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Publikationen 1991-2008

2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000,
1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1977-1990

 

2008


[317] Ethylene Polymerization, On-Line Particle Growth Monitoring, and in Situ Nanocomposite Formation
Using Catalysts Supported on Arylsulfonic Acid-Modified Boehmites.
R. Xalter, F. Pelascini, R. Mülhaupt, Macromolecules (2008), 41(9), 3136-3143.

[316] Boehmite nanorod-reinforced-polyethylenes and ethylene/1-octene thermoplastic elastomer
nanocomposites prepared by in situ olefin polymerization and melt compounding.
T. S. Halbach, Y. Thomann, R. Mülhaupt, Journal of Polymer Science, Part A: Polymer Chemistry (2008), 46(8), 2755-2765.

Ultra-high molecular weight polyethylene (UHMWPE) reactor blends prepared by supported blends of single
site catalysts.
A. Kurek, R. Mülhaupt, PMSE Preprints (2008), 99 484-485.

[315] Vascularization and biocompatibility of scaffolds consisting of different calcium phosphate
compounds.
M. Ruecker, M. W. Laschke, D. Junker, C. Carvalho, F. Tavassol, R. Mülhaupt, N.C.Gellrich, M.D. Menger,
Journal of Biomedical Materials Research, Part A (2008), 86A(4), 1002-1011.

[314] Acrylic nanocomposite resins for use in stereolithography and structural light modulation based rapid
prototyping and rapid manufacturing technologies.
M. Gurr, D. Hofmann, M. Ehm, Y. Thomann, R. Kuebler, R. Mülhaupt Advanced Functional Materials (2008),
18(16), 2390-2397.

[313] Novel polyolefins containing crystallizable isotactic polystyrene side chains.
B. T. Gall, J. McCahillD. W. Stephan, R. Mülhaupt, Macromolecular Rapid Communications (2008),
29(18), 1549-1553.

PAT82 Catalyst system for olefin polymerization, process for producing it and a process for the
polymerization of .alpha.-olefins using the catalyst system.
M.O. Kristen, R. Mülhaupt, G. Scheuermann, A. Kurek, PCT Int. Appl. (2008), 31pp.

[312] Bacterial and Candida albicans adhesion on rapid prototyping-produced 3D-scaffolds manufactured as
bone replacement materials.
A. Al-Ahmad, M. Wiedmann-Al-Ahmad, C. Carvalho, M. Lang, M. Follo, G. Braun, A. Wittmer, A., R. Mülhaupt,
E. Hellwig, Journal of Biomedical Materials Research, Part A (2008), 87A(4), 933-943.

[311] Boehmite nanorod-reinforced-polyethylenes and ethylene/1-octene thermoplastic
elastomer nanocomposites prepared by in situ olefin polymerization and melt compounding.
Halbach, Tobias S.; Thomann, Yi; Muelhaupt, Rolf.   Journal of Polymer Science, Part A: Polymer
Chemistry  (2008),  46(8),  2755-2765.  C

[310] Incorporation of growth factor containing Matrigel promotes vascularization of porous
PLGA scaffolds.   
Laschke, M. W.; Ruecker, M.; Jensen, G.; Carvalho, C.; Muelhaupt, R.; Gellrich, N.-C.; Menger, M. D.  
Journal of Biomedical Materials Research, Part A  (2008),  85A(2),  397-407. 

[309] On-Line Particle Growth Monitoring, and in Situ Nanocomposite Formation Using
Catalysts Supported on Arylsulfonic Acid-Modified Boehmites.  
Xalter, Rainer; Pelascini, Frederic; Muelhaupt, Rolf.  Ethylene Polymerization,  Macromolecules
(Washington, DC, United States)  (2008),  41(9),  3136-3143

[308] Isotactic poly(propylene) nanocomposites based upon boehmite nanofillers. 
Streller, Rouven C.; Thomann, R.; Torno, O.; Muelhaupt, R..   Macromolecular Materials and
Engineering  (2008),  293(3),  218-227.

New nitrile- and amine-functionalized polyolefin nanoparticles via tandem catalysis in aqueous
miniemulsion. 
Beierlein, Christine; Schuessele, Andreas; Thomann, Ralf; Muelhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (2008),  49(1),  533-534. 

[307] Boehmite-based polyethylene nanocomposites prepared by in-situ polymerization.  
Halbach, Tobias S.; Muelhaupt, Rolf.   Polymer  (2008),  49(4),  867-876.

[306] Molecular Weight and End Group Control of Isotactic Polystyrene Using Olefins and
Nonconjugated Diolefins as Chain Transfer Agents. 
Gall, Barbara T.; Pelascini, Frederic; Ebeling, Henner; Beckerle, Klaus; Okuda, Jun; Muelhaupt, Rolf.  
Macromolecules (Washington, DC, United States)  (2008),  41(5),  1627-1633.

[305] Incorporation of growth factor containing Matrigel promotes vascularization of porous
PLGA scaffolds.   
Laschke M W; Rucker M; Jensen G; Carvalho C; Mulhaupt R; Gellrich N-C; Menger M D Journal of
biomedical materials research.  Part A  (2008),  85(2),  397-407.  Journal code: 101234237.

 

2007


[304] Comparative in vitro study of the cell proliferation of ovine and human osteoblast-like
cells on conventionally and rapid prototyping produced scaffolds tailored for application as
potential bone replacement material.   
Wagner, M.; Kiapur, N.; Wiedmann-Al-Ahmad, M.; Huebner, U.; Al-Ahmad, A.; Schoen, R.;
Schmelzeisen, R.; Muelhaupt, R.; Gellrich, N.-C.  Journal of Biomedical Materials Research, Part A 
(2007),  83A(4),  1154-1164.

PAT81
A process for producing polyolefin-polyvinylaromatic block copolymers. 
Steininger, Helmut; Knoll, Konrad; Muelhaupt, Rolf; Weiser, Marc-Stephan.   Eur. Pat. Appl.  (2007), 

Nanostructured morphology of polymer conetworks: Resolving the controversy between AFM
and TEM images for disordered nanophase separated multicomponent polymers.   
Thomann, Ralf; Ivan, Bela; Erd-di, Gabor; Domjan, Attila; Scherble, Jonas; Mulhaupt, Rolf.  Abstracts
of Papers, 234th ACS National Meeting, Boston, MA, United States, August 19-23, 2007  (2007),

Isotactic polystyrene with controlled molecular weight using olefins as chain transfer agents.
Gall, Barbara T.; Pelascini, Frederic; Ebeling, Henner; Okuda, Jun; Mulhaupt, Rolf.    Abstracts of
Papers, 234th ACS National Meeting, Boston, MA, United States, August 19-23, 2007  (2007), 

Preparation and properties of iPP/boehmite nanocomposites. 
Streller, Rouven C.; Mulhaupt, Rolf  Abstracts of Papers, 234th ACS National Meeting, Boston, MA,
United States, August 19-23, 2007  (2007),  

Synthesis of boehmite polyolefin nanocomposites by in-situ polymerization.
Halbach, Tobias S.; Muelhaupt, Rolf.     PMSE Preprints  (2007),  97  547-548.

Nanostructured morphology of polymer conetworks: resolving the controversy between AFM
and TEM images for disordered nanophase separated multicomponent polymers.   
Thomann, Ralf; Ivan, Bela; Erdodi, Gabor; Domjan, Attila; Scherble, Jonas; Mulhaupt, Rolf.  Polymer
Preprints (American Chemical Society, Division of Polymer Chemistry)  (2007),  48(2),  515-516.

Isotactic polystyrene with controlled molecular weight using olefins as chain transfer agents.   
Gall, Barbara; Pelascini, Frederic; Ebeling, Henner; Okuda, Jun; Muelhaupt, Rolf.  Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (2007),  48(2),  313-314.

[303] Arylphosphonic acid-functionalized polyelectrolytes as fuel cell membrane material.  
Bock, Thorsten; Moehwald, Helmut; Muelhaupt, Rolf.   Macromolecular Chemistry and Physics 
(2007),  208(13),  1324-1340.

Am Anfang der Makromolekularen Chemie – Eine Pionierleistrung Hermann Staudingers (1881
– 1965),
Mülhaupt, Rolf Festschrift "550 Jahre Albert-Ludwigs universiträt Freiburg", 2007

Selbstheilende Kunststoffe – Nanotechnologie von der Natur in die Technik,
Mülhaupt, Rolf; Speck, Olga. Kunststoff Trends 6:16 (2007)

[302] Stereospecific styrene enchainment at a titanium site within a helical ligand framework:
evidence for the formation of homochiral polystyrene. 
Beckerle, Klaus; Manivannan, Ramanujachary; Lian, Bing; Meppelder, Geert-Jan M.; Raabe, Gerhard;
Spaniol, Thomas P.; Ebeling, Henner; Pelascini, Frederic; Muelhaupt, Rolf; Okuda, Jun.   
Angewandte Chemie, International Edition  (2007),  46(25),  4790-4793.  CODEN: ACIEF5 
ISSN:1433-7851.

[301] Photo-oxidation and Stabilization of sPP and iPP/Boehmite-Disperal Nanocomposites. 
Chmela, Stefan; Fiedlerova, Agnesa; Borsig, Eberhard; Erler, Jens; Muelhaupt, Rolf.    Journal of
Macromolecular Science, Part A: Pure and Applied Chemistry  (2007),  44(9),  1027-1034.

[300] DSC Study of Syndiotactic Polypropylene/Organoclay Nanocomposite Fibers:
Crystallization and Melting Behavior.  
Borsig, Eberhard; Ujhelyiova, Anna; Mlynarcikova, Zita; Kaemfer, Dirk; Muelhaupt, Rolf; Marcincin,
Anton; Berek, Dusan.   International Journal of Polymeric Materials  (2007),  56(8),  771-788.

[299] Controlled synthesis and characterization of poly[ethylene-block-(L,L-lactide)]s by
combining catalytic ethylene oligomerization with "coordination-insertion" ring-opening
polymerization. 
Ring, Jochen O.; Thomann, Ralf; Muelhaupt, Rolf; Raquez, Jean-Marie; Degee, Philippe; Dubois,
Philippe.    Macromolecular Chemistry and Physics  (2007),  208(8),  896-902.

Metallocene catalyzed olefin polymerization in presence of diethyl zinc: molecular weight
control and polyolefin functionalization.  
Ring, Jochen O.; Muelhaupt, Rolf.   Polymer Preprints (American Chemical Society, Division of
Polymer Chemistry)  (2007),  48(1),  961-962.

[298] PMMA nanocomposites and gradient materials prepared by means of polysilsesquioxane
(POSS) self-assembly.
Weickmann, Hans; Delto, Ralf; Thomann, Ralf; Brenn, Ruediger; Doell, Walter; Muelhaupt, Rolf.    
Journal of Materials Science  (2007),  42(1),  87-92.

[297] Comparative in vitro study of the cell proliferation of ovine and human osteoblast-like
cells on conventionally and rapid prototyping produced scaffolds tailored for application as
potential bone replacement material.  
Wagner M; Kiapur N; Wiedmann-Al-Ahmad M; Hubner U; Al-Ahmad A; Schon R; Schmelzeisen R;
Mulhaupt R; Gellrich N-C  Journal of biomedical materials research. Part A  (2007),  83(4),  1154-64.

[296] A dyadic sensitizer for dye solar cells with high energy-transfer efficiency in the device. 
Siegers Conrad; Hohl-Ebinger Jochen; Zimmermann Boris; Wurfel Uli; Mulhaupt Rolf; Hinsch Andreas;
Haag Rainer    Chemphyschem : a European journal of chemical physics and physical chemistry 
(2007),  8(10),  1548-56.

[295] Stereospecific styrene enchainment at a titanium site within a helical ligand framework:
evidence for the formation of homochiral polystyrene.
Beckerle Klaus; Manivannan Ramanujachary; Lian Bing; Meppelder Geert-Jan M; Raabe Gerhard;
Spaniol Thomas P; Ebeling Henner; Pelascini Frederic; Mulhaupt Rolf; Okuda Jun      Angewandte
Chemie (International ed. in English)  (2007),  46(25),  4790-3.

 

2006


Halogen-free polyarylphosphonates and polyelectrolyte membranes for PEMFC by nickel-
catalyzed phosphonylation with silylated phosphates.  Bock, Thorsten; Muelhaupt, Rolf;
Moehwald, Helmut.    Macromolecular Rapid Communications  (2006),  27(24),  2065-2071. 

Nanostructured poly(dimethylsiloxane)-based amphiphilic polymer conetworks.  Szabo L,
Sandor; Ivan, Bela; Scherble, Jonas; Thomann, Ralf; Mulhaupt, Rolf.    Abstracts of Papers, 232nd
ACS National Meeting, San Francisco, CA, United States, Sept. 10-14, 2006  (2006),    

Nanostructured poly(dimethylsiloxane)-based amphiphilic polymer co-networks.  Sandro,
Szabo L.; Ivan, Bela; Scherble, Jonas; Mulhaupt, Rolf; Thomann, Ralf.    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (2006),  47(2),  1154-1155

[294] Formation of polyolefin-block-polystyrene block copolymers on phenoxyimine catalysts.   
Weiser, Marc-Stephan; Muelhaupt, Rolf.  Macromolecular Rapid Communications  (2006),  27(13), 
1009-1014. 

[293] Angiogenic and inflammatory response to biodegradable scaffolds in dorsal skinfold
chambers of mice.  
Ruecker, Martin; Laschke, Matthias W.; Junker, Dominik; Carvalho, Carlos; Schramm, Alexander;
Muelhaupt, Rolf; Gellrich, Nils-Claudius; Menger, Michael D. Biomaterials  (2006),  27(29),  5027-
5038.

[292] Living random and block copolymerization of ethene and propene on a tailor-made
phenoxyimine catalyst and characterization of the resulting high molecular weight PE-block-
P(E-co-P) block copolymers.
Weiser, Marc-Stephan; Thomann, Yi; Heinz, Lars-Christian; Pasch, Harald; Muelhaupt, Rolf.   Polymer 
(2006),  47(13),  4505-4512. 

[291] The synthesis and X-ray structure of a phenoxyimine catalyst tailored for living olefin
polymerization and the synthesis of ultra-high molecular weight polyethylene and atactic
polypropylene. 
Weiser, Marc-Stephan; Wesolek, Marcel; Muelhaupt, Rolf.    Journal of Organometallic Chemistry 
(2006),  691(13),  2945-2952.

[290] Correlation of the acid-sensitivity of polyethylene glycol daunorubicin conjugates with
their in vitro antiproliferative activity.
Rodrigues, Paula C. A.; Roth, Thomas; Fiebig, Heinz H.; Unger, Clemens; Muelhaupt, Rolf; Kratz,
Felix.     Bioorganic & Medicinal Chemistry  (2006),  14(12),  4110-4117.


Ethylene/1,3-cyclohexadiene copolymerization by means of methylaluminoxane activated half-
sandwich complexes.  Heiser, Dirk E.; Pelascini, Frederic; Kramer, Dominic; Scott, Jennifer;
Gambarotta, Sandro; McCahill, Jennifer; Stephan, Douglas W.; Okuda, Jun; Muelhaupt, Rolf.   
Macromolecular Symposia  (2006),  236(Olefin Polymerization),  156-160.

New polyolefin nanocomposites and catalyst supports based on organophilic boehmites.   
Xalter, Rainer; Halbach, Tobias S.; Muelhaupt, Rolf.  Macromolecular Symposia  (2006),  236(Olefin
Polymerization),  145-150.


Living olefin polymerisation and block copolymer synthesis in the presence of a single-site
catalyst containing a phenoxyimine ligand.  Weiser, Marc-Stephan; Muelhaupt, Rolf.   
Macromolecular Symposia  (2006),  236(Olefin Polymerization),  111-116. 

Syndiospecific polymerization catalysts for styrene based on rare earth metal half-sandwich
complexes.  Hitzbleck, Julia; Beckerle, Klaus; Okuda, Jun; Halbach, Tobias; Muelhaupt, Rolf.   
Macromolecular Symposia  (2006),  236(Olefin Polymerization),  23-29. 

[289] Copolymerization of ethylene with styrene catalyzed by a linked bis(phenolato) titanium
catalyst.    Capacchione, Carmine; Proto, Antonio; Ebeling, Henner; Mulhaupt, Rolf; Okuda, Jun. 
Journal of Polymer Science, Part A: Polymer Chemistry  (2006),  44(6),  1908-1913.

Aluminoboronates supported on dispersible alumosilicates as activators for bis(imino)pyridine
iron catalysts.  Xalter, Rainer; Mulhaupt, Rolf.    Abstracts of Papers, 231st ACS National Meeting,
Atlanta, GA, United States, March 26-30, 2006  (2006), 

Nanostructured polymer conetworks and nanotemplating thereby.   
Ivan, Bela; Erd-di, Gabor; Mezey, Peter; Scherble, Jonas; Thomann, Ralf; Mulhaupt, Rolf.  Abstracts
of Papers, 231st ACS National Meeting, Atlanta, GA, United States, March 26-30, 2006  (2006),  

Sulfonic acid-modified boehmites as supports for metallocene-based ethylene polymerization
catalysts.   Xalter, Rainer; Muelhaupt, Rolf.   PMSE Preprints  (2006),  94  477-478.

[288] High-Temperature Liquid Chromatography at Critical Conditions: Separation of
Polystyrene from Blends with Polyethylene and Ethylene-Styrene Block Copolymers.  
Heinz, Lars-Christian; Macko, Tibor; Pasch, Harald; Weiser, Marc-Stephan; Muelhaupt, Rolf. 
International Journal of Polymer Analysis and Characterization  (2006),  11(1),  47-55.


PAT80
Laser curable polymerizable dental compositions.  Klee, Joachim; Facher, Andreas; Weber,
Christoph; Muelhaupt, Rolf; Schmider, Martin.   PCT Int. Appl.  (2006),     24 pp.

Hermann Staudinger Award 2006 
Mulhaupt Rolf    Macromolecular bioscience  (2006),  6(2),  187-8.  Journal code: 101135941. 
ISSN:1616-5187.

 

2005

 

Improving thermal endurance properties of polypropylene by nanostructuration.   Motori, A.; Patuelli,
F.; Saccani, A.; Montanari, G. C.; Mulhaupt, R..   Annual Report - Conference on Electrical Insulation
and Dielectric Phenomena  (2005),     195-198

Improving thermal endurance properties of polypropylene by nanostructuration.   Motori, A.; Patuelli,
F.; Saccani, A.; Montanari, G. C.; Mulhaupt, R..  Annual Report - Conference on Electrical Insulation
and Dielectric Phenomena  (2005),     195-198

PAT79
Dental sealant composition for the protection of hard tissue.    Klee, Joachim E.; Facher, Andreas;
Weber, Christoph; Muelhaupt, Rolf; Schmider, Martin.  PCT Int. Appl.  (2005),     22 pp.
 

PAT78
Laser curable polymerizable composition for the protection of hard tissue.   
Klee, Joachim E.; Facher, Andreas; Weber, Christoph; Muelhaupt, Rolf; Schmider, Martin. PCT Int.
Appl.  (2005),     21 pp. 

[287] Versatile synthetic route to phosphonate-functional monomers, oligomers, silanes, and
hybrid nanoparticles
M. Schmider, E. Müh, J.E. Klee, R. Mülhaupt, Macromolecules 2005, 38(23):9548-9555

[286] Metallized organoclays as new intermediates for aqueous nanohybrid dispersions,
nanohybrid catalysts and antimicrobial polymer hybrid nanocomposites
H. Weickmann, J.C. Tiller, R. Thomann, R. Mülhaupt, Macromol Mater. Eng. 2005, 290 (9): 875-883

New resins and nanosystems for high-performance adhesives
R. Mülhaupt in W. Possart (ed.) Adhesion – Current Research and Application, Wiley-VCH, Weinheim
2005, 189-203

Hermann Staudinger – im Spannungsfeld von Politik undTechnik
R. Mülhaupt, Freiburger Universitätsblätter 2005, Heft 167 (1. Heft), 63-76

Fabrication of soft and hard biocompatible scaffolds using 3D BioplottingTM 
C. Carvalho, R. Landers, R. Mülhaupt, U. Hübner, R. Schmelzeisen in P.J. Bàrtolo (ed.), Virtual
Modelling and Rapid Manufacturing – Afvanced Research in Virtual and Rapid Prototyping, Taylor &
Francis Group 2005, 97-102

Polymere Werk- und Effektstoffe im Nanokosmos
R. Mülhaupt, Proceedings, Fachtagung „Nanotechnologie in der Kunststofftechnik", Süddeutsches
Kunststoffzentrum, Würzburg 2005, N1-N17

New nanophase separated intelligent amphiphilic conetworks and gels
Macromol. Symp. 2005, 227:265-273

[285] Cobalt (II) octanoate and cobalt (II) perfluoroctanoate catalyzed atom transfer
polymerization of styrene in toluene and fluorous media – A verdsatile route to catalyst
recycling and oligomer formation
Weiser. M.S., Mülhaupt, R., J. Polym. Sci. Part A – Polym. Chem. 2005, 43(17): 3804-3813

[284] Photo-oxidation of sPP/organoclay nanocomposites
Chmela, S., Kleinova, A., Fiedlerova, A., Borsig, E., Kaempfer, D., Thomann, R., Mülhaupt, R., J.
Macromol. Sci. – Pure and Applied Chem. 2005, A42(7): 821-829

[283] Syndiotactic poly(propylene)/organoclay nanocomposite fibers: influence of the nano-
filler and the compatibilizer on the fiber properties,
Z. Mlynarcikova, D. Kaempfer, R. Thomann, R. Mülhaupt, E. Bprsig, A. Marcincin, Polym. Adv.
Techn. 2005, 16:362-369
 
[282] Polymer ionomers for rapuid prototyping and rapid manufacturing by means of 3D
printing
Pfister, A., Waltz, U., Laib, A., Macromol. Mater. Eng. 2005, 290(3):99-113

[281] Nanophase separated amphiphilic conetwork coatings and membranes
Bruns, N., Scherble ., Hartmann, L., Thomann, R., Ivan, B.,  Mülhaupt R., Tiller, J.C., Macromolecules
2005, 38:2431-2438

Armoured latex approach to thermoplastic nanocomposites and nanocompomers
Weickmann, H., Thomann, R.; Mulhaupt, R., Polymeric Materials: Science and Engineering  (2005), 
92  461-462. 

[280] Nanophase Separated Amphiphilic Conetwork Coatings and Membranes
Bruns, N.; Scherble, J.; Hartmann, L.; Thomann, R., Ivan, B., Muelhaupt, R., Tiller, J. C.   
Macromolecules  (2005),  38(6),  2431-2438.

[279] A novel polyamide 12 polymerization system and its use for a LCM-process to produce
CFRP.     Rosso, Patrick; Friedrich, Klaus; Wollny, Andreas; Muelhaupt, Rolf.    Journal of
Thermoplastic Composite Materials  (2005),  18(1),  77-90. 

[278] Catalytic 1,3-Cyclohexadiene homopolymerization and regioselective copolymerization
with ethylene.     Heiser, Dirk E.; Okuda, Jun; Gambarotta, Sandro; Muelhaupt, Rolf.   
Macromolecular Chemistry and Physics  (2005),  206(2),  195-202. 

[277] rac-Me2Si(2-Me-4-t-Bu-C5H2)2ZrMe+: An Alkyl Zirconocenium Cation Stabilized by Steric
Shielding against Interaction with Ancillary Ligands.     Schroeder, Lars; Brintzinger, Hans-
Herbert; Babushkin, Dmitrii E.; Fischer, David; Muelhaupt, Rolf.    Organometallics  (2005),  24(5), 
867-871

[276] PMMA gradient materials and in situ nanocoating via self-assembly of semifluorinated
hyperbranched amphiphiles.     Thomann, Yi; Haag, Rainer; Brenn, Ruediger; Delto, Ralf;
Weickman, Hans; Thomann, Ralf; Muelhaupt, Rolf, Macromolecular Chemistry and Physics  (2005), 
206(1),  135-141.

 

2004


Soft and hard implant fabrication using 3D-Bioplotting.     Carvalho, C.; Landers, R.; Muelhaupt,
R..    Solid Freeform Fabrication Symposium Proceedings  (2004),     732-741.

[275] Stereospecific post-metallocene polymerization catalysts: the example of isospecific
styrene polymerization.     Beckerle, Klaus; Capacchione, Carmine; Ebeling, Henner; Manivannan,
R.; Muelhaupt, Rolf; Proto, Antonio; Spaniol, Thomas P.; Okuda, Jun.    Journal of Organometallic
Chemistry  (2004),  689(24),  4636-4641. 

[274] Polymer nanocomposites as dielectrics and electrical insulation-perspectives for
processing technologies, material characterization and future applications.    
Tanaka, T.; Montanari, G. C.; Muelhaupt, R..    IEEE Transactions on Dielectrics and Electrical
Insulation  (2004),  11(5),  763-784. 

[273] Modification of electrical properties and performance of EVA and PP insulation through
nanostructure by organophilic silicates.    
Montanari, Gian Carlo; Fabiani, Davide; Palmieri, Fabrizio; Kaempfer, Dirk; Thomann, Ralf;
Muelhaupt, Rolf.    IEEE Transactions on Dielectrics and Electrical Insulation  (2004),  11(5),  754-762. 

Nanomaterials: Opportunities and risks. Market and trends.    
Muelhaupt, Rolf.    Kunststoffe  (2004),  94(8),  76-80,82-85,87-88.

PAT77
Dendritic polymer films as protein-rejecting coatings.    
Haag, Rainer; Siegers, Conrad; Muelhaupt, Rolf.  (Albert-Ludwigs-Universitaet Freiburg, Germany).   
Ger. Offen.  (2004),     7 pp. DE  10311163  A1  20040923  Application: DE  2003-10311163 
20030312.  CAN 141:279158   

PAT76
Impact modified thermoplastic polyamide molding compositions.    
Warth, Holger; Vathauer, Marc; Mulhaupt, Rolf; Friedrich, Christian; Meincke, Olaf.  (Germany).    U.S.
Pat. Appl. Publ.  (2004),     8 pp.  CODEN: USXXCO  US  2004181005  A1  20040916  Patent  written
in English.    Application: US  2004-796525  20040309.  Priority: DE  2003-10310693  20030312. 
CAN 141:261516   

Synthesis of new cycloolefin copolymers based upon 1,3-cyclohexadiene.    
Heiser, D.; Muelhaupt, R..    Polymeric Materials: Science and Engineering  (2004),  91  554-555. 

Cobalt(II) perfluorooctanoate mediated atom transfer on radical polymerization and fluorous
biphase catalysis.    
Weiser, Marc-Stephan; Muelhaupt, Rolf.    Polymeric Materials: Science and Engineering  (2004),  91 
761-762.  CODEN: PMSEDG  ISSN: 0743-0515.  Journal; Computer Optical Disk  written in English.   
CAN 141:

Cobalt(II) perfluorooctanoate mediated atom transfer radical polymerisation and fluorous
biphase catalysis.    
Weiser, Marc Stephan; Mulhaupt, Rolf.    Abstracts of Papers, 228th ACS National Meeting,
Philadelphia, PA, United States, August 22-26, 2004  (2004),     PMSE-412.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 69FTZ8  Conference;

Synthesis of new cycloolefin copolymers based upon 1,3-cyclohexadiene.    
Heiser, Dirk; Mulhaupt, Rolf.    I Abstracts of Papers, 228th ACS National Meeting, Philadelphia, PA,
United States, August 22-26, 2004  (2004),     PMSE-302.  Publisher: American Chemical Society, 
Washington,

New amphiphilic conetworks from methacrylate-telechelic polydimethylsiloxane
bismacromonomers.    
Szabo L, Sandor; Ivan, Bela; Scherble, Jonas; Mulhaupt, Rolf.    Abstracts of Papers, 228th ACS
National Meeting, Philadelphia, PA, United States, August 22-26, 2004  (2004),     PMSE-268. 
Publisher: American Chemical Society,  Washington, D. C  CODEN: 69FTZ8 

On-line monitoring and fingerprint technology: New tools for the development of new catalysts
and polyolefin materials.    
Tuchbreiter, Arno; Marquardt, Juergen; Kappler, Bernd; Honerkamp, Josef; Muelhaupt, Rolf.      
Macromolecular Symposia  (2004),  213(Stereospecific Polymerization and Stereoregular Polymers), 
327-333. 

[272] High-performance epoxy hybrid nanocomposites containing organophilic layered
silicates and compatibilized liquid rubber.    
Froehlich, J.; Thomann, R.; Gryshchuk, O.; Karger-Kocsis, J.; Muelhaupt, R..    Journal of Applied
Polymer Science  (2004),  92(5),  3088-3096. 

PAT75
Silane coupling agent, process for the preparation of a silane coupling agent, use of said silane
coupling agent in a composite or on a substrate, nanoparticles and use thereof in a coating.    
Loontjens, Jacobus Antonius; Plum, Bartholomeus Johannes Margretha; Mulhaupt, Rolf; Maier,
Steffen.  (DSM IP Assets B.V., Neth.).    PCT Int. Appl.  (2004),     15 pp.  WO  2004046156  A1 
20040603  Application: WO  2003-NL787  20031110.  Priority: EP  2002-79918  20021120.  CAN
141:24533   

[271] Herman Staudinger and the origin of macromolecular chemistry.    
Muelhaupt, Rolf.    Angewandte Chemie, International Edition  (2004),  43(9),  1054-1063. 

[270] Non-metallocene catalysts for the styrene polymerization: isospecific group 4 metal
bis(phenolate) catalysts.    
Capacchione, Carmine; Proto, Antonio; Ebeling, Henner; Mulhaupt, Rolf; Moller, Klaus; Manivannan,
R.; Spaniol, Thomas P.; Okuda, Jun.    Journal of Molecular Catalysis A: Chemical  (2004),  213(1), 
137-140. 

PAT74
Preparing biocompatible polyurea, and use.    
Loontjens, Jacobus Antonius; Maier, Steffen; Muelhaupt, Rolf; Zimmermann, Joerg.  (DSM IP Assets
B.V., Neth.).    Eur. Pat. Appl.  (2004),     13 pp.  EP  1394191  A1  20040303  DApplication: EP  2002-
78540  20020828.  CAN 140:218270   

[269] Reactive core/shell type hyperbranched block copolyethers as new liquid rubbers for
epoxy toughening.    
Froehlich, Joerg; Kautz, Holger; Thomann, Ralf; Frey, Holger; Muelhaupt, Rolf.    Polymer  (2004), 
45(7),  2155-2164.

[268] The formation of poly(ester-urea) networks in the absence of isocyanate monomers.    
Zimmermann, Jorg; Loontjens, Ton; Scholtens, B. J. R.; Mulhaupt, Rolf.    Biomaterials  (2004), 
25(14),  2713-2719. 

[267] Synthesis and characterisation of anhydride-cured epoxy nanocomposites containing
layered silicates modified with phenolic alkylimidazolineamide cations.    
Froehlich, Joerg; Golombowski, Dietmar; Thomann, Ralf; Muelhaupt, Rolf.   Macromolecular Materials
and Engineering  (2004),  289(1),  13-19. 

[266] Biofunctional rapid prototyping for tissue-engineering applications: 3D bioplotting versus
3D printing.   
 Pfister, Andreas; Landers, Ruediger; Laib, Andres; Huebner, Ute; Schmelzeisen, Rainer; Muelhaupt,
Rolf.    Journal of Polymer Science, Part A: Polymer Chemistry  (2004),  42(3),  624-638. 

[265] Synthesis of reactive hyperbranched and star-like polyethers and their use for
toughening of vinylester-urethane hybrid resins.    
Karger-Kocsis, J.; Frohlich, J.; Gryshchuk, O.; Kautz, H.; Frey, H.; Mulhaupt, R..      Polymer  (2004), 
45(4),  1185-1195. 

 

2003


Electrical properties of polymer nanocomposites based upon organophilic layered silicates.    
Zilg, C.; Kaempfer, D.; Thomann, R.; Muelhaupt, R.; Montanari, G. C.    Annual Report - Conference
on Electrical Insulation and Dielectric Phenomena  (2003),     546-550.  C

[264] Poly(Methyl methacrylate)/Palladium Nanocomposites: Synthesis and Characterization of
the Morphological, Thermomechanical, and Thermal Properties.    
Aymonier, Cyril; Bortzmeyer, Denis; Thomann, Ralf; Muelhaupt, Rolf.    Chemistry of Materials  (2003), 
15(25),  4874-4878. 

[263] Carbonylbiscaprolactam: A versatile reagent for organic synthesis and isocyanate-free
urethane chemistry.    
Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Muelhaupt, Rolf.    Angewandte Chemie,
International Edition  (2003),  42(41),  5094-5097. 

[262] Real-time monitoring of ethene/1-hexene copolymerizations: determination of catalyst
activity, copolymer composition and copolymerization parameters.    
Kappler, Bernd; Tuchbreiter, Arno; Faller, Daniel; Liebetraut, Peter; Horbelt, Werner; Timmer, Jens;
Honerkamp, Josef; Mulhaupt, Rolf.    Polymer  (2003),  44(20),  6179-6186. 

[261] In situ formation and compounding of polyamide 12 by reactive extrusion.    
Wollny, A.; Nitz, H.; Faulhammer, H.; Hoogen, N.; Muelhaupt, R..    Journal of Applied Polymer
Science  (2003),  90(2),  344-351. 

Rubber nanocomposites: Morphology and mechanical properties of BR and SBR vulcanizates
reinforced by organophilic layered silicates.     Gummi, Fasern, Kunststoffe  (2003),  56(7),  444-
454. 

[260] Interpenetrating vinylester/epoxy resins modified with organophilic layered silicates.    
Karger-Kocsis, J.; Gryshchuk, O.; Frohlich, J.; Mulhaupt, R..    Composites Science and Technology 
(2003),  63(14),  2045-2054.

[259] Toughened epoxy hybrid nanocomposites containing both an organophilic layered
silicate filler and a compatibilized liquid rubber.    
Froehlich, Joerg; Thomann, Ralf; Muelhaupt, Rolf.    Macromolecules  (2003),  36(19),  7205-7211.

[258] Transport properties of organic vapors in nanocomposites of isotactic polypropylene.    
Gorrasi, Giuliana; Tammaro, Loredana; Tortora, Mariarosaria; Vittoria, Vittoria; Kaempfer, Dirk;
Reichert, Peter; Muelhaupt, Rolf.    Journal of Polymer Science, Part B: Polymer Physics  (2003), 
41(15),  1798-1805. 

[257] Anionic ring-opening polymerization of propylene oxide in the presence of phosphonium
catalysts at various temperatures.    
Rexin, Ornulf; Muelhaupt, Rolf.     Macromolecular Chemistry and Physics  (2003),  204(8),  1102-
1109. 

PAT73
Hyper-branched polymers as selective solvents for the separation of azeotropic mixtures or
mixtures having very similar boiling points.   
Arlt, Wolfgang; Seiler, Matthias; Sadowski, Gabriele; Frey, Holger; Kautz, Holger; Muelhaupt, Rolf. 
(Germany).    Ger. Offen.  (2003),     10 pp.  DE  10160518  A1  20030626  Patent  written in German.   
Application: DE  2001-10160518  20011204.  CAN 139:70957   

[256] Transport properties of organic vapors in nanocomposites of organophilic layered
silicate and syndiotactic polypropylene.     Gorrasi, Giuliana; Tortora, Mariarosaria; Vittoria, Vittoria;
Kaempfer, Dirk; Mulhaupt, Rolf.   Polymer  (2003),  44(13),  3679-3685. 

[255] Fiber spinning from poly(propylene)-organoclay nanocomposite.     Pavlikova, Silvia;
Thomann, Ralf; Reichert, Peter; Mulhaupt, Rolf; Marcincin, Anton; Borsig, Eberhard.   Journal of
Applied Polymer Science  (2003),  89(3),  604-611.  CODEN: JAPNAB  ISSN: 0021-8995. 

[254] Rheological evidence of modifications of polypropylene by gamma-irradiation.    
Schulze, Dirk; Trinkle, Stefan; Muelhaupt, Rolf; Friedrich, Christian.   Rheologica Acta  (2003),  42(3), 
251-258. 

[253] Linear and Nonlinear Rheological Properties of Self-Assembling Tectons in
Polypropylene Matrices.    
Fahrlaender, Michael; Fuchs, Konrad; Muelhaupt, Rolf; Friedrich, Christian.    I Macromolecules 
(2003),  36(10),  3749-3757. 

[252] Ancillary Ligand Effect on Single-Site Styrene Polymerization: Isospecificity of Group 4
Metal Bis(phenolate) Catalysts.    
Capacchione, Carmine; Proto, Antonio; Ebeling, Henner; Muelhaupt, Rolf; Moeller, Klaus; Spaniol,
Thomas P.; Okuda, Jun.    Journal of the American Chemical Society  (2003),  125(17),  4964-4965.  C

Catalytic polymerization and post polymerization catalysis fifty years after the discovery of
Ziegler's catalysts.   
 Mulhaupt, Rolf.    Macromolecular Chemistry and Physics  (2003),  204(2),  289-327.  CODEN:

The 60th anniversary of the first polymer journal ("Die Makromolekulare Chemie"): Moving to
new horizons.   
 Mulhaupt, Rolf; Meisel, Ingrid.    Macromolecular Chemistry and Physics  (2003),  204(2),  199-206. 
CODEN: MCHPES  ISSN: 1022-1352. 

[251] Synthesis and in vitro efficacy of acid-sensitive poly(ethylene glycol) paclitaxel
conjugates.     Rodrigues, Paula C. A.; Scheuermann, Karin; Stockmar, Cornelia; Maier, Gerhard;
Fiebig, Heinz H.; Unger, Clemens; Muelhaupt, Rolf; Kratz, Felix.    Bioorganic & Medicinal Chemistry
Letters  (2003),  13(3),  355-360. 

[250] Near infrared reflection spectroscopy: A versatile tool for rapid characterization of olefin
copolymers and high-throughput experiments.    
Tuchbreiter, Arno; Kappler, Bernd; Stockmann, Roger; Mulhaupt, Rolf; Honerkamp, Josef.   
Macromolecular Materials and Engineering  (2003),  288(1),  29-34.

Carbonylbiscaprolactam: a versatile reagent for the synthesis of reactive oligomers.    
Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Mulhaupt, Rolf.    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (2003),  44(1),  115-116. 

PAT72
Reactive system for the 3D printing.     Pfister, Andreas; Muelhaupt, Rolf; Landers, Ruediger; Walz,
Uwe.  (Germany).    Ger. Offen.  (2003),     16 pp.  DE  10158233  A1  20030313      Application: DE 
2001-10158233  20011123.  Priority: DE  2001-10140380  20010823.  CAN 138:223101 

[249] Mechanical properties of epoxy-based hybrid composites containing glass beads and
alpha,omega-oligo(butylmethacrylate)diol.    
Schroder, N.; Konczol, L.; Doll, W.; Mulhaupt, R..    Journal of Applied Polymer Science  (2003), 
88(4),  1040-1048. 

Carbonylbiscaprolactam: A versatile reagent for the synthesis of reactive oligomers.    
Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Mulhaupt, Rolf.   Abstracts of Papers, 225th
ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003  (2003),     POLY-077. 
Publisher: American Chemical Society,  Washington, D. C  CODEN: 69DSA4  Conference; Meeting
Abstract  written in English.   

[248] High-output polymer screening: Exploiting combinatorial chemistry and data mining tools
in catalyst and polymer development.    
Tuchbreiter, Arno; Marquardt, Jurgen; Kappler, Bernd; Honerkamp, Josef; Kristen, Marc O.; Mulhaupt,
Rolf.    FMacromolecular Rapid Communications  (2003),  24(1),  47-62.  C

[247] Titanium and zirconium complexes that contain a tridentate bis(phenolato) ligand of the
[OOO]-type.    
Reimer, Valentine; Spaniol, Thomas P.; Okuda, Jun; Ebeling, Henner; Tuchbreiter, Arno; Mulhaupt,
Rolf.    Inorganica Chimica Acta  (2003),  345  221-227. 

[246] Depth profiling of latex blends of fluorinated and fluorine-free acrylates with laser-
induced secondary mass spectrometry.    
Walz, Stefanie M.; Malner, Thomas E.; Mueller, Ulrich; Muelhaupt, Rolf.    Journal of Polymer Science,
Part B: Polymer Physics  (2003),  41(4),  360-367. 

PAT71
Production and use of coated swollen polymers.    
Muelhaupt, Rolf; John, Hendrik.  (Envision Technologies G.m.b.H., Germany).    Ger. Offen.  (2003),    
20 pp.  CODEN: GWXXBX  DE  10130968  A1  20030116  Patent  written in German.    Application:
DE  2001-10130968  20010627.  CAN 138:91466   

[245] Carbonylbiscaprolactam: a versatile reagent for organic synthesis and isocyanate-free
urethane chemistry.    
Maier Steffen; Loontjens Ton; Scholtens Boudewijn; Mulhaupt Rolf     Angewandte Chemie
(International ed. in English)  (2003 Oct 27),  42(41),  5094-7. 

[244] Synthesis and in vitro efficacy of acid-sensitive poly(ethylene glycol) paclitaxel
conjugates.     Rodrigues Paula; Scheuermann Karen; Stockmar Cornelia; Maier Gerhard; Fiebig
Heinz; Unger Clemens; Mulhaupt Rolf; Kratz Felix    Bioorganic & medicinal chemistry letters  (2003
Feb 10),  13(3),  355-60. 

[243] Ancillary ligand effect on single-site styrene polymerization: isospecificity of group 4
metal bis(phenolate) catalysts.     Capacchione Carmine; Proto Antonio; Ebeling Henner; Mulhaupt
Rolf; Moller Klaus; Spaniol Thomas P; Okuda Jun    Journal of the American Chemical Society  (2003
Apr 30),  125(17),  4964-5.

 

2002


The way to isocyanate-free polyurethane. Additive for tailor-made PUR applications.    
Loontjens, Ton; Scholtens, Boudewijn; Maier, Steffen; Mulhaupt, Rolf.    DSM Research,  Geleen, 
Neth.    Kunststoffe  (2002),  92(12),  83-86.  C

[242] Morphology of stereoblock polypropylene.    
Thomann, Ralf; Thomann, Yi; Mulhaupt, R.; Kressler, Jorg; Busse, Karsten; Lilge, Dieter; Chien,
James C. W.    Journal of Macromolecular Science, Physics  (2002), 

PAT70
Process for preparing polyether polyols in the presence of phosphonium cations.    
Rexin, Ornulf; Mulhaupt, Rolf.  (Bayer Aktiengesellschaft, Germany).    U.S.  (2002),     4 pp.  US 
6469218  B1  20021022  Patent  written in English.    Application: US  2002-136208  20020501. 
Priority: DE  2001-10121807  20010504.  CAN 137:311375   

High performance epoxy-layered silicate nanocomposites.    
Kornmann, X.; Thomann, R.; Mulhaupt, R.; Finter, J.; Berglund, L. A.   Polymer Engineering and
Science  (2002),  42(9),  1815-1826. 

[241] Synthesis of amine-cured, epoxy-layered silicate nanocomposites: the influence of the
silicate surface modification on the properties.    
Kornmann, Xavier; Thomann, Ralph; Mulhaupt, Rolf; Finter, Jurgen; Berglund, Lars.    Journal of
Applied Polymer Science  (2002),  86(10),  2643-2652.  CODEN: JAPNAB  ISSN: 0021-8995.  Journal 
written in English.    CAN 138:56650    AN 2002:779487

[240] Online monitoring of silicone network formation by means of in-situ mid-infrared
spectroscopy.    
Scherble, Jonas; Ivan, Bela; Mulhaupt, Rolf.     Macromolecular Chemistry and Physics  (2002), 
203(12),  1866-1871. 

PAT69
Production of oligomeric vinyl alcohol-vinyl ester copolymers.    
Zimmermann, Joerg; Muelhaupt, Rolf.  (Bayer Aktiengesellschaft, Germany).    PCT Int. Appl.  (2002),    
25 pp.  WO  2002074819  A1  20020926  Application: WO  2002-EP2318  20020304.  Priority: DE 
2001-10112365  20010315; DE  2001-10121806  20010504.  CAN 137:248137    AN 2002:736297   
CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 

PAT68
3D-plotting process for the layer by layer production of dental materials.    
Moszner, Norbert; Burgath, Armin; Muelhaupt, Rolf; Salz, Ulrich; Rheinberger, Volker; Landers,
Ruediger.  (Ivoclar Vivadent A.-G., Liechtenstein).    Eur. Pat. Appl.  (2002),     10 pp.  CODEN: EP 
1243231  A2  20020925  Application: EP  2002-1493  20020122.  Priority: DE  2001-10114290 
20010323.  CAN 137:237813   

PAT67
Manufacture of oligomeric vinyl acetate-vinyl alcohol copolymers as polyol components for
polyurethanes.    
Zimmermann, Joerg; Muelhaupt, Rolf.  (Bayer Ag, Germany).    Ger. Offen.  (2002),     10 pp.  DE 
10112365  A1  20020919  Application: DE  2001-10112365  20010315.  CAN 137:233090   

[239] Carboxylated and Sulfonated Poly(arylene-co-arylene sulfone)s: Thermostable
Polyelectrolytes for Fuel Cell Applications.    
Poppe, D.; Frey, H.; Kreuer, K. D.; Heinzel, A.; Muelhaupt, R..    Macromolecules  (2002),  35(21), 
7936-7941. 

[238] Rapid prototyping of scaffolds derived from thermoreversible hydrogels and tailored for
applications in tissue engineering.    
Landers, Rudiger; Hubner, Ute; Schmelzeisen, Rainer; Mulhaupt, Rolf.    Biomaterials  (2002),  23(23), 
4437-4447. 

PAT66
Production of polymerizable dental compositions.    
Klee, Joachim E.; Walz, Uwe; Facher, Andreas; Weber, Christoph; Muelhaupt, Rolf; Frey, Holger;
Mueh, Ekkehard.  (Dentsply Detrey G.m.b.H., Germany).    Ger. Offen.  (2002),     12 pp.  DE 
10101537  A1  20020808  Patent  written in German.    Application: DE  2001-10101537  20010115. 
CAN 137:155779   

[237] Fabrication of soft tissue engineering scaffolds by means of rapid prototyping
techniques.
Landers, R.; Pfister, A.; Huebner, U.; John, H.; Schmelzeisen, R.; Muelhaupt, R..    Journal of
Materials Science  (2002),  37(15),  3107-3116. 

[236] Preparation of partially hydrolyzed oligo(vinyl acetate) as polyol for polyurethane
formation.     Zimmermann, Jorg; Sunder, Alexander; Mulhaupt, Rolf.     Journal of Polymer Science,
Part A: Polymer Chemistry  (2002),  40(12),  2085-2092. 

PAT65
Rubber mixture with improved mechanical characteristics containing layered silicates.    
Herrmann, Wolfram; Muelhaupt, Rolf.  (Conitech Holding GmbH, Germany).    Eur. Pat. Appl.  (2002),    
16 pp.  EP  1211282  A1  20020605    Application: EP  2001-125099  20011023.  Priority: DE  2000-
10058297  20001129.  CAN 137:7341   

[235] Impact fracture and failure behavior of in-situ polymerized, ethylene/butyl acrylate rubber
toughened polyamide-12.    
Lievana, Emiliano; Wollny, Andreas; Mulhaupt, Rolf; Karger-Kocsis, Jozsef.    Macromolecular
Materials and Engineering  (2002),  287(4),  266-271. 

[234] Lysineurethanedimethacrylate - a novel generation of amino acid-based monomers for
bone cements and tissue repair.    
Muh, Ekkehard; Zimmermann, Jorg; Kneser, Ulrich; Marquardt, Jurgen; Mulhaupt, Rolf; Stark, Bjorn.   
Biomaterials  (2002),  23(14),  2849-2854. 

[233] Polyethylene Glycol Conjugates of Methotrexate Varying in Their Molecular Weight from
MW 750 to MW 40000: Synthesis, Characterization, and Structure-Activity Relationships in Vitro
and in Vivo.    
Riebeseel, Katja; Biedermann, Elfi; Loeser, Roland; Breiter, Norbert; Hanselmann, Ralf; Muelhaupt,
Rolf; Unger, Clemens; Kratz, Felix.    Bioconjugate Chemistry  (2002),  13(4),  773-785. 

[232] Melt compounding of syndiotactic polypropylene nanocomposites containing
organophilic layered silicates and in situ formed core/shell nanoparticles.    
Kaempfer, Dirk; Thomann, Ralf; Mulhaupt, Rolf.    Polymer  (2002),  43(10),  2909-2916. 

[231] Anionic ring-opening polymerization of propylene oxide in the presence of phosphonium
catalysts.    
Rexin, Ornulf; Mulhaupt, Rolf.    Journal of Polymer Science, Part A: Polymer Chemistry  (2002), 
40(7),  864-873. 

Anionic polymerization process of lactams.    
Hoogen, Nicola; Wollny, Andreas; Faulhammer, Heike; Muelhaupt, Rolf.  (ATOFINA, Fr.).    Eur. Pat.
Appl.  (2002),     13 pp.    EP  1191050  A1  20020327      Application: EP  2001-402251  20010829. 
Priority: FR  2000-12084  20000922.  CAN 136:263633   

Rapid polymer characterization and on-line reaction monitoring.    
Tuchbreiter, Arno; Muelhaupt, Rolf; Warmbold, Andreas; Liebetraut, Peter; Kappler, Bernd;
Honerkamp, Josef.    Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 
(2002),  43(1),  285-286. 

Rapid polymer characterization and on-line reaction monitoring.    
Tuchbreiter, Arno; Warmbold, Andreas; Mulhaupt, Rolf; Kappler, Bernd; Honerkamp, Josef.   
Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002 
(2002),     POLY-343.  Publisher: American Chemical Society,  Washington, D. C  CODEN: 69CKQP 
Conference; Meeting Abstract  written in English.    AN 2002:192191    CAPLUS   (Copyright 2005
ACS on SciFinder (R)) 

[230] Poly(ethene-co-norbornene) Obtained with a Constrained Geometry Catalyst. A Study of
Reaction Kinetics and Copolymer Properties.    
Thorshaug, Knut; Mendichi, Raniero; Boggioni, Laura; Tritto, Incoronata; Trinkle, Stefan; Friedrich,
Christian; Muelhaupt, Rolf.       Macromolecules  (2002),  35(8),  2903-2911.  CODEN: MAMOBX 
ISSN: 0024-9297.

[229] Novel hydrogels as supports for in vitro cell growth: poly(ethylene glycol)- and gelatin-
based (meth)acrylamidopeptide macromonomers.    
Zimmermann, Jorg; Bittner, Katharina; Stark, Bjorn; Mulhaupt, Rolf.    Biomaterials  (2002),  23(10), 
2127-2134. 

[228] Rapid prototyping of scaffolds derived from thermoreversible hydrogels and tailored for
applications in tissue engineering.    
Landers Rudiger; Hubner Ute; Schmelzeisen Rainer; Mulhaupt Rolf    Biomaterials  (2002 Dec), 
23(23),  4437-47. 

[227] Polyethylene glycol conjugates of methotrexate varying in their molecular weight from
MW 750 to MW 40000: synthesis, characterization, and structure-activity relationships in vitro
and in vivo.    
Riebeseel Katja; Biedermann Elfi; Loser Roland; Breiter Norbert; Hanselmann Ralf; Mulhaupt Rolf;
Unger Clemens; Kratz Felix    Bioconjugate chemistry  (2002 Jul-Aug),  13(4),  773-85. 


[226] Novel hydrogels as supports for in vitro cell growth: poly(ethylene glycol)- and gelatine-
based (meth)acrylamidopeptide macromonomers.    
Zimmermann Jorg; Bittner Katharina; Stark Bjorn; Mulhaupt Rolf    Biomaterials  (2002 May),  23(10), 
2127-34.

 

2001


[225] Acrylate-terminated macromonomers by Michael addition.    
Muh, Ekkehard; Weickmann, Hans; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.    IMacromolecular
Chemistry and Physics  (2001),  202(18),  3484-3489. 

[224] Influence of lignin type on the mechanical properties of lignin based compounds.    
Nitz, Hansjorg; Semke, Hinnerk; Mulhaupt, Rolf.   Macromolecular Materials and Engineering  (2001), 
286(12),  737-743. 

Customized lignin. Use as nontoxic biostabilizers.    
Nitz, Hansjorg; Semke, Hinnerk; Mulhaupt, Rolf; Abacherli, Alfred.   Kunststoffe  (2001),  91(11),  98-
101. 

[223] Organic-inorganic hybrid nanocomposites prepared by means of sol-gel condensation of
bismethacrylatesilanes in reactive diluents.    
Muh, Ekkehard; Frey, Holger; Klee, Joachim E.; Mulhaupt, Rolf.    Advanced Functional Materials 
(2001),  11(6),  425-429. 

Nanocomposites - on the way to application.    
Mulhaupt, Rolf; Engelhardt, Thomas; Schall, Norbert.    Kunststoffe  (2001),  91(10), 
178,180,182,184,186-188,190. 

Combinatorial chemistry for the development of new catalysts and polymeric materials:
prospects and challenges.    
Tuchbreiter, Arno; Kappler, Bernd; Honerkamp, Josef; Mulhaupt, Rolf.    DECHEMA Monographien 
(2001),  137(7th International Workshop on Polymer Reaction Engineering, 2001),  323-334. 

[222] Organic-inorganic hybrid networks by the sol-gel process and subsequent
photopolymerization.    
Muh, Ekkehard; Stieger, Markus; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.  Advanced
Functional Materials  (2001),  11(6),  425-429. 

[221] Combustion behavior of EVA/fluorohectorite nanocomposites.    
Zanetti, Marco; Camino, Giovanni; Mulhaupt, Rolf.    Polymer Degradation and Stability  (2001),  74(3), 
413-417. 

PAT64
Thermoplastically processable elastomer compositions from in-situ formed elastomer
components and their use.    
Rhoenisch, Thomas; Steffl, Udo; Muelhaupt, Rolf; Barghoorn, Peter.  (Rehau A.-G. & Co., Germany).   
Eur. Pat. Appl.  (2001),     10 pp.  EP  1152034  A1  20011107   Application: EP  2001-110549 
20010428.  Priority: DE  2000-10021478  20000503.  CAN 135:345688   

[220] Miscibility of Branched Ethene Homopolymers with Iso- and Syndiotactic Polypropenes.    
Marquardt, Juergen; Thomann, Ralf; Thomann, Yi; Heinemann, Johannes; Muelhaupt, Rolf.   
Macromolecules  (2001),  34(25, k),  8669-8674. 

[219] A novel route to alpha,omega-bis(acrylamidopeptide)-terminated oligo(ethylene oxide)
and hydrogels.     Zimmermann, Jorg; Mulhaupt, Rolf.    Macromolecular Bioscience  (2001),  1(7), 
290-297.  C

PAT63
Device and method for the production of three-dimensional objects.    
Muelhaupt,  Rolf; Landers,  Ruediger; John,  Hendrik.  (Envision Technologies Gmbh, Germany).   
PCT Int. Appl.  (2001),    WO  2001078968  A1  20011025  Application: WO  2000-EP12102 
20001201.  Priority: DE  2000-10018987  20000417.  AN 2001:776620   

[218] High-Throughput Evaluation of Olefin Copolymer Composition by Means of Attenuated
Total Reflection Fourier Transform Infrared Spectroscopy.    
Tuchbreiter, Arno; Marquardt, Juergen; Zimmermann, Joerg; Walter, Philipp; Muelhaupt, Rolf; Kappler,
Bernd; Faller, Daniel; Roths, Tobias; Honerkamp, Josef.    Journal of Combinatorial Chemistry  (2001), 
3(6),  598-603. 

[217] Influence of copolymer composition and curing on toughness of isotactic polypropene
blended together with metallocene-EPDM and ethene/propene/vinylcyclohexane terpolymers.    
Walter, Philipp; Mader, Dietmar; Mulhaupt, Rolf.    Macromolecular Materials and Engineering  (2001), 
286(7),  388-397.

The polyolefin challenges: catalyst and process design, tailor-made materials, high-throughput
development and data mining.    
Tuchbreiter, Arno; Mulhaupt, Rolf.    Macromolecular Symposia  (2001),  173(Conference on Insertion
Polymerization, 2000),  1-20. 

[216] Rubber nanocomposites: morphology and mechanical properties of BR and SBR
vulcanizates reinforced by organophilic layered silicates.    
Ganter, Markus; Gronski, Wolfram; Reichert, Peter; Mulhaupt, Rolf.    Rubber Chemistry and
Technology  (2001),  74(2),  221-235. 

[215] Meso- and Microscopic Behavior of Spherical Polymer Particles Assembling at the Air-
Water Interface.    
Wolert, Elizabeth; Setz, Stefan M.; Underhill, Royale S.; Duran, Randolph S.; Schappacher, Michel;
Deffieux, Alan; Hoelderle, Matthias; Muelhaupt, Rolf.    Langmuir  (2001),  17(18),  5671-5677. 

PAT62
Metal-containing complexes from glycidol polymers for hydrogenation catalysts.    
Mecking, Stefan; Muelhaupt, Rolf.  (Germany).    Ger. Offen.  (2001),     6 pp.  DE  10104070  A1 
20010802  Application: DE  2001-10104070  20010129.  Priority: DE  2000-10004043  20000131. 
CAN 135:138992   

[214] Bismethacrylate-Based Hybrid Monomers via Michael-Addition Reactions.    
Mueh, Ekkehard; Marquardt, Juergen; Klee, Joachim E.; Frey, Holger; Muelhaupt, Rolf.     
Macromolecules  (2001),  34(17),  5778-5785. 

Nanofillers based upon organophilic layered silicates.    
Zilg, Carsten; Dietsche, Frank; Hoffmann, Botho; Dietrich, Christoph; Mulhaupt, Rolf.   
Macromolecular Symposia  (2001),  169(Fillers and Filled Polymers),  65-77.  CODEN: MSYMEC 
ISSN: 1022-1360.

[213] Hyperbranched polyesters and their application in dental composites: monomers for low
shrinking composites.   
Klee, J. E.; Schneider, C.; Holter, D.; Burgath, A.; Frey, H.; Mulhaupt, R..    Polymers for Advanced
Technologies  (2001),  12(6),  346-354. 

[212] Morphology of the transparent IPN-like system PE: (BMA-co-S).    
Borsig, Eberhard; Thomann, Ralf; Fiedlerova, Agnesa; Mulhaupt, Rolf.    Journal of Applied Polymer
Science  (2001),  81(11),  2615-2620.  C

PAT61
Impact-resistant modified thermoplastic polymer mixtures on the basis of SO2 copolymers
with an aliphatic main chain.    
Queisser, Joachim; Barghoorn, Peter; McKee, Graham Edmund; Muelhaupt, Rolf; Schnell, Rupert. 
(BASF A.-G., Germany).    Ger. Offen.  (2001),     15 pp.    DE  19962841  A1  20010705  Patent 
written in German.    Application: DE  99-19962841  19991223.  CAN 135:93383    AN 2001:488515   
CAPLUS  

[211] Reactive extrusion of polycaprolactone compounds containing wood flour and lignin.   
Nitz, Hansjorg; Semke, Hinnerk; Landers, Rudiger; Mulhaupt, Rolf.    Journal of Applied Polymer
Science  (2001),  81(8),  1972-1984. 

[210] Long chain branched polypropene prepared by means of propene copolymerization with
1,7-octadiene using MAO-activated rac-Me2Si(2-Me-4-phenyl-Ind)2ZrCl2.    
Walter, Philipp; Trinkle, Stefan; Lilge, Dieter; Friedrich, Christian; Mulhaupt, Rolf.    Macromolecular
Materials and Engineering  (2001),  286(5),  309-315. 

PAT60
Aqueous dispersions of ethylene polymers, their use and their production by emulsion
polymerization using metal complexes.    
Kristen, Marc Oliver; Manders, Lambertus; Mecking, Stefan; Bauers, Florian M.; Muelhaupt, Rolf. 
(Basf Aktiengesellschaft, Germany).    PCT Int. Appl.  (2001),     55 pp.  WO  2001044325  A1 
20010621  D  Application: WO  2000-EP10244  20001018.  Priority: DE  99-19961340  19991217. 
CAN 135:46655   

PAT59
Procedure for the homogeneous catalytic production of high-branched amorphous
polyethylene with rubber properties.    
Heinemann, Johannes; Muelhaupt, Rolf; Queisser, Joachim; Luinstra, Gerrit; Gepraegs, Michael. 
(Basf A.-G., Germany).    Ger. Offen.  (2001),     16 pp. DE  19960123  A1  20010621  Application: DE 
99-19960123  19991213. 

[209] Influence of microstructure on properties of polymers with high glass transition
temperatures obtained by ring-opening metathesis polymerization of polycyclic hydrocarbons.    
Preishuber-Pflugl, Peter; Eder, Elisabeth; Stelzer, Franz; Reisinger, Harald; Mulhaupt, Rolf; Forsyth,
John; Perena, Jose M.    Macromolecular Chemistry and Physics  (2001),  202(7),  1130-1137. 

[208] Morphological stability of polypropylene nanocomposites.    
Reichert, Peter; Hoffmann, Botho; Bock, Thorsten; Thomann, Ralf; Mulhaupt, Rolf; Friedrich, Christian.   
Macromolecular Rapid Communications  (2001),  22(7),  519-523.

[207] Influence of zirconocene structure and propene content on melt rheology of polyethene
and ethene/propene copolymers.    
Walter, Philipp; Trinkle, Stefan; Mulhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (2001),  46(2-3), 
205-213. 

[206] Formation of CdS nanoclusters in phase-separated poly(2-hydroxyethyl methacrylate)-l-
polyisobutylene amphiphilic conetworks.    
Scherble, Jonas; Thomann, Ralf; Ivan, Bela; Mulhaupt, Rolf.    Journal of Polymer Science, Part B:
Polymer Physics  (2001),  39(12),  1429-1436. 

Correlations between chain branching, morphology development and polymer properties of
polyethenes.    
Walter, Philipp; Heinemann, Johannes; Ebeling, Henner; Mader, Dietmar; Trinkle, Stefan; Mulhaupt,
Rolf.    Organometallic Catalysts and Olefin Polymerization  (2001),     317-326.  Publisher: Springer-
Verlag,  Berlin, Germany  CODEN: 69BGVD  Conference; General Review  written in English.    CAN
135:318724   

[205] Carbohydrate analogue polymers by ring opening metathesis polymerisation (ROMP) and
subsequent catalytic dihydroxylation.    
Meier, Stefan; Stelzer, Franz; Reisinger, Harald; Haag, Rainer; Mecking, Stefan; Mulhaupt, Rolf.   
Chemical Communications (Cambridge, United Kingdom)  (2001),   (9),  855-856. 

Copolymerization of arylchlorides by nickel catalyzed coupling: novel polyelectrolytes.    
Poppe, D.; Frey, H.; Heinzel, A.; Mulhaupt, R..    Polymeric Materials Science and Engineering 
(2001),  84  333-334. 

Copolymerization of arylchlorides by nickel-catalyzed coupling: Novel polyelectrolytes.    
Poppe, Dirk; Frey, Holger; Heinzel, Angelika; Mulhaupt, Rolf.    Abstracts of Papers, 221st ACS
National Meeting, San Diego, CA, United States, April 1-5, 2001  (2001),     PMSE-189.  CODEN:
69FZD4  Journal;

[203] Thermal behavior of poly(propylene) layered silicate nanocomposites.    
Zanetti, Marco; Camino, Giovanni; Reichert, Peter; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (2001),  22(3),  176-180. 

[202] Influence of stereoirregularities on the formation of the gamma-phase in isotactic
polypropene.     Thomann, R.; Semke, H.; Maier, R.-D.; Thomann, Y.; Scherble, J.; Mulhaupt, R.;
Kressler, J.    Polymer  (2001),  42(10),  4597-4603. 

[201] Synthesis and thermal behavior of layered silicate-EVA nanocomposites.    
Zanetti, M.; Camino, G.; Thomann, R.; Mulhaupt, R..    Polymer  (2001),  42(10),  4501-4507. 

PAT58
Siloxane-containing macromonomers and dental composites thereof.    
Klee, Joachim E.; Walz, Uwe; Fiedler, Jurgen; Mulhaupt, Rolf; Frey, Holger; Muh, Ekkehardt. 
(Dentsply International Inc., USA).    PCT Int. Appl.  (2001),     30 pp.  WO  2001008639  A1 
20010208  Application: WO  2000-US20348  20000726.  Priority: US  99-146093  19990728.  CAN
134:152704   

PAT57
Nanocomposites containing organophilic layered silicates.   
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Vantico A.-G., Switz.).    PCT Int. Appl.  (2001),     21
pp.  WO  2001004205  A1  20010118  Designated States W: US.  Designated States RW: AT, BE,
CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE.  Patent  written in English.   
Application: WO  2000-EP6422  20000706.  Priority: CH  99-1288  19990713.  CAN 134:116625   


PAT56
Filler mixture for thermosetting resin to form nanocomposite with improved mech. properties.    
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Vantico A.-G., Switz.).    PCT Int. Appl.  (2001),     24
pp.  WO  2001004193  A1  20010118  Application: WO  2000-EP6424  20000706.  Priority: CH  99-
1289  19990713.  CAN 134:116623   

PAT55
Rubber-modified polymer mixtures, their production and their use.    
Gepraegs, Michael; Queisser, Joachim; Muelhaupt, Rolf; Schnell, R.  (BASF A.-G., Germany).    Ger.
Offen.  (2001),     8 pp.  DE  19931187  A1  20010111  Patent  written in German.    Application: DE 
99-19931187  19990707.  CAN 134:101637   

[200] High-throughput evaluation of olefin copolymer composition by means of attenuated total
reflection Fourier tranform infrared spectroscopy.    
Tuchbreiter A; Marquardt J; Zimmermann J; Walter P; Mulhaupt R; Kappler B; Faller D; Roths T;
Honerkamp J    Journal of combinatorial chemistry  (2001 Nov-Dec),  3(6),  598-603.

 

2000


 [199] Organic/inorganic hybrid materials and nanocomposites based upon layered silicates
modified with cyclic amidines.    
Zilg, Carsten; Thomann, Ralf; Baumert, Martin; Finter, Jurgen; Mulhaupt, Rolf.    Macromolecular
Rapid Communications  (2000),  21(17),  1214-1219. 

PAT54
Method for producing graft copolymers containing an elastic backbone.     Mulhaupt, Rolf;
Heinemann, Johannes; Baumert, Martin; Queisser, Joachim; Geprags, Michael.  (BASF A.-G.,
Germany).    PCT Int. Appl.  (2000),     43 pp.  WO  2000077060  A1  20001221  DPriority: DE  99-
19927347  19990616.  CAN 134:57145   

PAT53
Production of polysulfones with aliphatic main chain.    
Queisser, Joachim; Gepraegs, Michael; Erbes, Joerg; Baumert, Martin; Muelhaupt, Rolf.  (BASF A.-G.,
Germany).    Ger. Offen.  (2000),     8 pp.  DE  19926778  A1  20001214  Application: DE  99-
19926778  19990611.  CAN 134:42597    AN 2000:880628    CAPLUS   (Copyright 2005 ACS on
SciFinder (R)) 

[198] Desktop manufacturing of complex objects, prototypes and biomedical scaffolds by
means of computer-assisted design combined with computer-guided 3D plotting of polymers
and reactive oligomers.    
Landers, Rudiger; Mulhaupt, Rolf. Macromolecular Materials and Engineering  (2000),  282  17-21. 

[197] Rheology and processing of metallocene-based polyolefins.    
Friedrich, Chr.; Eckstein, A.; Stricker, F.; Mulhaupt, R..    Editor(s): Scheirs, John; Kaminsky, Walter.   
Metallocene-Based Polyolefins  (2000),  2  399-417.  Publisher: John Wiley & Sons Ltd.,  Chichester,
UK  CODEN: 69AHES  Conference; General Review  written in English.    CAN 134:208376  

[196] Influence of metallocene structures on molecular and supermolecular architectures of
polyolefins.    
Fischer, D.; Jungling, S.; Schneider, M. J.; Suhm, J.; Mulhaupt, R..    Editor(s): Scheirs, John;
Kaminsky, Walter.    Metallocene-Based Polyolefins  (2000),  1  103-117.  Publisher: John Wiley &
Sons Ltd.,  Chichester, UK  CODEN: 69AHES  Conference; General Review  written in English.    CAN
134:208144   

[195] The influence of silicate modification and compatibilizers on mechanical properties and
morphology of anhydride-cured epoxy nanocomposites.    
Zilg, Carsten; Thomann, Ralf; Finter, Jurgen; Mulhaupt, Rolf.    Macromolecular Materials and
Engineering  (2000),  280/281  41-46. 

PAT52
Synthesis of melamine-modified organophilic layered phyllosilicates in fabrication of
nanocomposites and molded polymer parts.   
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Vantico A.-G., Switz.).    PCT Int. Appl.  (2000),     32
pp.  CODEN: PIXXD2  WO  2000044669  A1  20000803  Designated States W: BR, CN, JP, KR, US. 
Designated States RW: AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE. 
Patent  written in German.    Application: WO  2000-EP480  20000122.  Priority: CH  99-160 
19990128.  CAN 133:122434   

[194] Development of acid-sensitive platinum(II) complexes with protein-binding properties.    
Schutte, M. T.; Mulhaupt, R.; Kratz, F.  Metal-Based Drugs  (2000),  7(2),  89-100. 

PAT51
Method for producing highly branched glycidol-based polyols.    
Sunder, Alexander; Mulhaupt, Rolf.  (Bayer Aktiengesellschaft, Germany).    PCT Int. Appl.  (2000),    
13 pp.  Application: WO  99-EP9773  19991210.  Priority: DE  98-19859300  19981222; DE  99-
19947631  19991004.  CAN 133:74520   

Hyperbranched polyglycerols by ring-opening multibranching polymerization.    
Sunder, A.; Frey, H.; Mulhaupt, R..    Macromolecular Symposia  (2000),  153(Recent Advances in
Ring Opening (Metathesis) Polymerization),  187-196. 

PAT50
Dental compositions containing polycyanoacrylates.     Klee, Joachim E.; Walz, Uwe; Mulhaupt,
Rolf.  (Dentsply International Inc., USA).    PCT Int. Appl.  (2000),     24 pp.  WO  2000033793  A1 
20000615  DApplication: WO  99-US29367  19991210.  Priority: US  98-111864  19981211.  CAN
133:48969    A

[193] Multi-arm star block copolymers based on ?-caprolactone with hyperbranched
polyglycerol core.    
Burgath, Armin; Sunder, Alexander; Neuner, Ingo; Mulhaupt, Rolf; Frey, Holger.    Macromolecular
Chemistry and Physics  (2000),  201(7),  792-797. 

Synthesis of methacrylated macromonomers for biocompatible hydrogels.    
Mulhaupt, Rolf; Zimmermann, Jorg.    Book of Abstracts, 219th ACS National Meeting, San Francisco,
CA, March 26-30, 2000  (2000),    

Bismethacrylate-based hybrid monomers for advanced dental composites.    
Muh, Ekkehard; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.   Book of Abstracts, 219th ACS
National Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-165.  Publisher: American
Chemical Society,  Washington, D. C 

Polypropylene nanocomposites based on organophilic-layered silicates.    
Reichert, Peter; Zilg, Carsten; Mulhaupt, Rolf.    Book of Abstracts, 219th ACS National Meeting, San
Francisco, CA, March 26-30, 2000  (2000),     PMSE-137.  Publisher: American Chemical Society, 
Washington, D. C  CODEN: 69CLAC  Conference;

Epoxy nanocomposites based on organophilic-layered silicates: Improving
toughness/stiffness/strength balance.    
Zilg, Carsten; Mulhaupt, Rolf; Thomann, Ralf; Finter, Jurgen.    Book of Abstracts, 219th ACS National
Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-136.  Publisher: American
Chemical Society,  Washington, D. C 

Morphology, mechanical properties, and mechanism of reinforcement of rubber
nanocomposites.    
Ganter, Markus; Reichert, Peter; Mulhaupt, Rolf; Gronski, Wolfram.    Book of Abstracts, 219th ACS
National Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-099.  Publisher: American
Chemical Society,  Washington,

Acrylic nanocomposites containing organoclay nanofillers: Morphology development,
properties, and fracture behavior.    
Mulhaupt, Rolf; Dietsche, Frank; Doell, Wilhelm; Thomann, Ralf.    Book of Abstracts, 219th ACS
National Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-097.  Publisher: American
Chemical Society,  Washington, D. C 

Complex hyperbranched molecular architectures based on polyether polyols as versatile
alternative to dendrimers.    
Frey, Holger; Mulhaupt, Rolf; Sunder, Alexander.    Book of Abstracts, 219th ACS National Meeting,
San Francisco, CA, March 26-30, 2000  (2000),    

Morphologies and miscibilities of polypropene with random poly(ethene-co-1-butene).    
Thomann, Yi; Suhm, Jurgen; Thomann, Ralf; Maier, Ralf-Dieter; Mulhaupt, Rolf; Bar, Georg.   
Macromolecular Symposia  (2000),  149(6th European Symposium on Polymer Blends, 1999),  125-
129.

[192] Highly branched polyethylene graft copolymers prepared by means of migratory insertion
polymerization combined with TEMPO-mediated controlled radical polymerization.    
Baumert, Martin; Heinemann, Johannes; Thomann, Ralf; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (2000),  21(6),  271-276.

[191] Synthesis of poly(glycerol)-block-poly(methyl acrylate) multi-arm star polymers.    
Maier, Steffen; Sunder, Alexander; Frey, Holger; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (2000),  21(5),  226-230. 

[190] Influence of compatibilizers on the surface hardness, water uptake, and the mechanical
properties of poly(propylene) wood flour composites prepared by reactive extrusion.    
Nitz, Hansjorg; Reichert, Peter; Romling, Hartmut; Mulhaupt, Rolf.    Macromolecular Materials and
Engineering  (2000),  276/277  51-58. 

[189] Short and long chain branching of polyethene prepared by means of ethene
copolymerization with 1-eicosene using MAO activated Me2Si(Me4Cp)(NtBu)TiCl2.    
Walter, Philipp; Trinkle, Stefan; Suhm, Jurgen; Mader, Dietmar; Friedrich, Christian; Mulhaupt, Rolf.   
Macromolecular Chemistry and Physics  (2000),  201(5),  604-612.  C

PAT49
Polyolefin nanocomposites.    
Muelhaupt, Rolf; Heinemann, Johannes; Reichert, Peter; Gepraegs, Michael; Queisser, Joachim. 
(BASF A.-G., Germany).    Ger. Offen.  (2000),     20 pp.  DE  19846314  A1  20000413  Patent 
written in German.    Application: DE  98-19846314  19981008.  CAN 132:279669   

[188] Melt modification of poly(styrene-co-maleic anhydride) with alcohols in the presence of
1,3-Oxazolines.   
 Bruch, Matthias; Mader, Dietmar; Bauers, Florian; Loontjens, Ton; Mulhaupt, Journal of Polymer
Science, Part A: Polymer Chemistry  (2000),  38(8),  1222-1231. 

[187] Poly(propylene)/organoclay nanocomposite formation: influence of compatibilizer
functionality and organoclay modification.    
Reichert, Peter; Nitz, Hansjorg; Klinke, Stefan; Brandsch, Rainer; Thomann, Ralf; Mulhaupt, Rolf.   
Macromolecular Materials and Engineering  (2000),  275  8-17. 

[186] Toughening of epoxy resins modified with polyetherester block copolymers: the
influence of modifier molecular architecture on mechanical properties.    
Hofflin, F.; Konczol, L.; Doll, W.; Morawiec, J.; Mulhaupt, R..    Journal of Applied Polymer Science 
(2000),  76(5),  623-634.

Polypropylene nanocomposites based upon organophilic layered silicates.    
Reichert, Peter; Nitz, Hansjorg; Klinke, Stefan; Thomann, Ralf; Brandsch, Rainer; Zilg, Carsten;
Mulhaupt, Rolf.   Polymeric Materials Science and Engineering  (2000),  82  251-252. 

Epoxy nanocomposites based upon organophilic layered silicates: improving
toughness/stiffness/strength balance.    
Zilg, Carsten; Mulhaupt, Rolf; Thomann, Ralf; Finter, Jurgen.   Polymeric Materials Science and
Engineering  (2000),  82  249-250.  CODEN: PMSEDG  ISSN: 0743-0515. 

Morphology, mechanical properties and mechanism of reinforcement of rubber
nanocomposites.    
Ganter, Markus; Reichert, Peter; Mulhaupt, Rolf; Gronski, Wolfram.    Polymeric Materials Science and
Engineering  (2000),  82  228-229. 

Acrylic nanocomposites containing organoclay nanofillers: morphology development,
properties and fracture behavior.    
Dietsche, Frank; Thomann, Ralf; Doell, Wilhelm; Mulhaupt, Rolf.    Polymeric Materials Science and
Engineering  (2000),  82  222-223. 

Bismethacrylate-based hybrid monomers for advanced dental composites.    
Muh, Ekkehard; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.     Polymeric Materials Science and
Engineering  (2000),  82  99-100. 

[185] Relationship between morphology and mechanical properties of polypropylene/ethene-
co-butene binary blends with various butene contents.    
Mouzakis, D. E.; Mader, D.; Mulhaupt, R.; Karger-Kocsis, J.    Journal of Materials Science  (2000), 
35(5),  1219-1230.  CODEN: JMTSAS  ISSN: 0022-2461.  Journal  written in English.   

[184] Hyperbranched polyether polyols. A modular approach to complex polymer architectures.    
Sunder, Alexander; Mulhaupt, Rolf; Haag, Rainer; Frey, Holger.   Advanced Materials (Weinheim,
Germany)  (2000),  12(3),  235-239. 

[183] Influence of n-Alkyl Branches on Glass-Transition Temperatures of Branched
Polyethylenes Prepared by Means of Metallocene- and Palladium-Based Catalysts.    
Maeder, Dietmar; Heinemann, Johannes; Walter, Philipp; Muelhaupt, Rolf.    Macromolecules  (2000), 
33(4),  1254-1261. 

[182] Synthesis and Thermal Behavior of Esterified Aliphatic Hyperbranched Polyether Polyols.    
Sunder, Alexander; Bauer, Thorsten; Muelhaupt, Rolf; Frey, Holger.    Macromolecules  (2000),  33(4), 
1330-1337. 

[181] Chiral Hyperbranched Dendron Analogues.    
Sunder, Alexander; Muelhaupt, Rolf; Haag, Rainer; Frey, Holger.    Macromolecules  (2000),  33(2), 
253-254.

[180] Functional Poly(ethylene oxide) Multiarm Star Polymers: Core-First Synthesis Using
Hyperbranched Polyglycerol Initiators.    
Knischka, Ralf; Lutz, Pierre J.; Sunder, Alexander; Muelhaupt, Rolf; Frey, Holger.    Macromolecules 
(2000),  33(2),  315-320.

[179] Hyperbranched Polyether-Polyols Based on Polyglycerol: Polarity Design by Block
Copolymerization with Propylene Oxide.    
Sunder, Alexander; Muelhaupt, Rolf; Frey, Holger.    Macromolecules  (2000),  33(2),  309-314. 

[178] Translucent acrylic nanocomposites containing anisotropic laminated nanoparticles
derived from intercalated layered silicates.    
Dietsche, Frank; Thomann, Yi; Thomann, Ralf; Mulhaupt, Rolf.    Journal of Applied Polymer Science 
(2000),  75(3),  396-405.  CODEN: JAPNAB  ISSN: 0021-8995.  Journal  written in English.    CAN
132:94279    AN 1999:785116    CAPLUS   (Copyright 2005 ACS)

 

1999


[177] Transition metal catalyzed olefin, cycloolefin, and styrene polymerization.    
Okuda, Jun; Mulhaupt, Rolf.    Editor(s): Schlueter, A.-Dieter.    Materials Science and Technology 
(1999),  20(Synthesis of Polymers),  123-162.  Publisher: Wiley-VCH Verlag GmbH,  Weinheim,
Germany  CODEN: 58AMAL  Conference; General Review  written in English.   

Materials Week '98, Volume VIII: Symposium 10, Polymers; Symposium 14, Simulation of
Polymers.  (Werkstoffwoch '98 Band VIII Symposium 10 Polymere, Symposium 14 Simulation
Polymere) 
Michaeli, Walter; Mulhaupt, Rolf; Moller, Martin; Riedel, Hermann; Editors.    Germany.    (1999),    
273 pp.  Publisher: (Wiley-VCH,  Weinheim, Germany)  Book  written in German.    CAN 132:251869   

Branched bismethacrylates - a variable modular system for low-shrinkage matrix system.    
Klee, J. E.; Holter, D.; Frey, H.; Mulhaupt, R..    Dentsply GmbH,  Konstanz,  Germany.  Editor(s):
Michaeli, Walter.    Werkstoffwoche '98, Band VIII: Symposium 10, Polymere; Symposium 14,
Simulation Polymere, Munich, Sept., 1998  (1999),  Meeting Date 1998,     181-186.  Publisher: Wiley-
VCH Verlag GmbH,  Weinheim, Germany  C

Nickel(II) and palladium(II) complexes with 1,4-diaza-1,3-butadiene ligands as catalysts for
polymerization of ethene and 1-olefins.    
Schleis, Thomas; Heinemann, Johannes; Spaniol, Thomas P.; Mulhaupt, Rolf; Okuda, Jun.   
JEditor(s): Michaeli, Walter.    Werkstoffwoche '98, Band VIII: Symposium 10, Polymere; Symposium
14, Simulation Polymere, Munich, Sept., 1998  (1999),  Meeting Date 1998,     99-102.  Publisher:
Wiley-VCH Verlag GmbH,  Weinheim, Germany 

Fascinating transition metal catalysis: new polymer architectures in copolymers with polar
monomers.    
Heinemann, J.; Mulhaupt, R.; Brinkmann, P. H. P.; Luinstra, G. A.; Wursche, R.; Rieger, B.; Geprags,
M.   Editor(s): Michaeli, Walter.    Werkstoffwoche '98, Band VIII: Symposium 10, Polymere;
Symposium 14, Simulation Polymere, Munich, Sept., 1998  (1999),  Meeting Date 1998,     95-98. 
Publisher: Wiley-VCH Verlag GmbH,  Weinheim, Germany 

[176] Thermal properties and flammability of acrylic nanocomposites based upon organophilic
layered silicates.    
Dietsche, F.; Mulhaupt, R..   Polymer Bulletin (Berlin)  (1999),  43(4-5),  395-402. 

[175] Acid-sensitive polyethylene glycol conjugates of doxorubicin: preparation, in vitro
efficacy and intracellular distribution.    
Rodrigues, Paula C. A.; Beyer, Ulrich; Schumacher, Peter; Roth, Thomas; Fiebig, Heinz H.; Unger,
Clemens; Messori, Luigi; Orioli, PierLuigi; Paper, Dietrich H.; Mulhaupt, Rolf; Kratz, Felix.    Bioorganic
& Medicinal Chemistry  (1999),  7(11),  2517-2524. 

[174] Molecular nanocapsules based on amphiphilic hyperbranched polyglycerols.    
Sunder, Alexander; Kramer, Michael; Hanselmann, Ralf; Mulhaupt, Rolf; Frey, Holger.    Angewandte
Chemie, International Edition  (1999),  38(23),  3552-3555. 

[173] Novel polypropylene materials.    
Walter, Philipp; Mader, Dietmar; Reichert, Peter; Mulhaupt, Rolf.    Journal of Macromolecular
Science, Pure and Applied Chemistry  (1999),  A36(11),  1613-1639. 

PAT48
Liquid crystalline (meth)acrylate compounds, composition and method.    
Klee, Joachim E.; Frey, Holger; Holter, Dirk; Mulhaupt, Rolf.  (Dentsply G.m.b.H., Germany).    U.S. 
(1999),     23 pp., Cont.-in-part of U.S. Ser. No. 543,950, abandoned. US  5998499  A  19991207 
Patent  written in English.    Application: US  96-723443  19961007.  Priority: US  94-217998 
19940325; US  94-231535  19940422; US  95-543950  19951017.  CAN 132:15678   

[172] Nanostructure Formation via Association of Tectons in Amorphous Polymer Matrices.    
Fuchs, Konrad; Bauer, Thorsten; Thomann, Ralf; Wang, Chun; Friedrich, Christian; Muelhaupt, Rolf.   
IMacromolecules  (1999),  32(25),  8404-8412. 

[171] Energy transfer from phenanthrene to anthracene in a dye-labeled (ethylene-methyl
acrylate) copolymer.    
Liu, Ronghua; Moffitt, Matthew; Winnik, Mitchell A.; Heinemann, Johannes; Mulhaupt, Rolf.    Journal
of Polymer Science, Part A: Polymer Chemistry  (1999),  37(22),  4169-4175.  CODEN: J

[170] Hyperbranched polyether polyols with liquid crystalline properties.    
Sunder, Alexander; Quincy, Marie-France; Mulhaupt, Rolf; Frey, Holger.      Angewandte Chemie,
International Edition  (1999),  38(19),  2928-2930.  C

PAT47
Method for producing copolymers from functional olefinically unsaturated monomers and
nonpolar olefinically unsaturated compounds, and uses for the copolymers.    
Geprags, Michael; Mulhaupt, Rolf; Heinemann, Johannes.  (BASF Aktiengesellschaft, Germany).   
PCT Int. Appl.  (1999),     33 pp.  WO  9947569  A1  19990923  Priority: DE  98-19812124  19980319. 
CAN 131:258066   

[169] Combined ultramicrotomy for AFM and TEM using a novel sample holder.    
Thomann, Y.; Thomann, R.; Bar, G.; Ganter, M.; Machutta, B.; Mulhaupt, R..    Journal of Microscopy
(Oxford)  (1999),  195(2),  161-163.  CODEN: JMICAR  ISSN: 0022-2720.  J

[168] Influence of comonomer incorporation on morphology and thermal and mechanical
properties of blends based upon isotactic metallocene-polypropene and random ethene/1-
butene copolymers.    
Mader, Dietmar; Thomann, Yi; Suhm, Jurgen; Mulhaupt, Rolf.   Journal of Applied Polymer Science 
(1999),  74(4),  838-848. 

Transition metal catalyzed ethene homo- and copolymerization in the presence of exfoliated
organophilic layered silicates and polyolefin nanocomposite formation.    
Heinemann, Johannes; Reichert, Peter; Thomann, Ralf; Mulhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1999),  40(2),  788-789.  CODEN:
ACPPAY  ISSN: 0032-3934.  Journal  written in English.    C

The influence of n-alkyl branches on thermal properties of polyethylenes prepared by means of
metallocene- and palladium-based catalysts.    
Mader, Dietmar; Walter, Philipp; Heinemann, Johannes; Mulhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1999),  40(2),  719-720.  C

Synthesis of highly branched polyethylene graft copolymers by combination of palladium-
diazadiene catalyzed and tempomediated polymerization.    
Baumert, Martin; Heinemann, Johannes; Thomann, Ralf; Mulhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1999),  40(2),  466-467.  CODEN: A

PAT46
Organophilic phyllosilicates for filling polymeric materials.    
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Ciba Specialty Chemicals Holding Inc., Switz.).    PCT
Int. Appl.  (1999),     59 pp.  WO  9942518  A2  19990826  DPriority: CH  98-408  19980220.  CAN
131:171089    AN 1999:549317   

Synthesis of highly branched polyethylene graft copolymers by combination of palladium
diazadiene catalyzed and TEMPO-mediated polymerization.    
Mulhaupt, Rolf; Baumert, Martin; Heinemann, Johannes; Thomann, Ralf.    Book of Abstracts, 218th
ACS National Meeting, New Orleans, Aug. 22-26  (1999),     POLY-519.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 67ZJA5  Conference; Meeting Abstract  written in
English.   

Transition-metal-catalyzed ethene homo- and copolymerization in the presence of exfoliated
organophilic layered silicates and polyolefin nanocomposite formation.    
Mulhaupt, Rolf; Heinemann, Johannes; Reichert, Peter; Thomann, Ralf.     Book of Abstracts, 218th
ACS National Meeting, New Orleans, Aug. 22-26  (1999),     POLY-180.  Publisher: American
Chemical Society,  Washington,

Influence of -alkyl branches on thermal properties of polyethylenes prepared by means of
metallocene- and palladium-based catalysts.    
Mulhaupt, Rolf; Mader, Dietmar; Walter, Philipp; Heinemann, Johannes.    Book of Abstracts, 218th
ACS National Meeting, New Orleans, Aug. 22-26  (1999),     POLY-124.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 67ZJA5  Conference; Meeting Abstract  written in
English.   

[167] Synthesis and characterization of polyesteramides derived from an oxazoline-functional
alcohol and dicarboxylic acid anhydrides.    
Bruch, Matthias; Burgath, Armin; Loontjens, Ton; Mulhaupt, Rolf.    Journal of Polymer Science, Part
A: Polymer Chemistry  (1999),  37(16),  3367-3376. 

[166] Polyolefin nanocomposites formed by melt compounding and transition metal-catalyzed
ethene homo- and copolymerization in the presence of layered silicates.    
Heinemann, Johannes; Reichert, Peter; Thomann, Ralf; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (1999),  20(8),  423-430. 

PAT45
Preparation of heterocyclic group-functionalized azo compounds as radical polymerization
initiators.    
Muelhaupt, Rolf; Baumert, Martin; Gepraegs, Michael.  (BASF A.-G., Germany).    Ger. Offen.  (1999),    
16 pp.  DE  19802335  A1  19990729  Patent  written in German.    Application: DE  98-19802335 
19980123.  CAN 131:144593   

[165] Impact-modified poly(styrene-co-acrylonitrile) blends containing both oxazoline-
functionalized poly(ethene-co-1-octene) elastomers and poly(styrene-co-maleic anhydride) as
compatibilizer.     Mader, Dietmar; Kressler, Jorg; Mulhaupt, Rolf.    Journal of Applied Polymer
Science  (1999),  73(9),  1685-1695.  C

Moving forces for new technologies. Polymers for the 21st Century.    
Mulhaupt, Rolf.   Plastverarbeiter  (1999),  50(5),  68-70,72,74,76,79-80,82,84,86.

[164] Controlled Synthesis of Hyperbranched Polyglycerols by Ring-Opening Multibranching
Polymerization.    
Sunder, Alexander; Hanselmann, Ralf; Frey, Holger; Muelhaupt, Rolf.    Macromolecules  (1999), 
32(13),  4240-4246. 

[163] Silsesquioxane-Based Amphiphiles.    
Knischka, Ralf; Dietsche, Frank; Hanselmann, Ralf; Frey, Holger; Muelhaupt, Rolf; Lutz, Pierre J.   
Langmuir  (1999),  15(14),  4752-4756. 

PAT44
Method for nucleation of crystallizable polymers.    
Roesch, Joachim; Muelhaupt, Rolf; Bauer, Thorsten.  (BASF A.-G., Germany).    Ger. Offen.  (1999),    
12 pp.  C DE  19750371  A1  19990520  Patent  written in German.    Application: DE  97-19750371 
19971114.  CAN 131:6018  

[162] Styrene-vinylferrocene random and block copolymers by TEMPO-mediated radical
polymerization.    
Baumert, Martin; Frohlich, Jorg; Stieger, Markus; Frey, Holger; Mulhaupt, Rolf; Plenio, Herbert.   
IMacromolecular Rapid Communications  (1999),  20(4),  203-209. 

Hermann Staudinger and the development of macromolecular chemistry.    
Mulhaupt, Rolf.    Freiburg/Br.,  Germany.    Nachrichten aus Chemie, Technik und Laboratorium 
(1999),  47(4),  413-414,416-418. 

Nucleation of metallocene polypropylene (mPP).    
Maier, Ralph-Dieter; Friedrich, Christian; Mulhaupt, Rolf.    Kunststoffe  (1999),  89(4),  89-90,92-94. 

A versatile route to hyperbranched polyglycerols and new branched polymer architectures.    
Sunder, A.; Frey, H.; Mulhaupt, R..    Polymeric Materials Science and Engineering  (1999),  80  203-
204. 

[161] Synthesis of Oxazoline-Terminated Polystyrene via Controlled-Radical Polymerization.    
Baumert, Martin; Zimmermann, Joerg; Scherble, Jonas; Muelhaupt, Rolf; Kressler, Joerg.   
Macromolecules  (1999),  32(8),  2503-2510. 

PAT43
Thermoplastic molding compositions based on polyesters and polycarbonates.    
Weber, Martin; Muelhaupt, Rolf.  (BASF A.-G., Germany).    Ger. Offen.  (1999),     16 pp.  DE 
19739686  A1  19990311 Application: DE  97-19739686  19970910.  CAN 130:238266   

[160] Morphology and toughness/stiffness balance of nanocomposites based upon anhydride-
cured epoxy resins and layered silicates.   
Zilg, Carsten; Muelhaupt, Rolf; Finter, Juergen.    Macromolecular Chemistry and Physics  (1999), 
200(3),  661-670.  CODEN:

[159] Monomers for low shrinking composites. Part 2. Synthesis of branched methacrylates
and their application in dental composites.   
Klee, Joachim E.; Neidhart, Frank; Flammersheim, Hans-Juergen; Muelhaupt, Rolf.    Macromolecular
Chemistry and Physics  (1999),  200(3),  517-523. 

[158] Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and
Tapping Mode Atomic Force Microscopy of Film Formation.    
Linemann, Reinhard F.; Malner, Thomas E.; Brandsch, Rainer; Bar, Georg; Ritter, Wolfgang;
Muelhaupt, Rolf.    Macromolecules  (1999),  32(6),  1715-1721. 

[157] Copolymerization of ethene with methyl acrylate and ethyl 10-undecenoate using a
cationic palladium diimine catalyst.    
Heinemann, Johannes; Muelhaupt, Rolf; Brinkmann, Peter; Luinstra, Gerrit.    Macromolecular
Chemistry and Physics  (1999),  200(2),  384-389.  C

A versatile route to hyperbranched polyglycerols and new branched polymer architectures.    
Sunder, A.; Frey, H.; Mulhaupt, R..    F Book of Abstracts, 217th ACS National Meeting, Anaheim,
Calif., March 21-25  (1999),     PMSE-234.  Publisher: American Chemical Society,  Washington, D. C 
CODEN: 67GHA6  Conference; Meeting Abstract  written in English.   

[156] Glass Transition Temperature Depression of Elastomers Blended with Poly(propene)s of
Different Stereoregularities.    
Maeder, Dietmar; Bruch, Matthias; Maier, Ralph-Dieter; Stricker, Florian; Muelhaupt, Rolf.   
Macromolecules  (1999),  32(4),  1252-1259. 

[155] Addition-fragmentation free radical polymerization in the presence of olefinic dithioethers
as chain transfer agents.    
Sunder, Alexander; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1999),  200(1),  58-
64. 

PAT42
Monodisperse dilatant polymer dispersions and their preparation.    
Rupaner, Robert; Horn, Frank M.; Richtering, Walter; Muelhaupt, Rolf.  (BASF A.-G., Germany).   
Ger. Offen.  (1999),     8 pp.  DE  19757669  A1  19990107  Application: DE  97-19757669  19971223. 
CAN 130:111035   

[154] Polyurethane nanocomposites containing laminated anisotropic nanoparticles derived
from organophilic layered silicates.    
Zilg, Carsten; Thomann, Ralf; Muelhaupt, Rolf; Finter, Juergen.    Advanced Materials (Weinheim,
Germany)  (1999),  11(1),  49-52.  CODEN: ADVMEW  ISSN: 0935-9648.  J

[153] Acid-sensitive polyethylene glycol conjugates of doxorubicin: preparation, in vitro
efficacy and intracellular distribution.   
Rodrigues P C; Beyer U; Schumacher P; Roth T; Fiebig H H; Unger C; Messori L; Orioli P; Paper D H;
Mulhaupt R; Kratz F    TBioorganic & medicinal chemistry  (1999 Nov),  7(11),  2517-24. 

[152] Combined ultramicrotomy for AFM and TEM using a novel sample holder.    
Thomann Y; Thomann R; Bar G; Ganter M; MacHutta B; Mulhaupt R    Journal of microscopy  (1999
Aug),  195 ( Pt 2) 161-3.

 

1998


[151] Influence of glass bead fillers on phase transitions of syndiotactic polypropene.    
Stricker, F.; Maier, R.-D.; Bruch, M.; Thomann, R.; Mulhaupt, R..    Polymer  (1998),  Volume Date
1999,  40(8),  2077-2084. 

[151] Ni(II) and Pd(II) complexes of camphor-derived diazadiene ligands: steric bulk tuning and
ethylene polymerization.   
 Schleis, Thomas; Heinemann, Johannes; Spaniol, Thomas P.; Mulhaupt, Rolf; Okuda, Jun.  
Inorganic Chemistry Communications  (1998),  1(11),  431-434. 

[150] Branched macromonomers and their application in dental composites. Monomers for
low-shrinking composites. Part 3.    
Klee, Joachim E.; Walz, Uwe; Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf.    Angewandte
Makromolekulare Chemie  (1998),  260  71-75. 

Polymer and rubber nanocomposites based upon layered silicates.    
Zilg, Carsten; Reichert, Peter; Dietsche, Frank; Engelhardt, Thomas; Muelhaupt, Rolf.    Kunststoffe 
(1998),  88(10),  1812-1813,1916,1818,1820.  C

[149] Influence of morphology on the toughening mechanisms of polypropylene modified with
core-shell particles derived from thermoplastic elastomers.   
Kim, G. M.; Michler, G. H.; Gahleitner, M.; Mulhaupt, R..    Polymers for Advanced Technologies 
(1998),  9(10-11),  709-715.  CODEN: PADTE5  ISSN: 1042-7147. 

Determination of plateau moduli and entanglement molecular weights of polypropylenes of
different tacticity.   
Friedrich, Chr.; Eckstein, A.; Suhm, J.; Maier, R.-D.; Sassmannshausen, J.; Bochmann, M.; Mulhaupt,
R..    Editor(s): Emri, I.    Progress and Trends in Rheology V, Proceedings of the European Rheology
Conference, 5th, Portoroz, Slovenia, Sept. 6-11, 1998  (1998),     387.  Publisher: Steinkopff, 
Darmstadt, Germany  CODEN: 66TJA2  Conference  written in English.  

[148] Modification of epoxy resin with alpha,omega-oligo(butyl methacrylate)diols.    
Schroder, N.; Konczol, L.; Doll, W.; Mulhaupt, R..    Journal of Applied Polymer Science  (1998), 
70(4),  785-796.  CODEN: JAPNAB  ISSN: 0021-8995.  Journal  written in English.   

Comparison of isotactic and syndiotactic polypropylene as matrix materials of hybrid
composites.    
Stricker, F.; Mulhaupt, R..    Polymer Engineering and Science  (1998),  38(9),  1463-1470. 

[147]Two-Component Gelators and Nucleating Agents for Polypropylene Based upon
Supramolecular Assembly.    
Bauer, Thorsten; Thomann, Ralf; Muelhaupt, Rolf.   Macromolecules  (1998),  31(22),  7651-7658. 

PAT41
Low shrinking polymerizable dental material.    
Klee, Joachim E.; Walz, Uwe; Holter, Dirk; Burgath, Armin; Frey, Holger; Mulhaupt, Rolf.  (Dentsply
International Inc., USA).    PCT Int. Appl.  (1998),     20 pp.  WO  9836729  A2  19980827  DePriority:
US  97-38812  19970221; US  97-960955  19971030.  CAN 129:221217    A

[146] Hyperbranched carbosilane oxazoline-macromonomers. Polymerization and coupling to a
trimesic acid core.    
Lach, Christian; Hanselmann, Holger; Muelhaupt, Rolf.    Macromolecular Rapid Communications 
(1998),  19(9),  461-465.  CODEN: MRCOE3  ISSN: 1022-1336. 

[145] Ethylene polymerization catalysts based on nickel(II) 1,4-diazadiene complexes: the
influence of the 1,4-diazadiene backbone substituents on structure and reactivity.    
Schleis, Thomas; Spaniol, Thomas P.; Okuda, Jun; Heinemann, Johannes; Mulhaupt, Rolf.  
Germany.    Journal of Organometallic Chemistry  (1998),  569(1-2),  159-167.

[144] Influence of morphology on rheological and mechanical properties of SEBS-toughened,
glass-bead-filled isotactic polypropene.    
Stricker, F.; Friedrich, C.; Mulhaupt, R..    Journal of Applied Polymer Science  (1998),  69(12),  2499-
2506. 

Micromechanical deformation processes in PA12-layered silicate nanocomposite.    
Kim, G.-M.; Michler, G. H.; Reichert, P.; Kressler, J.; Mulhaupt, R..    Polymeric Materials Science and
Engineering  (1998),  79  178-179. 

Synthesis and characterization of oxazoline-terminated polymers via controlled radical
polymerization as intermediates for reactive processing.    
Baumert, Martin; Zimmermann, Jorg; Mulhaupt, Rolf.    Polymeric Materials Science and Engineering 
(1998),  79  5-6.

[143] Ambient-temperature liquid-crystalline bismethacrylates based on cholesterol.
Cholesteric and smectic thermosets.   
 Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.    Advanced Materials  (1998),  10(11), 
864-868. 

Synthesis, characterization and film formation of fluorine-containing polyacrylate dispersions
and their blends.    
Linemann, R.; Malner, T.; Brandsch, R.; Bar, G.; Mulhaupt, R..    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (1998),  39(2),  966-967.  CODEN: ACPPAY  ISSN:
0032-3934.  Journal  written in English.    CAN 129:261198   

Film formation study of fluorine-containing dispersions by atomic-force microscopy.    
Linemann, R.; Malner, T.; Brandsch, R.; Bar, G.; Mulhaupt, R..     Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (1998),  39(2),  952-953.  C

Film formation study of fluorine-containing dispersions by atomic-force and environmental
scanning electron microscopy.   
Brandsch, R.; Linemann, R.; Malner, T.; Bar, G.; Muelhaupt, R..   Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     POLY-512.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.   

Synthesis, characterization and film formation of fluorine-containing polyacrylate dispersions
and their blends.    
Bar, G.; Linemann, R.; Malner, T.; Brandsch, R.; Muelhaupt, R..    Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     POLY-466.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.    AN
1998:528177   

Micromechanical deformation processes in PA 12-layered silicate nanocomposite.    
Kim, G. -M.; Michler, G. H.; Reichert, P.; Kressler, J.; Muelhaupt, R..    Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     PMSE-092.  Publisher: American Chemical
Society,  Washington, D. C  C

Synthesis and characterization of oxazoline-terminated polymers via controlled radical
polymerization as intermediates for reactive processing.    
Baumert, Martin; Zimmermann, Joerg; Muelhaupt, Rolf.    Book of Abstracts, 216th ACS National
Meeting, Boston, August 23-27  (1998),     PMSE-003.  Publisher: American Chemical Society, 
Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.    AN
1998:526944  

Nanostructure formation via supramolecular assembly of tectonics in a polymer matrix.    
Bauer, Thorsten; Muelhaupt, Rolf.    Book of Abstracts, 216th ACS National Meeting, Boston, August
23-27  (1998),     MACR-042.  Publisher: American Chemical Society,  Washington, D. C 

Polyurethane nanocomposites prepared from novel silsesquioxane polyols.    
Dietsche, Frank; Muelhaupt, Rolf.    Book of Abstracts, 216th ACS National Meeting, Boston, August
23-27  (1998),     MACR-041.  Publisher: American Chemical Society,  Washington, D. C  CODEN:
66KYA2  Conference; Meeting Abstract  written in English.   

Nonionic silsesquioxane based amphiphiles.    
Knischka, Ralf; Dietsche, Frank; Muelhaupt, Rolf; Frey, Holger.      Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     COLL-123.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.    A

[142] Investigation of Morphologies of One- and Two-Phase Blends of Isotactic Poly(propene)
with Random Poly(ethene-co-1-butene).    
Thomann, Y.; Suhm, J.; Thomann, R.; Bar, G.; Maier, R.-D.; Muelhaupt, R..   Macromolecules  (1998), 
31(16),  5441-5449.  CODEN: MAMOBX  ISSN: 0024-9297.

[141] Comparison of N,N'-bidentate ligands in copper-catalyzed atom-transfer polymerization of
styrene.    
DiRenzo, Geraldine M.; Messerschmidt, Martin; Muelhaupt, Rolf.    Macromolecular Rapid
Communications  (1998),  19(7),  381-384.

[140] Propene polymerization with rac-Me2Si(2-methylbenz[e]ind)2ZrX2 [X = Cl, Me] using
different cation-generating reagents.    
Beck, Stefan; Brintzinger, H. H.; Suhm, Juergen; Muelhaupt, Rolf.    Macromolecular Rapid
Communications  (1998),  19(5),  235-239. 

[139] Synthesis and properties of polyaramides and poly(amide-imide)s containing 5,10-
dihydrophenazine units.    
Mikulla, Markus; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1998),  199(5),  795-
805. 

PAT40
Preparation of membrane-electrode units for polymer electrolyte fuel cells.    
Ledjeff-Hey, Konstantin; Nolte, Roland; Zerfass, Torsten; Frey, Holger; Muelhaupt, Rolf.  (Fraunhofer-
Gesellschaft zur Foerderung der angewandten Forschung e.V., Germany).    Ger. Offen.  (1998),     14
pp.  DE  19653484  A1  19980625  Application: DE  96-19653484  19961220.  CAN 129:97744   


[138] Fracture behavior of polypropylene/glass bead elastomer composites by using the
essential work-of-fracture method.    
Mouzakis, D. E.; Stricker, F.; Mulhaupt, R.; Karger-Kocsis, J.    Journal of Materials Science  (1998), 
33(10),  2551-2562. 

[137] Rubber-toughened cycloolefin copolymers.    
Stricker, Florian; Muelhaupt, Rolf.   Angewandte Makromolekulare Chemie  (1998),  256  101-104. 

[136] The influence of metallocene-based LLDPE on polypropene compounds in the presence
of SEBS and talcum.    
Stricker, Florian; Maier, Ralph-Dieter; Muelhaupt, Rolf.    Angewandte Makromolekulare Chemie 
(1998),  256  95-99. 

[135] Influence of rubber particle size on mechanical properties of polypropylene-SEBS blends.
Stricker, F.; Thomann, Y.; Mulhaupt, R..    Journal of Applied Polymer Science  (1998),  68(12),  1891-
1901. 

m-PP blends. Processing and properties of blends based on m-PP and ethylene copolymers.    
Stricker, Florian; Maier, Ralph Dieter; Thomann, Yi; Muelhaupt, Rolf.    Kunststoffe  (1998),  88(4), 
527-530.

Novel polyolefin materials via catalysis and reactive processing.    
Suhm, Juergen; Heinemann, Johannes; Woerner, Christof; Mueller, Philipp; Stricker, Florian; Kressler,
Joerg; Okuda, Jun; Muelhaupt, Rolf.    Macromolecular Symposia  (1998),  129(Modified Polyolefins
for Advanced Polymeric Materials),  1-28. 

[134] Influence of metallocene structures on ethene copolymerization with 1-butene and 1-
octene.
Suhm, J.; Schneider, M. J.; Mulhaupt, R..    Journal of Molecular Catalysis A: Chemical  (1998), 
128(1-3),  215-227. 

[133] New molecular and supermolecular polymer architectures via transition metal catalyzed
alkene polymerization.    
Suhm, Jurgen; Heinemann, Johannes; Thomann, Yi; Thomann, Ralf; Maier, Ralph-dieter; Schleis,
Thomas; Okuda, Jun; Kressler, Jorg; Mulhaupt, Rolf.    Journal of Materials Chemistry  (1998),  8(3), 
553-563.  C

[132] Crystallization of syndiotactic poly(propene-co-octene).    
Thomann, Ralf; Kressler, Jorg; Mulhaupt, R..      Polymer  (1998),  39(10),  1907-1915.  C

[131] Vapor-induced crystallization of syndiotactic random copolymers of styrene with 4-n-
butylstyrene.    
Thomann, Ralf; Thomann, Yi; Sernetz, Friedrich G.; Muelhaupt, Rolf; Kressler, Joerg.    Polymer
Bulletin (Berlin)  (1998),  40(2-3),  313-319. 

[130] Nanocomposites based on a synthetic layer silicate and polyamide-12.    
Reichert, P.; Kressler, J.; Thomann, R.; Muelhaupt, R.; Stoeppelmann, G.    Acta Polymerica  (1998), 
49(2-3),  116-123. 

[129] Micromechanical deformation processes in toughened PP/PA/SEBS-g-MA blends
prepared by reactive processing.    
Kim, G. M.; Michler, G. H.; Roesch, J.; Muelhaupt, R..    IActa Polymerica  (1998),  49(2-3),  88-95. 
CODEN: ACPODY  I

[128] Microstructure and pressure-volume-temperature properties of ethene/1-octene random
copolymers.    
Suhm, J.; Maier, R. D.; Kressler, J.; Muelhaupt, R..    Acta Polymerica  (1998),  49(2-3),  80-87. 

Oxazoline compounds for thermoplastic polymers stabilized against heat, oxidation, and light.    
Steinmann, Alfred; Mulhaupt, Rolf.  (Ciba Specialty Chemicals Holding Inc., Switz.).    Eur. Pat. Appl. 
(1998),     52 pp.  EP  816346  A1  19980107  Application: EP  97-810391  19970619.  Priority: CH 
96-1631  19960628.  CAN 128:128745    AN 1998:116089   

[127] Determination of Plateau Moduli and Entanglement Molecular Weights of Isotactic,
Syndiotactic, and Atactic Polypropylenes Synthesized with Metallocene Catalysts.    
Eckstein, A.; Suhm, J.; Friedrich, C.; Maier, R.-D.; Sassmannshausen, J.; Bochmann, M.; Muelhaupt,
R..    Macromolecules  (1998),  31(4),  1335-1340. 

[126] Studies on reactions of oxazoline functionalized polymer particles.    
Schafer, Rudiger; Holderle, Matthias; Mulhaupt, Rolf.    Polymer  (1998),  39(6-7),  1259-1268. 
CODEN: POLMAG  ISSN: 0032-3861.  Journal  written in English.    C

[125] 1,3-Oxazoline intermediates in reactive processing applications: 3. Bis (1,3-oxazolin-2-yl)-
terminated oligotetrahydrofuran liquid rubbers and preparation of the corresponding
segmented copolyether ester amides.    
Worner, Christof; Muller, Philipp; Mulhaupt, Rolf.    I   Polymer  (1998),  39(3),  611-620.  CODEN:

[124] Synthesis of two maleimide derivatives of cis-configurated platinum(II) complexes for the
preparation of chemoimmunoconjugates.    
Schutte, Mark Thomas; Schumacher, Peter; Unger, Clemens; Mulhaupt, Rolf; Kratz, Felix.       
Inorganica Chimica Acta  (1998),  267(1),  133-136. 

 

1997


[123]Synthesis and Crystallization of Syndiotactic Random Copolymers of Styrene and p-n-
Butylstyrene and of Syndiotactic Poly(p-n-butylstyrene).    
Thomann, Ralf; Sernetz, Friedrich G.; Heinemann, Johannes; Steinmann, Sandra; Muelhaupt, Rolf;
Kressler, Joerg.    Macromolecules  (1997),  30(26),  8401-8409. 

[122] Fuzzy set approach for fitting a continuous response surface in adhesion formulation.    
Setz, Stefan; Semling, Marcus; Mulhaupt, Rolf.    Journal of Chemometrics  (1997),  11(5),  403-418. 

[121] Carbosilane Dendrimers with Perfluoroalkyl End Groups. Core-Shell Macromolecules with
Generation-Dependent Order.    
Lorenz, Klaus; Frey, Holger; Stuehn, Bernd; Muelhaupt, Rolf.    Macromolecules  (1997),  30(22), 
6860-6868. 

[120] Toughened poly(butylene terephthalate)s and blends prepared by simultaneous chain
extension, interfacial coupling, and dynamic vulcanization using oxazoline intermediates.    
Worner, Christof; Muller, Philipp; Mulhaupt, Rolf.    Journal of Applied Polymer Science  (1997),  66(4), 
633-642.  CODEN:

[119] Mechanical and thermal properties of syndiotactic polypropene filled with glass beads
and talcum.    
Stricker, F.; Bruch, M.; Mulhaupt, R..    Polymer  (1997),  38(21),  5347-5353.  CODEN: POLMAG 
ISSN: 0032-3861. 

[118] Carboxy-terminated homo- and copolymers of styrene using dicarboxylic acid-functional
azo initiator and 2,2,6,6-tetramethyl-1-piperidyloxyl (TEMPO).    
Baumert, Martin; Mulhaupt, Rolf. Macromolecular Rapid Communications  (1997),  18(9),  787-794. 

[117] Synthesis of fluorine-containing dispersions and an environmental scanning electron
microscope analysis of their morphology when applied to cotton fabrics.    
Linemann, Reinhard; Gorenberg, Arkadii; Bar, Georg; Cantow, Hans-Joachim; Mulhaupt, Rolf.   
Journal of Coatings Technology  (1997),  69(871),  77-81. 

[116] Nine-Membered Titanacyclic Complexes Based on an Ethylene-Bridged Bis(phenolato)
Ligand: Synthesis, Structure, and Olefin Polymerization Activity.    
Fokken, Stefan; Spaniol, Thomas P.; Okuda, Jun; Sernetz, Fritz G.; Muelhaupt, Rolf.   
Organometallics  (1997),  16(20),  4240-4242. 

PAT39
Manufacture of polymers containing oxazine groups.    
Weber, Martin; Muelhaupt, Rolf; Kressler, Joerg; Mueller, Philipp; Schaefer, Ruediger.  (BASF A.-G.,
Germany).    Eur. Pat. Appl.  (1997),     9 pp.  EP  791606  A2  19970827  CAN 127:221177  

PAT38
Alkylalkoxysilyl-1,3-oxazolines, and their use.    
Muenzenberg, Joerg; Muelhaupt, Rolf; Mueller, Philipp.  (Degussa Aktiengesellschaft, Germany).   
Eur. Pat. Appl.  (1997),     13 pp.  EP  791598  A2  19970827  Designated States R: BE, DE, FR, GB,
IT.  Patent  written in German.    Application: EP  97-102559  19970218.  Priority: DE  96-19606413 
19960221.  CAN 127:251949   

Progress in controlled polymerization and design of novel polymer architectures.    
Baumert, Martin; Frey, Holger; Holderle, Matthias; Kressler, Jorg; Sernetz, Friedrich G.; Mulhaupt,
Rolf.   Macromolecular Symposia  (1997),  121  53-74.

Hyperbranched polyallyisilanes bearing oxazoline groups as versatile building blocks for new
polymer architectures.    
Lach, Christian; Frey, Holger; Mulhaupt, Rolf.    Polymeric Materials Science and Engineering  (1997), 
77  199.  CODEN: PMSEDG  ISSN: 0743-0515.  Journal  written in English.    CAN 127:234651   

Branched bismethacrylates based on bis-GMA - a systematic route to low shrinkage
composites.    
Holter, Dirk; Frey, Holger; Mulhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division
of Polymer Chemistry)  (1997),  38(2),  84-85. 

[115] Metallocene-catalyzed ethene/styrene co- and terpolymerization with olefinic
termonomers.     Sernetz, Friedrich G.; Mulhaupt, Rolf.   Journal of Polymer Science, Part A: Polymer
Chemistry  (1997),  35(13),  2549-2560.

[114] Synthesis and characterization of oxazoline-functional polymer particles by free radical
nonaqueous dispersion polymerization.    
Holderle, Matthias; Bar, Georg; Mulhaupt, Rolf.    Journal of Polymer Science, Part A: Polymer
Chemistry  (1997),  35(13),  2539-2548. 

[113] Polyester networks based upon epoxidized and maleated natural oils.    
Warth, Holger; Mulhaupt, Rolf; Hoffmann, Botho; Lawson, Sonya.   Angewandte Makromolekulare
Chemie  (1997),  249  79-92.  CODEN: ANMCBO  ISSN: 0003-3146. 

[112] Gas transport properties of soluble poly(phenylene sulfone imides).    
Xu, Z.-K.; Bohning, M.; Springer, J.; Glatz, F. P.; Mulhaupt, R..    Journal of Polymer Science, Part B:
Polymer Physics  (1997),  35(12),  1855-1868.  C

Branched bismethacrylates based on Bis-GMA - a systematic route to low shrinkage
composites.    
Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.    Book of Abstracts, 214th ACS
National Meeting, Las Vegas, NV, September 7-11  (1997),     POLY-009.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 64RNAO  Conference; Meeting Abstract  written in
English.    AN 1997:489151   

Hyperbranched polyallylsilanes bearing oxazoline groups as versatile building blocks for new
polymer architectures.    
Lach, Christian; Frey, Holger; Muelhaupt, Rolf.    Book of Abstracts, 214th ACS National Meeting, Las
Vegas, NV, September 7-11  (1997),     PMSE-224.  Publisher: American Chemical Society, 
Washington, D.

[111] Morphology and phase behavior of poly(methyl methacrylate)/poly(styrene-co-
acrylonitrile) blends monitored by FTIR microscopy.    
Schafer, Rudiger; Zimmermann, Jorg; Kressler, Jorg; Mulhaupt, Rolf.    Inst. Makromol. Chem.
Frieburger Materialforschungszentrum, Polymer  (1997),  38(15),  3745-3752.  CAN 127:82048   

[110] The interfacial reaction of modified poly(arylether sulfone)s and polyaramides.    
Mader, Dietmar; Coen, Martine Collaud; Kressler, Jorg; Mulhaupt, Rolf; Weber, Martin.   Journal of
Applied Polymer Science  (1997),  65(3),  567-579. 

[109] Viscoelastic properties of poly(ethylene-co-styrene) copolymers.    
Lobbrecht, A.; Friedrich, Chr.; Sernetz, F. G.; Mulhaupt, R..    Journal of Applied Polymer Science 
(1997),  65(2),  209-215. 

[108] Thermal Properties of the Homologous Series of 8-fold Alkyl-Substituted
Octasilsesquioxanes
Bolln, Carsten; Tsuchida, Akira; Frey, Holger; Muelhaupt, Rolf, Chemistry of Materials  (1997),  9(6), 
1475-1479. 

[107] Liquid crystalline acrylates or ?-substituted acrylates, curable dental compositions
containing these compounds, and methods for using these compositions.    
Klee, Joachem E.; Frey, Holger; Holter, Dirk; Mulhaupt, Rolf.  (Dentsply International, Inc., USA).   
PCT Int. Appl.  (1997),     60 pp.  WO  9714674  A1  19970424  Priority: US  95-543950  19951017;
US  96-723443  19961007.  CAN 126:344209  

[106] Aminofunctional linear low density polyethylene via metallocene-catalyzed ethene
copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene.    
Schneider, Martin Julius; Schafer, Rudiger; Mulhaupt, Rolf.    Polymer  (1997),  38(10),  2455-2459. 

PAT37
Preparation of functionalized copoly-m-phenylenes as solid electrolytes.    
Muelhaupt, Rolf; Frey, Holger; Zerfass, Torsten; Ledjeff-Hey, Konstantin; Nolte, Roland.  (Fraunhofer-
Gesellschaft zur Foerderung der Angewandten Forschung e.V., Germany).    Ger. Offen.  (1997),     14
pp.  DE  19535086  A1  19970327  Patent  written in German.    Application: DE  95-19535086 
19950921.  CAN 126:294405   

[105] Influence of Indenyl Ligand Substitution Pattern on Metallocene-Catalyzed Ethene
Copolymerization with 1-Octene.    
Schneider, Martin Julius; Suhm, Juergen; Muelhaupt, Rolf; Prosenc, Marc-Heinrich; Brintzinger, Hans-
Herbert.    Macromolecules  (1997),  30(11),  3164-3168. 

[104] Comparison of controlled radical styrene polymerizations in bulk and nonaqueous
dispersion.
Hoelderle, Matthias; Baumert, Martin; Muelhaupt, Rolf.    Macromolecules  (1997),  30(11),  3420-
3422. 

Trends in polymer chemistry 1996.     Frey, H.; Kressler, J.; Richtering, W.; Mulhaupt, R..   Acta
Polymerica  (1997),  48(4),  107-115.  C

[103] Ethene and Propene Copolymers Containing Silsesquioxane Side Groups.    
Tsuchida, Akira; Bolln, Carsten; Sernetz, Friedrich G.; Frey, Holger; Muelhaupt, Rolf.   
Macromolecules  (1997),  30(10),  2818-2824. 

[102] Copolymerization of ethene with styrene using different methylalumoxane activated half-
sandwich complexes.    
Sernetz, Friedrich G.; Mulhaupt, Rolf; Amor, Francisco; Eberle, Thomas; Okuda, Jun.   Journal of
Polymer Science, Part A: Polymer Chemistry  (1997),  35(8),  1571-1578. 

[101] The influence of stereoregularity on the miscibility of poly(propylene)s.    
Maier, Ralph-Dieter; Thomann, Ralf; Kressler, Jorg; Mulhaupt, Rolf; Rudolf, Bernd.    Journal of
Polymer Science, Part B: Polymer Physics  (1997),  35(7),  1135-1144. 

[100] Single crystals of syndiotactic poly[propene-co-(1-octene)] and syndiotactic polypropene
crystallized in bulk.    
Thomann, Ralf; Kressler, Jorg; Mulhaupt, Rolf.    Macromolecular Chemistry and Physics  (1997), 
198(4),  1271-1279. 

[99] Influence of indenyl ligand substitution pattern on metallocene-catalyzed propene
copolymerization with 1-octene.    
Schneider, Martin Julius; Mulhaupt, Rolf.    Macromolecular Chemistry and Physics  (1997),  198(4), 
1121-1129. 

Organosilicon 1,3-oxazolines: reactive silicone liquid rubbers and silane coupling agents
tailored for reactive processing application and nanocomposite formation.    
Mueller, Philipp; Woerner, Christof; Schaefer, Ruediger; Muelhaupt, Rolf.   Polymeric Materials
Science and Engineering  (1997),  76  51-52. 

Polymer nanoparticles with new architectures prepared via non-aqueous dispersion
copolymerization of oxazoline-functional methacrylates.    
Holderle, Matthias; Bruch, Matthias; Schaefer, Ruediger; Muelhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1997),  38(1),  479-480. 

[98] Gas transport properties of poly (phenylene thioether imide)s.    
Xu, Z.-K.; Boehning, M.; Schultze, J. D.; Li, G.-T.; Springer, J.; Glatz, F. P.; Muelhaupt, R..   Polymer 
(1997),  38(7),  1573-1580.  C

[97] Thermoplastic cellulose acetate and cellulose acetate compounds prepared by reactive
processing.    
Warth, Holger; Mulhaupt, Rolf; Schatzle, Joachim.    Journal of Applied Polymer Science  (1997), 
64(2),  231-242.  CODEN:

PAT36
2-Oxazolinyl group-terminated polymers and oligomers for use as compatibilizers.    
Roesch, Joachim; Mueller, Hans-Joachim; Hoehn, Arthur; Muelhaupt, Rolf; Woerner, Christof.  (BASF
A.-G., Germany).    Eur. Pat. Appl.  (1997),     10 pp.   EP  757062  A2  19970205  Application: EP  96-
111813  19960723.  Priority: DE  95-19528192  19950801.  CAN 126:199964   

[96] Hyperbranched polycarbosilane macromonomers bearing oxazoline functionalities.    
Lach, Christian; Muller, Philipp; Frey, Holger; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (1997),  18(3),  253-260.  C

[95] Temperature rising elution fractionation of a random ethene/styrene copolymer.    
Thomann, Yi; Sernetz, Friedrich G.; Thomann, Ralf; Kressler, Jorg; Mulhaupt, Rolf.    Macromolecular
Chemistry and Physics  (1997),  198(3),  739-748. 

[94]Copolymerization of Ethene with Styrene Using Methylaluminoxane-Activated
Bis(phenolate) Complexes.    
Sernetz, Friedrich G.; Muelhaupt, Rolf; Fokken, Stefan; Okuda, Jun.    Macromolecules  (1997),  30(6), 
1562-1569.

[93] Temperature dependence of copolymerization parameters in ethene/1-octene
copolymerization using homogeneous rac-Me2Si(2-MeBenz[e]Ind)2ZrCl2/MAO catalyst.    
Suhm, J.; Schneider, M. J.; Muelhaupt, R..   Journal of Polymer Science, Part A: Polymer Chemistry 
(1997),  35(4),  735-740.  C

Polymer nanoparticles with new architectures prepared via non-aqueous dispersion
copolymerization of oxazoline-functional methacrylates.    
Hoelderle, Matthias; Bruch, Matthias; Schaefer, Ruediger; Muelhaupt, Rolf.    Book of Abstracts, 213th
ACS National Meeting, San Francisco, April 13-17  (1997),     POLY-206.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 64AOAA  Conference; Meeting Abstract  written in
English.    AN 1997:164131   

Organosilicon 1,3-oxazolines: Reactive silicone liquid rubbers and silane coupling agents
tailored for reactive processing application and nanocomposite formation.    
Mueller, P.; Woerner, C.; Schaefer, R.; Muelhaupt, R..    Book of Abstracts, 213th ACS National
Meeting, San Francisco, April 13-17  (1997),     PMSE-031.  Publisher: American Chemical Society, 
Washington, D.

[92] Comparison of the viscoelastic properties of syndio- and isotactic polypropylenes.    
Eckstein, A.; Friedrich, C.; Lobbrecht, A.; Spitz, R.; Muelhaupt, R..   Acta Polymerica  (1997),  48(1/2), 
41-46.  CODEN: ACPODY  ISSN: 0323-7648. 

[91] Gas transport properties of highly fluorinated polyamideimides.    
Xu, Z.-K.; Boehning, M.; Springer, J.; Steinhauser, N.; Muelhaupt, R..    Polymer  (1997),  38(3),  581-
588.  CODEN:

[90] Homo-, co-, and terpolymerization of 1,5-hexadiene using a methyl aluminoxane-activated
mono-Cp-amido-complex.    
Sernetz, F. G.; Muelhaupt, R.; Waymouth, R. M.    Polymer Bulletin (Berlin)  (1997),  38(2),  141-148. 

[89] Propene homo- and copolymerization using homogeneous and supported metallocene
catalysts based on Me2Si(2-Me-Benz[e]Ind)2ZrCl2.    
Juengling, Stephan; Koltzenburg, Sebastian; Muelhaupt, Rolf.   Journal of Polymer Science, Part A:
Polymer Chemistry  (1997),  35(1),  1-8. 

 

1996


Starch and dextrins in emulsion copolymerization.    
Boediger, M.; Demharter, S.; Muelhaupt, R..    Freiburger Materialforschungszentrum und Institut fur
Makromolekulare,  Chemie der Albert-Ludwigs Universitat,  Freiburg i.Br.,  Germany.  Editor(s): Van
Bekkum, Herman; Roeper, Harald; Voragen, Fons.    Carbohydrates as Organic Raw Materials III,
developed from a Workshop, Wageningen, Nov. 28-29, 1994  (1996),  Meeting Date 1994,     141-154. 
Publisher: VCH,  Weinheim, Germany 

PAT35
Functionalized polymers, block copolymers, graft copolymers of norbornene-type polycyclic
monomers and polymer blends and alloys containing them.    
Rhodes, Larry F.; Goodall, Brian L.; Mulhaupt, Rolf; Shick, Robert A.; Benedikt, George M.;
Jayaraman, Sai Kumar; Soby, Lynn M.; Mc Intosh, Lester H., III.  (B.F. Goodrich Company, USA).   
PCT Int. Appl.  (1996),     90 pp.  WO  9637528  A1  19961128  Application: WO  96-US6521 
19960520.  Priority: US  95-450648  19950525.  CAN 126:118327   

Controlled architectures and property synergisms of polypropene/polyamide 6 blends
prepared via reactive processing.    
Roesch, Joachim; Muelhaupt, Rolf; Michler, G. H.    Macromolecular Symposia  (1996),  112(Fifth
European Symposium on Polymer Blends, 1996),  141-150.  C

Toughened polypropylene-polyamide 6 blends prepared by reactive blending.    
Roesch, J.; Muelhaupt, R..    Advances in Chemistry Series  (1996),  252(Toughened Plastics II),  291-
302.

Compatibilized, segmented liquid rubbers as epoxy-toughening agents.   
 Muelhaupt, R.; Buchholz, U.    Advances in Chemistry Series  (1996),  252(Toughened Plastics II), 
75-94.   

[88] Influence of thermoplastic elastomers on mechanical properties and morphologies of
isotactic polypropene/glass bead hybrid composites.    
Stricker, F.; Muelhaupt, R..    Journal of Applied Polymer Science  (1996),  62(11),  1799-1806.  C

[87] On the gamma-phase of isotactic polypropylene.    
Thomann, Ralf; Wang, Chun; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecules  (1996),  29(26), 
8425-8434. 

[86] Mono- and Multilayers of Mesogen-Substituted Carbosilane Dendrimers on Mica.    
Coen, Martine Collaud; Lorenz, Klaus; Kressler, Joerg; Frey, Holger; Muelhaupt, Rolf.  
Macromolecules  (1996),  29(25),  8069-8076.

[85] Novel materials through stereocomplexation.    
Brizzolara, Davide; Cantow, Hans Joachim; Muelhaupt, Rolf; Domb, Abraham J.   Journal of
Computer-Aided Materials Design  (1996),  3(1-3, Modeling of Industrial Materials),  341-350. 

Silicon-based thermoset resins.    
Muelhaupt, R..    Editor(s): Kricheldorf, Hans R.    Silicon in Polymer Synthesis  (1996),     458-468. 
Publisher: Springer,  Berlin, Germany  C

[84] Liquid Crystalline Thermosets Based on Branched Bismethacrylates.    
Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.; Macromolecules  (1996),  29(22), 
7003-7011. 

Engineering of new supermolecular structures defined by the chain architectures of
polypropylenes and their blends.    
Kressler, Joerg; Thomann, Ralf; Muelhaupt, Rolf.    Annual Technical Conference - Society of Plastics
Engineers  (1996),  54th(Vol. 2),  2289-2293.

[83] Morphology and phase behavior of blends of syndiotactic and isotactic polypropylene: 2.
Differential scanning calorimetry, light transmission measurements, and PVT measurements.    
Thomann, Ralf; Kressler, Joerg; Rudolf, Bernd; Muelhaupt, Rolf.    Polymer  (1996),  37(13),  2635-
2640.

[82]  Morphology and phase behavior of blends of syndiotactic and isotactic polypropylene: 1.
X-ray scattering, light microscopy, atomic force microscopy, and scanning electron
microscopy.
Thomann, Ralf; Kressler, Joerg; Setz, Stefan; Wang, Chun; Muelhaupt, Rolf.    Polymer  (1996), 
37(13),  2627-2634.

Innovation for plastics through metallocene catalysis.     Muelhaupt, Rolf.    Gummi, Fasern,
Kunststoffe  (1996),  49(5),  394-403. 

[81] Utilization of renewable resources. Possibilities and limits.    
Muelhaupt, R..    Chimia  (1996),  50(5),  191-198. 

[80] A mesogen-functionalized carbosilane dendrimer. A dendritic liquid crystalline polymer.
Lorenz, Klaus; Hoelter, Dirk; Stuehn, Bernd; Muelhaupt, Rolf; Frey, Holger.   Advanced Materials
(Weinheim, Germany)  (1996),  8(5),  414-16. 

[79] Comparison of thermal and microwave-activated polymerization of epsilon-caprolactone
with titanium tetrabutylate as catalyst.    
Albert, Philipp; Warth, Holger; Muelhaupt, Rolf; Janda, Ralf.    Macromolecular Chemistry and Physics 
(1996),  197(5),  1633-1641. 

PAT34
Manufacture of oligomers and polymers of aminoalkenes.    
Fischer, David; Langhauser, Franz; Kerth, Juergen; Schweier, Guenther; Muelhaupt, Rolf; Schneider,
Martin.  (BASF A.-G., Germany).    Ger. Offen.  (1996),     10 pp.  CODEN: GWXXBX  DE  4433481 
A1  19960321  Patent  written in German.    Application: DE  94-4433481  19940920.  CAN
124:290597  

Mesogen-functionalized carbosilane dendrimers-dendritic liquid crystalline polymers.    
Frey, Holger; Lorenz, Klaus; Hoelter, Dirk; Muelhaupt, Rolf.   Polymer Preprints (American Chemical
Society, Division of Polymer Chemistry)  (1996),  37(1),  758-9. 

Branched LC bismethacrylates.     Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1996),  37(1),  756-7.  CODEN:
ACPPAY  ISSN: 0032-3934.  Journal  written in English.   

Controlled polypropylene crystallization via metallocene-catalyzed propene polymerization and
stereoisomer blend formation.    
Thomann, R.; Kressler, J.; Fischer, D.; Juengling, S.; Muelhaupt, R..    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (1996),  37(1),  269-70.

FTIR spectroscopic studies on the interfacial reactions of oxazoline-functionalized polymers.    
Schaefer, R.; Kressler, J.; Muelhaupt, R..    Acta Polymerica  (1996),  47(4),  170-6. 

[78] Trends in polymer chemistry 1995.    
Frey, H.; Kressler, J.; Richtering, W.; Muelhaupt, R..    Acta Polymerica  (1996),  47(4),  131-40. 

Interpenetrating networks containing dispersed silicone micro- and nanophases.    
Buchholz, U.; Muelhaupt, R..    IPolymeric Materials Science and Engineering  (1996),  74  339-40. 
CODEN: PMSEDG  ISSN: 0743-0515.

Mesogen-functionalized carbosilane dendrimers - dendritic liquid crystalline polymers.    
Frey, Holger; Lorenz, Klaus; Hoelter, Dirk; Muelhaupt, Rolf.   Book of Abstracts, 211th ACS National
Meeting, New Orleans, LA, March 24-28  (1996),     POLY-280.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 62PIAJ  Conference; Meeting Abstract  written in English.    AN
1996:222015    CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 


Branched LC bismethacrylates.    
Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.    Book of Abstracts, 211th ACS
National Meeting, New Orleans, LA, March 24-28  (1996),     POLY-279.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 62PIAJ  Conference; Meeting Abstract  written in
English.    AN 1996:222014    CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 


Controlled polypropene crystallization via metallocene-catalyzed propene polymerization and
stereoisomer blend formation.    
Juengling, S.; Fischer, D.; Thomann, R.; Kressler, J.; Muelhaupt, Rolf.   Book of Abstracts, 211th ACS
National Meeting, New Orleans, LA, March 24-28  (1996),     POLY-278.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 62PIAJ  Conference; Meeting Abstract  written in
English.    AN 1996:222013    CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 

Interpentrating networks containing dispersed silicone micro- and nanophases.    
Buchholz, U.; Muelhaupt, R..    Book of Abstracts, 211th ACS National Meeting, New Orleans, LA,
March 24-28  (1996),     PMSE-201.  Publisher: American Chemical Society,  Washington, D. C 
CODEN: 62PIAJ  Conference; Meeting Abstract  written in English.   

[78] Compatibilized polypropylene hybrid composites: influence of elastomeric interlayers on
mechanical properties and nucleation behavior.    
Stricker, Florian; Muelhaupt, Rolf.   High Performance Polymers  (1996),  8(1),  97-108. 

[77] Syntheses of mono(1,3-oxazolin-2-yl)-terminated oligopropene macromonomers and novel
polymers containing oligopropene side chains.    
Woerner, Christof; Roesch, Joachim; Hoehn, Arthur; Muelhaupt, Rolf.    Polymer Bulletin (Berlin) 
(1996),  36(3),  303-9. 

[76] Synthesis and Photoinitiated Cationic Polymerization of 2-Methylene-7-phenyl-1,4,6,9-
tetraoxaspiro[4.4]nonane.    
Bolln, Carsten; Frey, Holger; Muelhaupt, Rolf.    Macromolecules  (1996),  29(9),  3111-16.  CODEN:
MAMOBX  ISSN: 0024-9297.  J

[75] Negative pressure effects during the isothermal crystallization of isotactic poly(propylene)
studied by light and atomic force microscopy.    
Thomann, Ralf; Wang, Chun; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecular Chemistry and
Physics  (1996),  197(3),  1085-91. 

[74] Influence of polymerization conditions on the copolymerization of styrene with ethylene
using Me2Si(Me4Cp)(N-tert-butyl)TiCl2/methylaluminoxane Ziegler-Natta catalysts.    
Sernetz, Friedrich G.; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1996),  197(3), 
1071-83. 

[73] Characterization of supra-molecular assemblies of N-(n-alkyl)-N'-D-maltosylsemicarbazone
adsorbates by atomic force microscopy.    
Craemer, K.; Demharter, S.; Muelhaupt, R.; Frey, H.; Magonov, S. N.; Tuzov, I.; Whangbo, M.-H.   
New Journal of Chemistry  (1996),  20(1),  5-11. 

[72] Transition metal catalysts for the polymerization of olefins. Part 2. Preparation of
stereoregular poly(1-olefins).    
Muelhaupt, Rolf; Rieger, Bernhard.    Chimia  (1996),  50(1-2),  10-19. 

Modification of catheter materials by coating with polymer layers containing silver.   
Coen, Martine Collaud; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecular Symposia  (1996), 
103(Polymers and Medicine),  109-17.  CODEN: MSYMEC  ISSN: 1022-1360. 

[71] Miscibility of Poly(sila-?-methylstyrene) with Polystyrene.    
Maier, Ralph-Dieter; Kressler, Joerg; Rudolf, Bernd; Reichart, Peter; Koopmann, Florian; Frey, Holger;
Muelhaupt, Rolf.    Macromolecules  (1996),  29(5),  1490-7.  C

Dendritic polyols based on carbosilanes - lipophilic dendrimers with hydrophilic skin.    
Frey, Holger; Lorenz, Klaus; Muelhaupt, Rolf.   Macromolecular Symposia  (1996),  102(9th Rolduc
Polymer Meeting, Smart Polymer Materials & Products, 1995),  19-26.  CODEN: MSYMEC  ISSN:
1022-1360.  Journal  written in English.    CAN 124:147038  

[70] Morphology and mechanical properties of blends of isotactic or syndiotactic
polypropylene with SEBS block copolymers.   
Setz, Stefan; Sticker, Florian; Kressler, Joerg; Duschek, Thomas; Muelhaupt, Rolf.    Journal of
Applied Polymer Science  (1996),  59(7),  1117-28.

[69] Modification of isotactic poly(propylene) by oxygen and helium plasma with reference to
thermo-oxidative stability.    
Bauer, Michael; Rembold, Manfred; Marti, Erwin; Schneider, Hans Adam; Muelhaupt, Rolf.   
Macromolecular Chemistry and Physics  (1996),  197(1),  61-82. 

 

1995


New high-performance polymers obtained from bis-acenaphthyls.    
Rusanov, A.L.; Mulhaupt, R..    A.N. Nesmeyanov Institute of Organo-Element Compounds, Russian
Academy of Sciences,  Moscow,  Russia.    Polymer Yearbook  (1995),  12  3-52. 

Preparation of functionalized materials by reactive extrusion.    
Roesch, Joachim; Warth, Holger; Stricker, Florian; Woerner, Christof; Muelhaupt, Rolf.    Germany.   
Aufbereiten von Polymeren mit Neuartigen Eigenschaften  (1995),     81-96.  Publisher: VDI-Verlag, 
Duesseldorf,

[68] Transition metal catalysts for olefin polymerization. Part 1. Low pressure manufacture of
polyethene.    
Muelhaupt, Rolf; Rieger, Bernhard.    Chimia  (1995),  49(12),  486-91.  Bibliographic Information

The influence of structural parameters on the glass temperature and compatibility of
poly(phenylene ether ketone)s.    
Schneider, H. A.; Glatz, F.; Muelhaupt, R..   New Polymeric Materials  (1995),  4(4),  289-99.  CCAN
124:118829    AN 1996:12579   

LC-dendrimers based on carbosilanarborols.    
Frey, Holger; Muelhaupt, Rolf; Lorenz, Klaus; Rapp, Uwe; Mayer-Posner, Franz J.    Polymeric
Materials Science and Engineering  (1995),  73  127-8. 

PAT33
In-situ encapsulation of fillers by polyesters in thermoplastic resins.    
Muelhaupt, Rolf; Roesch, Joachim; Barghoorn, Peter; Hopperdietzel, Siegfried; Poersch, Franz;
Weingber, Ekkehard; Klein, Herbert.  (Rehau A.-G. & Co., Germany).    Eur. Pat. Appl.  (1995),     9
pp.  EP  669368  A1  19950830  Application: EP  95-101526  19950204.  Priority: DE  94-4405745 
19940223.  CAN 123:342124   

LC-dendrimers based on carbosilanarborols.    
Frey, Holger; Muelhaupt, Rolf; Lorenz, Klaus; Rapp, Uwe; Mayer-Posner, Franz J.   Book of Abstracts,
210th ACS National Meeting, Chicago, IL, August 20-24  (1995),   (Pt. 2),  PMSE-066.  Publisher:
American Chemical Society,  Washington, D. C  CODEN: 61XGAC  Conference; Meeting Abstract 
written in English.  

Multiphase polypropenes prepared by reactive blending.    
Muelhaupt, Rolf; Stricker, Florian; Barghoorn, Peter; Roesch, Joachim.    Macromolecular Symposia 
(1995),  100(5th European Polymer Federation Symposium on Polymeric Materials, 1994),  149-54. 

[67] Morphology of syndiotactic polypropylene.   
Thomann, Ralf; Wang, Chun; Kressler, Joerg; Juengling, Stephan; Muelhaupt, Rolf.   Polymer  (1995), 
36(20),  3795-801. 

Dynamic fracture behavior of epoxy systems blended with block copolymers based on
polyetheresters.    
Hoefflin, F.; Boehme, W.; Muelhaupt, R..   ESIS Publication  (1995),  19(Impact and Dynamic Fracture
of Polymers and Composites),  181-90. 

The role of dormant sites in propene polymerization using methylaluminoxane activated
metallocene catalysts.    
Juergling, Stephen; Muelhaupt, Rolf; Stehling, Udo; Brintzinger, Hans-Herbert; Fischer, David;
Langhauser, Franz.    Macromolecular Symposia  (1995),  97  205-16. 

[66] Synthesis and gel formation of amphiphilic semicarbazones containing saccharide units.    
Demharter, S.; Frey, H.; Drechsler, M.; Muelhaupt, R..    Colloid and Polymer Science  (1995),  273(7), 
661-74. .    CAN 124:59894

[65] Modified syndiotactic polypropene. Propene-octene copolymers and blends with atactic
oligopropene.    
Juengling, Stephan; Muelhaupt, Rolf; Fischer, David; Langhauser, Franz.   Angewandte
Makromolekulare Chemie  (1995),  229  93-112. 

[64] Carbosilane-Based Dendritic Polyols.   
Lorenz, Klaus; Muelhaupt, Rolf; Frey, Holger; Rapp, Uwe; Mayer-Posner, Franz J.    Macromolecules 
(1995),  28(19),  6657-61. 

[63] Reaction calorimetric investigation of 1-olefin homo-and copolymerization using
homogeneous metallocene catalysts.    
Schneider, Martin J.; Muelhaupt, Rolf.      Journal of Molecular Catalysis A: Chemical  (1995),  101(1), 
11-16.

PAT33
Dihydrophenazine polymers.    
Kreuder, Willi; Muelhaupt, Rolf; Mikulla, Markus.  (Hoechst A.-G., Germany).    Ger. Offen.  (1995),    
19 pp.  DE  4325591  A1  19950202  Application: DE  93-4325591  19930730.  CAN 123:84343   

[62] The influence of methylalumoxane concentration on propene polymerization with
homogeneous metallocene-based Ziegler-Natta catalysts.    
Juengling, Stephan; Muelhaupt, Rolf.    Journal of Organometallic Chemistry  (1995),  497(1-2),  27-
32.

[61] Emulsion polymerization of styrene in the presence of carbohydrate-based amphiphiles.
[Erratum to document cited in CA123:33768].    
Demharter, Susanne; Richtering, Walter; Muelhaupt, Rolf.    Polymer Bulletin (Berlin)  (1995),  34(5/6), 
691-8.  CODEN: POBUDR  ISSN: 0170-0839.  Journal  written in English.   

[60] Formation of colloidal PMMA particles via free radical and group transfer dispersion
polymerization of methyl methacrylate and methyl methacrylate/ethylene glycol dimethacrylate.    
Hoelderle, M.; Muelhaupt, R..    Acta Polymerica  (1995),  46(3),  226-32. 

[59] Stereospecific olefin polymerization with chiral metallocene catalysts.    
Brintzinger, Hans H.; Fischer, David; Muelhaupt, Rolf; Rieger, Bernhard; Waymouth, Robert M.   
Angewandte Chemie, International Edition in English  (1995),  34(11),  1143-70. 

[58] FTIR Spectroscopy and Microscopy on the Interfacial Reaction and Interdiffusion of
Styrene/Maleic Anhydride and Bis(amine)-Terminated Poly(tetrahydrofuran).   
Schaefer, Ruediger; Kressler, Joerg; Neuber, Rolf; Muelhaupt, Rolf.    Macromolecules  (1995), 
28(14),  5037-42.  CODEN: MAMOBX  ISSN: 0024-9297.  J

Novel polyolefin materials and processes: Overview and prospects.    
Muelhaupt, Rolf.    Editor(s): Fink, Gerhard; Muelhaupt, Rolf; Brintzinger, Hans H.    Ziegler Catal. 
(1995),     35-55.  Publisher: Springer,  Berlin, Germany 

[57] 1,3-Oxazoline intermediates in reactive processing applications. 2. Multiphase polymer
blends via in-situ cationic melt phase polymerization of 2-phenyl-1,3-oxazoline.    
Mueller, Philipp; Woerner, Christof; Muelhaupt, Rolf.   Macromolecular Chemistry and Physics  (1995), 
196(6),  1929-36. 

[56] 1,3-Oxazoline intermediates in reactive processing applications. 1. Melt grafting of
poly(ethene-co-methacrylic acid) with 2-substituted 1,3-oxazolines.    
Mueller, Philipp; Werner, Christof; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1995), 
196(6),  1917-28.  C

[55] Deformation behavior of polypropylene/polyamide blends.    
Roesch, Joachim; Muelhaupt, Rolf.     Journal of Applied Polymer Science  (1995),  56(12),  1607-13. 

[54] Mechanical and morphological properties of elastomer-modified polypropylene/polyamide-
6 blends.     Roesch, Joachim; Muelhaupt, Rolf.   Journal of Applied Polymer Science  (1995),  56(12), 
1599-605.  CODEN: JAPNAB  ISSN: 0021-8995. 

Ziegler Catalysts: Recent Scientific Innovations and Technological Improvements.    
Fink, Gerhard; Muelhaupt, Rolf; Brintzinger, Hans H.; Editors.    Germany.    (1995),     511 pp. 
Publisher: (Springer,  Berlin, Germany)  Book 

[53] Propene polymerization using homogeneous MAO-activated metallocene catalysts:
Me2Si(benz[e]indenyl)2ZrCl2/MAO vs. Me2Si(2-Me-benz[e]indenyl)2ZrCl2/MAO.    
Juengling, Stephan; Muelhaupt, Rolf; Stehling, Udo; Brintzinger, Hans Herbert; Fischer, David;
Langhauser, Franz.   Journal of Polymer Science, Part A: Polymer Chemistry  (1995),  33(8),  1305-
17. 

[52] Interpenetrating polymer networks derived from epoxide-amine adducts in neither polymer
network.    
Klee, Joachim E.; Leube, Walter; Muelhaupt, Rolf.    Angewandte Makromolekulare Chemie  (1995), 
226  173-82. 

[51] Thermal polymerization and reactive blending of 2-(4-hydroxyphenyl)-1,3-oxazoline.   
 Woerner, C.; Mueller, P.; Muelhaupt, R..    Polymer Bulletin (Berlin)  (1995),  34(3),  301-8. 

[50] Anhydride-cured epoxy resins toughened with diol- and bis(4-hydroxybenzoate)-
terminated poly(tetrahydrofuran) liquid rubbers. Part II. Phase separation.    
Laeuger, J.; Albert, P.; Kressler, J.; Gronski, W.; Muelhaupt, R..    Acta Polymerica  (1995),  46(1),  74-
8.  C

[49] Anhydride-cured epoxy resins toughened with diol- and bis(4-hydroxybenzoate)-
terminated poly(tetrahydrofuran) liquid rubbers. Part I. Morphology and blend properties.    
Albert, P.; Laeuger, J.; Kressler, J.; Muelhaupt, R..    Acta Polymerica  (1995),  46(1),  68-73. 

[48] Transcrystallinity of thin films of isotactic polypropylene.    
Setz, Stefan; Schnell, Rupert; Thomann, Ralf; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecular
Rapid Communications  (1995),  16(1),  81-7.  C

[47] Fullerene-End-Capped Polystyrenes. Monosubstituted Polymeric C60 Derivatives.    
Weis, Christine; Friedrich, Christian; Muelhaupt, Rolf; Frey, Holger.    Macromolecules  (1995),  28(1), 
403-5. 

 

1994


PAT32
Aqueous polymer dispersions for preparation of water vapor-permeable coatings on textiles.    
Moebus, Helmut; Bister, Erhard; Muelhaupt, Rolf.  (Rotta GmbH, Germany).    Ger. Offen.  (1994),     7
pp.  DE  4315269  A1  19941110  Application: DE  93-4315269  19930507.  CAN 122:292753 

Phase compatibilizers for polypropylene-polyamide 6 blends.    
Muelhaupt, R.; Roesch, J.    Freiburg/Br.,  Germany.    Kunststoffe  (1994),  84(9),  1153, 1155-6

[46] Progress in synthesis and application of segmented polymers.    
Muelhaupt, Rolf; Buchholz, Udo; Roesch, Joachim; Steinhauser, Norbert.    Angewandte
Makromolekulare Chemie  (1994),  223  47-60.  CODEN: ANMCBO  ISSN: 0003-3146. 

[45] Use of polystyrene-block-poly(ethylene oxide) as emulsifier in emulsion polymerization.    
Berger, Markus; Richtering, Walter; Muelhaupt, Rolf.   Polymer Bulletin (Berlin)  (1994),  33(5),  521-8. 

PAT31
Plasticized cellulose acetate, its manufacture, and its use in manufacturing filaments.    
Muelhaupt, Rolf; Schaetzle, Joachim; Warth, Holger.  (Rhone-Poulenc Rhodia AG, Germany).    Ger. 
(1994),     9 pp.  DE  4325352  C1  19940901  Patent  written in German.    Application: DE  93-
4325352  19930728.  CAN 122:136516   

[44] Preparation and properties of soluble polyamide imides containing
oligo(tetrafluoroethene) segments and application in gas separation.    
Steinhauser, Norbert; Muelhaupt, Rolf; Hohmann, Marcus; Springer, Juergen.    Polymers for
Advanced Technologies  (1994),  5(8),  438-43. 

[43] Preparation and properties of polyaramides derived from aromatic diamine-terminated
oligo(tetrafluoroethene)s.    
Steinhauser, N.; Muelhaupt, R..    High Performance Polymers  (1994),  6(2),  133-47. 

[42] Anisotropic dispersion polymerization of N-(4-aminobenzoyl)-caprolactam in polymer
melts.     Muelhaupt, Rolf; Roesch, Joachim.    Polymers for Advanced Technologies  (1994),  5(5), 
282-6. 

[41] Ultimate properties of epoxy resins modified with a polysiloxane-polycaprolactone block
copolymer.    
Konczol, L.; Doll, W.; Buchholz, U.; Mulhaupt, R..    Journal of Applied Polymer Science  (1994), 
54(6),  815-26.

[40] Synthesis of N-acylated derivatives of 5,10-dihydrophenazine.   
Mikulla, Markus; Muelhaupt, Rolf.   Chemische Berichte  (1994),  127(9),  1723-8. 

[39] The role of compatibilizers and elastomeric interlayers in glass-bead-reinforced
poly(propylene).    
Roesch, Joachim; Barghoorn, Peter; Muelhaupt, Rolf.   Macromolecular Rapid Communications 
(1994),  15(9),  691-6. 

[38] Preparation and properties of copolyamides-6,6F and copolyamides-4,8F containing
oligo(tetrafluoroethylene) segments.    
Steinhauser, Norbert; Muelhaupt, Rolf.   Macromolecular Chemistry and Physics  (1994),  195(9), 
3199-211.  C

[37] The role of core/shell-microparticle dispersions in polypropylene/polyamide-6 blends.    
Roesch, Joachim; Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (1994),  32(5-6),  697-704. 

[36] Living dispersion polymerization of styrene in the presence of polystyrene-block-poly(4-
trimethylsilylstyrene).    
Schneider, Michael; Muelhaupt, Rolf.     Polymer Bulletin (Berlin, Germany)  (1994),  32(5-6),  545-50. 

[35] Scanning force microscopy of oriented iso- and syndiotactic polypropylene films.    
Craemer, K.; Schneider, M.; Muelhaupt, R.; Cantow, H.-J.; Magonov, S. N.    Polymer Bulletin (Berlin,
Germany)  (1994),  32(5-6),  637-44. 

[34] Mechanical properties of organosolv-lignin-filled thermoplastics.     Roesch, Joachim;
Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (1994),  32(3),  361-5.  C

[33] Preparation and cure behavior of dimethacrylates containing oligo(tetrafluoroethene)
segments.    
Steinhauser, Norbert; Muelhaupt, Rolf.   Polymer Bulletin (Berlin, Germany)  (1994),  32(4),  403-10. 

[32] Influence of flexible oligo(tetrafluoroethene) segments on the glass temperature of
poly(aramide)s and poly(amide imide)s.    
Schneider, H. A.; Steinhauser, N.; Muelhaupt, R..    Polymer Bulletin (Berlin, Germany)  (1994),  32(3), 
339-46. 

[31] Gas permeabilities and permselectivities of amorphous segmented 6F poly(arylene
thioether imide)s and the corresponding poly(arylene sulfone imide)s.   
Glatz, F. P.; Muelhaupt, R.; Schultze, J. D.; Springer, J.    Journal of Membrane Science  (1994), 
90(1-2),  151-9.

[30] Preparation, cure behavior and properties of bis(2-oxazoline)s containing well-defined
oligo(tetrafluoroethylene) segments.     Steinhauser, Norbert; Muelhaupt, Rolf.    Macromolecular
Rapid Communications  (1994),  15(4),  365-72.

[29] The influence of regio- and stereoirregularities on the crystallization behavior of isotactic
poly(propylene)s prepared with homogeneous group IVa metallocene/methylaluminoxane
Ziegler-Natta catalysts.    
Fischer, David; Muelhaupt, Rolf.    Inst. Makromol. Chem.,  Macromolecular Chemistry and Physics 
(1994),  195(4),  1433-41. 

[28] ansa-Zirconocene Polymerization Catalysts with Anelated Ring Ligands - Effects on
Catalytic Activity and Polymer Chain Length.    
Stehling, Udo; Diebold, Josef; Kirsten, Robin; Roell, Werner; Brintzinger, Hans Herbert; Juengling,
Stephan; Muelhaupt, Rolf; Langhauser, Franz.    Organometallics  (1994),  13(3),  964-70.

 

1993


[27] Reactive blending of polypropylene/polyamide-6 in the presence of tailor-made succinic
anhydride-terminated oligo-propene compatibilizers.    
Muelhaupt, Rolf; Duschek, Thomas; Roesch, Joachim.    Polymers for Advanced Technologies 
(1993),  4(7),  465-74.

[26] Novel polypropene materials derived from vinylidene-terminated oligopropenes.    
Muelhaupt, Rolf; Duschek, Thomas; Fischer, David; Setz, Stefan.    Polymers for Advanced
Technologies  (1993),  4(7), 

Organic microcomposites via reactive processing.    
Muelhaupt, R.; Roesch, J.; Demharter, S.    Journal de Physique IV:  Proceedings  (1993),  3(C7, 3RD
EUROPEAN CONFERENCE ON ADVANCED MATERIALS AND PROCESSES, 1993, VOL. 2), 
1519-24.  CODEN: JPICEI  ISSN: 1155-4339. 

Reinforcement of polyurethane by in-situ particle precipitation.    
Krenceski, Mary. A.; Cantow, H. -J.; Mulhaupt, R..     Polymeric Materials Science and Engineering 
(1993),  70  356-7. 

Toughened polypropylene/polyamide blends prepared by reactive blending.    
Roesch, Joachim; Muelhaupt, Rolf.    Polymeric Materials Science and Engineering  (1993),  70  193. 

Compatibilized liquid rubbers as epoxy toughening agents.    
Muelhaupt, Rolf; Buchholz, Udo.   Polymeric Materials Science and Engineering  (1993),  70  4. 

Donor- and acceptor-modified metallocene-based homogeneous Ziegler-Natta catalysts.    
Fischer, David; Juengling, Stephan; Muelhaupt, Rolf.   Macromolecular Symposia  (1993), 
66(Advances in Olefin, Cycloolefin and Diolefin Polymerization),  191-202. 

[25] Semi-interpenetrating networks of sulfur-containing bismaleimides.    
Glatz, F. P.; Muelhaupt, R..   High Performance Polymers  (1993),  5(4),  297-305. 

[24] Syntheses and blend behavior of poly(phenylene thioether ether ketones) (PTEKs) and
poly(phenylene sulfone ether ketones) (PSEKs).   
Glatz, F P.; Muelhaupt, R..    High Performance Polymers  (1993),  5(3),  219-28. 

[23] Preparation, cure behavior and properties of bismaleimides containing well defined
oligo(phenylene sulfide) segments.    
Glatz, F P.; Muelhaupt, R..    High Performance Polymers  (1993),  5(3),  213-18.

New building blocks for melt adhesives.    
Muelhaupt, Rolf; Setz, Stefan; Elster, Clemens; Honerkamp, Josef.    Adhaesion--Kleben & Dichten 
(1993),  37(11),  26, 28-30.  CAN 121:59031    AN 1994:459031    C

[22] Cooperative effects in binuclear zirconocenes: their synthesis and use as catalyst in
propene polymerization.    
Juengling, Stephan; Muelhaupt, Rolf; Plenio, Herbert.    Journal of Organometallic Chemistry  (1993), 
460(2),  191-5.  CODEN: JORCAI  ISSN: 0022-328X. 

PAT30
Catalyst system for polymerization of C2-10 olefins.    
Langhauser, Franz; Lux, Martin; Muelhaupt, Rolf; Fischer, David.  (BASF A.-G., Germany).    Ger.
Offen.  (1993),     10 pp.  DE  4203753  A1  19930812  Application: DE  92-4203753  19920210.  CAN
120:165219    AN 1994:165219   

Modified polysulfones as membrane electrolytes.    
Nolte, R.; Ledjeff, K.; Bauer, M.; Muelhaupt, R., BHR Group Conference Series Publication  (1993), 
3(Effective Membrane Processes--New Perspectives),  381-5. 

[21] Syntheses and properties of soluble poly(arylene thioether imides) and the corresponding
poly(arylene sulfone imides).    
Glatz, Frank P.; Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (1993),  31(2),  137-43. 

New generations of polyolefin materials.    
Muelhaupt, Rolf.   Nachrichten aus Chemie, Technik und Laboratorium  (1993),  41(12),  1341-6,
1348, 1351. 

PAT29
Elastomeric polymer alloys, their preparation and use.    
Muelhaupt, Rolf; Demharter, Susanne; Hopperdietzel, Siegfried; Weinberg, Ekkehard; Klein, Herbert. 
(Rehau AG und Co., Germany).    Ger.  (1993),     6 pp. DE  4205428  C1  19930527  CAN
120:109275   

[20] Anisotropic polyaramide/polyol dispersions - new components for the preparation of
polyurethane microcomposites.    
Demharter, Susanne; Roesch, Joachim; Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany) 
(1993),  31(4),  421-8. 

[19] Polymers from renewable resources: polyester resins and blends based upon anhydride-
cured epoxidized soybean oil.   
Roesch, Joachim; Muelhaupt, Rolf.   Polymer Bulletin (Berlin, Germany)  (1993),  31(6),  679-85. 

[18] Polynitrile- and polyamine-functionalized poly(trimethylenimine) dendrimers.    
Woerner, Christof; Muelhaupt, Rolf.    Angewandte Chemie  (1993),  105(9),  1367-70 (See also
Angew. Chem., Int. Ed. Engl., 1993, 32(9), 1306-8).  C

[17] Partially sulfonated poly(arylene ether sulfone) - a versatile proton conducting membrane
material for modern energy conversion technologies.    
Nolte, R.; Ledjeff, K.; Bauer, M.; Muelhaupt, R..    Journal of Membrane Science  (1993),  83(2),  211-
20. 

[16] Syntheses and thermal properties of aromatic and semi-aromatic poly(thioether amides)
containing oligo(thio-1,4-phenylene) segments.    
Glatz, Frank P.; Muelhaupt, Rolf.    Inst. Makromol. Chem.,  Albert-Ludwigs Univ.,  Freiburg, 
Germany.    Polymer Bulletin (Berlin, Germany)  (1993),  31(2),  129-36. 

PAT28
Blends of olefin polymers and in-situ-prepared polyesters.    
Muelhaupt, Rolf; Roesch, Joachim; Hopperdietzel, Siegfried; Weinberg, Ekkehard; Klein, Herbert. 
(Rehau AG und Co., Germany).    Eur. Pat. Appl.  (1993),     7 pp.  EP  535526  A1  19930407 
Priority: DE  91-4132671  19911001.  CAN 119:251360   

[15] Synthesis of polymer electrolytes with high ion conductivity using experimental design of
multicomponent polymer systems.    
Schneider, Martin J.; Elster, Clemens; Muelhaupt, Rolf; Honerkamp, Josef; Nolte, Roland; Wittwer,
Volker; Ledjeff, Konstantin.    Industrial & Engineering Chemistry Research  (1993),  32(12),  3128-34. 

[14] Comparison of maleic anhydride-grafted polypropylene with maleic anhydride-grafted
polystyrene-block-poly(ethene-co-but-1-ene)-block-polystyrene as blend compatibilizers of
polypropylene/polyamide-6 blends.   
Roesch, Joachim; Muelhaupt, Rolf.    Makromolekulare Chemie, Rapid Communications  (1993), 
14(8),  503-9. 

 

1992


Syntheses and gas permeabilities of soluble polyimides containing well-defined
oligo(phenylene)(sulfide) and oligo(phenylenesulfone) segments.    
Muelhaupt, R.; Glatz, F. P.; Schultz, J. D.; Springer, J.    Polymer Preprints (American Chemical
Society, Division of Polymer Chemistry)  (1992),  33(1),  203-4. 

Polyamide microcomposites via in-situ polymerization of activated p-aminobenzoic acid.    
Roesch, Joachim; Muelhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division of
Polymer Chemistry)  (1992),  33(1),  370-1. 

Branched polysiloxane block copolymers as epoxy toughening agents.    
Buchholz, Udo; Muelhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division of Polymer
Chemistry)  (1992),  33(1),  205-6.  CO

Polypropylene block and graft copolymers via vinylidene-terminated propene oligomers.    
Duschek, Thomas; Muelhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division of
Polymer Chemistry)  (1992),  33(1),  170-1. 

PAT27
Polymer alloys prepared in situ and their preparation and use.     Muelhaupt, Rolf; Roesch,
Joachim; Hopperdietzel, Siegfried; Weinberg, Ekkehard; Klein, Herbert.  (Rehau AG und Co.,
Germany).    Eur. Pat. Appl.  (1992),     9 pp.  EP  518062  A1  19921216  Priority: DE  91-4119146 
19910611.  CAN 119:9822 

 

1991


PAT26
Functional polypropylene blend compatibilizers.    
Muelhaupt, Rolf; Duschek, Thomas; Rieger, Bernhard.   Macromolecular Symposia  (1991),  48-
49(Eur. Polym. Fed. Symp. Polym. Mater., 3rd, 1990),  317-32. 

[13] Reversible and irreversible deactivation of propene polymerization using homogeneous
Cp2ZrCl2/methylaluminoxane Ziegler-Natta catalysts.     Fischer, David; Muelhaupt, Rolf.    Freib.
Materialforschungszent.,  Albert-Ludwigs Univ.,  Freiburg/Br.,  Germany.    Journal of Organometallic
Chemistry  (1991),  417(1-2),  C7-C11. 

[12] (Trialkylsiloxy)dialkylaluminum dimers.    
Mulhaupt, Rolf; Calabrese, Joseph; Ittel, Steven D.    Organometallics  (1991),  10(9),  3403-6. 

PAT25
Iminosilanes as coupling agents.    
Parrinello, Giovanni; Muelhaupt, Rolf.  (Ciba-Geigy A.-G., Switz.).    Eur. Pat. Appl.  (1991),     17 pp. 
EP  414640  A2  19910227  Priority: CH  89-3069  19890824.  CAN 115:115736 

PAT24
Couplers for polyurethanes.    
Parrinello, Giovanni; Simon, Hubert; Muelhaupt, Rolf.  (Ciba-Geigy A.-G., Switz.).    Eur. Pat. Appl. 
(1991),     31 pp.  EP  406160  A2  19910102  Priority: CH  89-2203  19890613.  CAN 114:248568   

 

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