A, Ag(Br2)A, and Ag(I2)Aderived from the soluble silver compound Ag(A) (characterized by single-crystal/powder XRD, Raman spectra, and quantum-mechanical calculations).

DOI: 10.1002/anie.201603741

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