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Publications 1991 - 2008

Chronologically ordered list of journal publications [], patents PAT, etc. (1991 - 2008)

The following list is not necessarily complete. Publications from 1977 - 1990 you will find here: Prof. Mülhaupt Publications 1977 - 1990

 

2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000,
1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1977-1990

 

2008


[309] Boehmite nanorod-reinforced-polyethylenes and ethylene/1-octene thermoplastic
elastomer nanocomposites prepared by in situ olefin polymerization and melt compounding.
Halbach, Tobias S.; Thomann, Yi; Muelhaupt, Rolf.   Journal of Polymer Science, Part A: Polymer
Chemistry  (2008),  46(8),  2755-2765.  C

[308] Incorporation of growth factor containing Matrigel promotes vascularization of porous
PLGA scaffolds.   
Laschke, M. W.; Ruecker, M.; Jensen, G.; Carvalho, C.; Muelhaupt, R.; Gellrich, N.-C.; Menger, M. D.  
Journal of Biomedical Materials Research, Part A  (2008),  85A(2),  397-407. 

[307] On-Line Particle Growth Monitoring, and in Situ Nanocomposite Formation Using
Catalysts Supported on Arylsulfonic Acid-Modified Boehmites.  
Xalter, Rainer; Pelascini, Frederic; Muelhaupt, Rolf.  Ethylene Polymerization,  Macromolecules
(Washington, DC, United States)  (2008),  41(9),  3136-3143

[306] Isotactic poly(propylene) nanocomposites based upon boehmite nanofillers. 
Streller, Rouven C.; Thomann, R.; Torno, O.; Muelhaupt, R..   Macromolecular Materials and
Engineering  (2008),  293(3),  218-227.

New nitrile- and amine-functionalized polyolefin nanoparticles via tandem catalysis in aqueous
miniemulsion. 
Beierlein, Christine; Schuessele, Andreas; Thomann, Ralf; Muelhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (2008),  49(1),  533-534. 

[306] Boehmite-based polyethylene nanocomposites prepared by in-situ polymerization.  
Halbach, Tobias S.; Muelhaupt, Rolf.   Polymer  (2008),  49(4),  867-876.

Molecular Weight and End Group Control of Isotactic Polystyrene Using Olefins and
Nonconjugated Diolefins as Chain Transfer Agents. 
Gall, Barbara T.; Pelascini, Frederic; Ebeling, Henner; Beckerle, Klaus; Okuda, Jun; Muelhaupt, Rolf.  
Macromolecules (Washington, DC, United States)  (2008),  41(5),  1627-1633.

[305] Incorporation of growth factor containing Matrigel promotes vascularization of porous
PLGA scaffolds.   
Laschke M W; Rucker M; Jensen G; Carvalho C; Mulhaupt R; Gellrich N-C; Menger M D Journal of
biomedical materials research.  Part A  (2008),  85(2),  397-407.  Journal code: 101234237.

2007


[304] Comparative in vitro study of the cell proliferation of ovine and human osteoblast-like
cells on conventionally and rapid prototyping produced scaffolds tailored for application as
potential bone replacement material.   
Wagner, M.; Kiapur, N.; Wiedmann-Al-Ahmad, M.; Huebner, U.; Al-Ahmad, A.; Schoen, R.;
Schmelzeisen, R.; Muelhaupt, R.; Gellrich, N.-C.  Journal of Biomedical Materials Research, Part A 
(2007),  83A(4),  1154-1164.


PAT81
A process for producing polyolefin-polyvinylaromatic block copolymers. 
Steininger, Helmut; Knoll, Konrad; Muelhaupt, Rolf; Weiser, Marc-Stephan.   Eur. Pat. Appl.  (2007), 

Nanostructured morphology of polymer conetworks: Resolving the controversy between AFM
and TEM images for disordered nanophase separated multicomponent polymers.   
Thomann, Ralf; Ivan, Bela; Erd-di, Gabor; Domjan, Attila; Scherble, Jonas; Mulhaupt, Rolf.  Abstracts
of Papers, 234th ACS National Meeting, Boston, MA, United States, August 19-23, 2007  (2007),

Isotactic polystyrene with controlled molecular weight using olefins as chain transfer agents.
Gall, Barbara T.; Pelascini, Frederic; Ebeling, Henner; Okuda, Jun; Mulhaupt, Rolf.    Abstracts of
Papers, 234th ACS National Meeting, Boston, MA, United States, August 19-23, 2007  (2007), 

Preparation and properties of iPP/boehmite nanocomposites. 
Streller, Rouven C.; Mulhaupt, Rolf  Abstracts of Papers, 234th ACS National Meeting, Boston, MA,
United States, August 19-23, 2007  (2007),  

Synthesis of boehmite polyolefin nanocomposites by in-situ polymerization.
Halbach, Tobias S.; Muelhaupt, Rolf.     PMSE Preprints  (2007),  97  547-548.

Nanostructured morphology of polymer conetworks: resolving the controversy between AFM
and TEM images for disordered nanophase separated multicomponent polymers.   
Thomann, Ralf; Ivan, Bela; Erdodi, Gabor; Domjan, Attila; Scherble, Jonas; Mulhaupt, Rolf.  Polymer
Preprints (American Chemical Society, Division of Polymer Chemistry)  (2007),  48(2),  515-516.


Isotactic polystyrene with controlled molecular weight using olefins as chain transfer agents.   
Gall, Barbara; Pelascini, Frederic; Ebeling, Henner; Okuda, Jun; Muelhaupt, Rolf.  Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (2007),  48(2),  313-314.

[303] Arylphosphonic acid-functionalized polyelectrolytes as fuel cell membrane material.  
Bock, Thorsten; Moehwald, Helmut; Muelhaupt, Rolf.   Macromolecular Chemistry and Physics 
(2007),  208(13),  1324-1340.

Am Anfang der Makromolekularen Chemie – Eine Pionierleistrung Hermann Staudingers (1881
– 1965),
Mülhaupt, Rolf Festschrift "550 Jahre Albert-Ludwigs universiträt Freiburg", 2007

Selbstheilende Kunststoffe – Nanotechnologie von der Natur in die Technik,
Mülhaupt, Rolf; Speck, Olga. Kunststoff Trends 6:16 (2007)

[302] Stereospecific styrene enchainment at a titanium site within a helical ligand framework:
evidence for the formation of homochiral polystyrene. 
Beckerle, Klaus; Manivannan, Ramanujachary; Lian, Bing; Meppelder, Geert-Jan M.; Raabe, Gerhard;
Spaniol, Thomas P.; Ebeling, Henner; Pelascini, Frederic; Muelhaupt, Rolf; Okuda, Jun.   
Angewandte Chemie, International Edition  (2007),  46(25),  4790-4793.  CODEN: ACIEF5 
ISSN:1433-7851.

[301] Photo-oxidation and Stabilization of sPP and iPP/Boehmite-Disperal Nanocomposites. 
Chmela, Stefan; Fiedlerova, Agnesa; Borsig, Eberhard; Erler, Jens; Muelhaupt, Rolf.    Journal of
Macromolecular Science, Part A: Pure and Applied Chemistry  (2007),  44(9),  1027-1034.

[300] DSC Study of Syndiotactic Polypropylene/Organoclay Nanocomposite Fibers:
Crystallization and Melting Behavior.  
Borsig, Eberhard; Ujhelyiova, Anna; Mlynarcikova, Zita; Kaemfer, Dirk; Muelhaupt, Rolf; Marcincin,
Anton; Berek, Dusan.   International Journal of Polymeric Materials  (2007),  56(8),  771-788.

[299] Controlled synthesis and characterization of poly[ethylene-block-(L,L-lactide)]s by
combining catalytic ethylene oligomerization with "coordination-insertion" ring-opening
polymerization. 
Ring, Jochen O.; Thomann, Ralf; Muelhaupt, Rolf; Raquez, Jean-Marie; Degee, Philippe; Dubois,
Philippe.    Macromolecular Chemistry and Physics  (2007),  208(8),  896-902.


Metallocene catalyzed olefin polymerization in presence of diethyl zinc: molecular weight
control and polyolefin functionalization.  
Ring, Jochen O.; Muelhaupt, Rolf.   Polymer Preprints (American Chemical Society, Division of
Polymer Chemistry)  (2007),  48(1),  961-962.

[298] PMMA nanocomposites and gradient materials prepared by means of polysilsesquioxane
(POSS) self-assembly.
Weickmann, Hans; Delto, Ralf; Thomann, Ralf; Brenn, Ruediger; Doell, Walter; Muelhaupt, Rolf.    
Journal of Materials Science  (2007),  42(1),  87-92.

[297] Comparative in vitro study of the cell proliferation of ovine and human osteoblast-like
cells on conventionally and rapid prototyping produced scaffolds tailored for application as
potential bone replacement material.  
Wagner M; Kiapur N; Wiedmann-Al-Ahmad M; Hubner U; Al-Ahmad A; Schon R; Schmelzeisen R;
Mulhaupt R; Gellrich N-C  Journal of biomedical materials research. Part A  (2007),  83(4),  1154-64.

[296] A dyadic sensitizer for dye solar cells with high energy-transfer efficiency in the device. 
Siegers Conrad; Hohl-Ebinger Jochen; Zimmermann Boris; Wurfel Uli; Mulhaupt Rolf; Hinsch Andreas;
Haag Rainer    Chemphyschem : a European journal of chemical physics and physical chemistry 
(2007),  8(10),  1548-56.

[295] Stereospecific styrene enchainment at a titanium site within a helical ligand framework:
evidence for the formation of homochiral polystyrene.
Beckerle Klaus; Manivannan Ramanujachary; Lian Bing; Meppelder Geert-Jan M; Raabe Gerhard;
Spaniol Thomas P; Ebeling Henner; Pelascini Frederic; Mulhaupt Rolf; Okuda Jun      Angewandte
Chemie (International ed. in English)  (2007),  46(25),  4790-3.

2006


Halogen-free polyarylphosphonates and polyelectrolyte membranes for PEMFC by nickel-
catalyzed phosphonylation with silylated phosphates.  Bock, Thorsten; Muelhaupt, Rolf;
Moehwald, Helmut.    Macromolecular Rapid Communications  (2006),  27(24),  2065-2071. 

Nanostructured poly(dimethylsiloxane)-based amphiphilic polymer conetworks.  Szabo L,
Sandor; Ivan, Bela; Scherble, Jonas; Thomann, Ralf; Mulhaupt, Rolf.    Abstracts of Papers, 232nd
ACS National Meeting, San Francisco, CA, United States, Sept. 10-14, 2006  (2006),    

Nanostructured poly(dimethylsiloxane)-based amphiphilic polymer co-networks.  Sandro,
Szabo L.; Ivan, Bela; Scherble, Jonas; Mulhaupt, Rolf; Thomann, Ralf.    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (2006),  47(2),  1154-1155

[294] Formation of polyolefin-block-polystyrene block copolymers on phenoxyimine catalysts.   
Weiser, Marc-Stephan; Muelhaupt, Rolf.  Macromolecular Rapid Communications  (2006),  27(13), 
1009-1014. 

[293] Angiogenic and inflammatory response to biodegradable scaffolds in dorsal skinfold
chambers of mice.  
Ruecker, Martin; Laschke, Matthias W.; Junker, Dominik; Carvalho, Carlos; Schramm, Alexander;
Muelhaupt, Rolf; Gellrich, Nils-Claudius; Menger, Michael D. Biomaterials  (2006),  27(29),  5027-
5038.

[292] Living random and block copolymerization of ethene and propene on a tailor-made
phenoxyimine catalyst and characterization of the resulting high molecular weight PE-block-
P(E-co-P) block copolymers.
Weiser, Marc-Stephan; Thomann, Yi; Heinz, Lars-Christian; Pasch, Harald; Muelhaupt, Rolf.   Polymer 
(2006),  47(13),  4505-4512. 

[291] The synthesis and X-ray structure of a phenoxyimine catalyst tailored for living olefin
polymerization and the synthesis of ultra-high molecular weight polyethylene and atactic
polypropylene. 
Weiser, Marc-Stephan; Wesolek, Marcel; Muelhaupt, Rolf.    Journal of Organometallic Chemistry 
(2006),  691(13),  2945-2952.

[290] Correlation of the acid-sensitivity of polyethylene glycol daunorubicin conjugates with
their in vitro antiproliferative activity.
Rodrigues, Paula C. A.; Roth, Thomas; Fiebig, Heinz H.; Unger, Clemens; Muelhaupt, Rolf; Kratz,
Felix.     Bioorganic & Medicinal Chemistry  (2006),  14(12),  4110-4117.


Ethylene/1,3-cyclohexadiene copolymerization by means of methylaluminoxane activated half-
sandwich complexes.  Heiser, Dirk E.; Pelascini, Frederic; Kramer, Dominic; Scott, Jennifer;
Gambarotta, Sandro; McCahill, Jennifer; Stephan, Douglas W.; Okuda, Jun; Muelhaupt, Rolf.   
Macromolecular Symposia  (2006),  236(Olefin Polymerization),  156-160.

New polyolefin nanocomposites and catalyst supports based on organophilic boehmites.   
Xalter, Rainer; Halbach, Tobias S.; Muelhaupt, Rolf.  Macromolecular Symposia  (2006),  236(Olefin
Polymerization),  145-150.


Living olefin polymerisation and block copolymer synthesis in the presence of a single-site
catalyst containing a phenoxyimine ligand.  Weiser, Marc-Stephan; Muelhaupt, Rolf.   
Macromolecular Symposia  (2006),  236(Olefin Polymerization),  111-116. 

Syndiospecific polymerization catalysts for styrene based on rare earth metal half-sandwich
complexes.  Hitzbleck, Julia; Beckerle, Klaus; Okuda, Jun; Halbach, Tobias; Muelhaupt, Rolf.   
Macromolecular Symposia  (2006),  236(Olefin Polymerization),  23-29. 

[289] Copolymerization of ethylene with styrene catalyzed by a linked bis(phenolato) titanium
catalyst.    Capacchione, Carmine; Proto, Antonio; Ebeling, Henner; Mulhaupt, Rolf; Okuda, Jun. 
Journal of Polymer Science, Part A: Polymer Chemistry  (2006),  44(6),  1908-1913.

Aluminoboronates supported on dispersible alumosilicates as activators for bis(imino)pyridine
iron catalysts.  Xalter, Rainer; Mulhaupt, Rolf.    Abstracts of Papers, 231st ACS National Meeting,
Atlanta, GA, United States, March 26-30, 2006  (2006), 

Nanostructured polymer conetworks and nanotemplating thereby.   
Ivan, Bela; Erd-di, Gabor; Mezey, Peter; Scherble, Jonas; Thomann, Ralf; Mulhaupt, Rolf.  Abstracts
of Papers, 231st ACS National Meeting, Atlanta, GA, United States, March 26-30, 2006  (2006),  

Sulfonic acid-modified boehmites as supports for metallocene-based ethylene polymerization
catalysts.   Xalter, Rainer; Muelhaupt, Rolf.   PMSE Preprints  (2006),  94  477-478.

[288] High-Temperature Liquid Chromatography at Critical Conditions: Separation of
Polystyrene from Blends with Polyethylene and Ethylene-Styrene Block Copolymers.  
Heinz, Lars-Christian; Macko, Tibor; Pasch, Harald; Weiser, Marc-Stephan; Muelhaupt, Rolf. 
International Journal of Polymer Analysis and Characterization  (2006),  11(1),  47-55.


PAT80
Laser curable polymerizable dental compositions.  Klee, Joachim; Facher, Andreas; Weber,
Christoph; Muelhaupt, Rolf; Schmider, Martin.   PCT Int. Appl.  (2006),     24 pp.

Hermann Staudinger Award 2006 
Mulhaupt Rolf    Macromolecular bioscience  (2006),  6(2),  187-8.  Journal code: 101135941. 
ISSN:1616-5187.

2005

2005

Improving thermal endurance properties of polypropylene by nanostructuration.   Motori, A.; Patuelli,
F.; Saccani, A.; Montanari, G. C.; Mulhaupt, R..   Annual Report - Conference on Electrical Insulation
and Dielectric Phenomena  (2005),     195-198

Improving thermal endurance properties of polypropylene by nanostructuration.   Motori, A.; Patuelli,
F.; Saccani, A.; Montanari, G. C.; Mulhaupt, R..  Annual Report - Conference on Electrical Insulation
and Dielectric Phenomena  (2005),     195-198

PAT79
Dental sealant composition for the protection of hard tissue.    Klee, Joachim E.; Facher, Andreas;
Weber, Christoph; Muelhaupt, Rolf; Schmider, Martin.  PCT Int. Appl.  (2005),     22 pp.
 

PAT78
Laser curable polymerizable composition for the protection of hard tissue.   
Klee, Joachim E.; Facher, Andreas; Weber, Christoph; Muelhaupt, Rolf; Schmider, Martin. PCT Int.
Appl.  (2005),     21 pp. 

[287] Versatile synthetic route to phosphonate-functional monomers, oligomers, silanes, and
hybrid nanoparticles
M. Schmider, E. Müh, J.E. Klee, R. Mülhaupt, Macromolecules 2005, 38(23):9548-9555

[286] Metallized organoclays as new intermediates for aqueous nanohybrid dispersions,
nanohybrid catalysts and antimicrobial polymer hybrid nanocomposites
H. Weickmann, J.C. Tiller, R. Thomann, R. Mülhaupt, Macromol Mater. Eng. 2005, 290 (9): 875-883

New resins and nanosystems for high-performance adhesives
R. Mülhaupt in W. Possart (ed.) Adhesion – Current Research and Application, Wiley-VCH, Weinheim
2005, 189-203

Hermann Staudinger – im Spannungsfeld von Politik undTechnik
R. Mülhaupt, Freiburger Universitätsblätter 2005, Heft 167 (1. Heft), 63-76

Fabrication of soft and hard biocompatible scaffolds using 3D BioplottingTM 
C. Carvalho, R. Landers, R. Mülhaupt, U. Hübner, R. Schmelzeisen in P.J. Bàrtolo (ed.), Virtual
Modelling and Rapid Manufacturing – Afvanced Research in Virtual and Rapid Prototyping, Taylor &
Francis Group 2005, 97-102

Polymere Werk- und Effektstoffe im Nanokosmos
R. Mülhaupt, Proceedings, Fachtagung „Nanotechnologie in der Kunststofftechnik", Süddeutsches
Kunststoffzentrum, Würzburg 2005, N1-N17

New nanophase separated intelligent amphiphilic conetworks and gels
Macromol. Symp. 2005, 227:265-273

[285] Cobalt (II) octanoate and cobalt (II) perfluoroctanoate catalyzed atom transfer
polymerization of styrene in toluene and fluorous media – A verdsatile route to catalyst
recycling and oligomer formation
Weiser. M.S., Mülhaupt, R., J. Polym. Sci. Part A – Polym. Chem. 2005, 43(17): 3804-3813

[284] Photo-oxidation of sPP/organoclay nanocomposites
Chmela, S., Kleinova, A., Fiedlerova, A., Borsig, E., Kaempfer, D., Thomann, R., Mülhaupt, R., J.
Macromol. Sci. – Pure and Applied Chem. 2005, A42(7): 821-829

[283] Syndiotactic poly(propylene)/organoclay nanocomposite fibers: influence of the nano-
filler and the compatibilizer on the fiber properties,
Z. Mlynarcikova, D. Kaempfer, R. Thomann, R. Mülhaupt, E. Bprsig, A. Marcincin, Polym. Adv.
Techn. 2005, 16:362-369
 
[282] Polymer ionomers for rapuid prototyping and rapid manufacturing by means of 3D
printing
Pfister, A., Waltz, U., Laib, A., Macromol. Mater. Eng. 2005, 290(3):99-113

[281] Nanophase separated amphiphilic conetwork coatings and membranes
Bruns, N., Scherble ., Hartmann, L., Thomann, R., Ivan, B.,  Mülhaupt R., Tiller, J.C., Macromolecules
2005, 38:2431-2438

Armoured latex approach to thermoplastic nanocomposites and nanocompomers
Weickmann, H., Thomann, R.; Mulhaupt, R., Polymeric Materials: Science and Engineering  (2005), 
92  461-462. 

[280] Nanophase Separated Amphiphilic Conetwork Coatings and Membranes
Bruns, N.; Scherble, J.; Hartmann, L.; Thomann, R., Ivan, B., Muelhaupt, R., Tiller, J. C.   
Macromolecules  (2005),  38(6),  2431-2438.

[279] A novel polyamide 12 polymerization system and its use for a LCM-process to produce
CFRP.     Rosso, Patrick; Friedrich, Klaus; Wollny, Andreas; Muelhaupt, Rolf.    Journal of
Thermoplastic Composite Materials  (2005),  18(1),  77-90. 

[278] Catalytic 1,3-Cyclohexadiene homopolymerization and regioselective copolymerization
with ethylene.     Heiser, Dirk E.; Okuda, Jun; Gambarotta, Sandro; Muelhaupt, Rolf.   
Macromolecular Chemistry and Physics  (2005),  206(2),  195-202. 

[277] rac-Me2Si(2-Me-4-t-Bu-C5H2)2ZrMe+: An Alkyl Zirconocenium Cation Stabilized by Steric
Shielding against Interaction with Ancillary Ligands.     Schroeder, Lars; Brintzinger, Hans-
Herbert; Babushkin, Dmitrii E.; Fischer, David; Muelhaupt, Rolf.    Organometallics  (2005),  24(5), 
867-871

[276] PMMA gradient materials and in situ nanocoating via self-assembly of semifluorinated
hyperbranched amphiphiles.     Thomann, Yi; Haag, Rainer; Brenn, Ruediger; Delto, Ralf;
Weickman, Hans; Thomann, Ralf; Muelhaupt, Rolf, Macromolecular Chemistry and Physics  (2005), 
206(1),  135-141.

2004


Soft and hard implant fabrication using 3D-Bioplotting.     Carvalho, C.; Landers, R.; Muelhaupt,
R..    Solid Freeform Fabrication Symposium Proceedings  (2004),     732-741.

[275] Stereospecific post-metallocene polymerization catalysts: the example of isospecific
styrene polymerization.     Beckerle, Klaus; Capacchione, Carmine; Ebeling, Henner; Manivannan,
R.; Muelhaupt, Rolf; Proto, Antonio; Spaniol, Thomas P.; Okuda, Jun.    Journal of Organometallic
Chemistry  (2004),  689(24),  4636-4641. 

[274] Polymer nanocomposites as dielectrics and electrical insulation-perspectives for
processing technologies, material characterization and future applications.    
Tanaka, T.; Montanari, G. C.; Muelhaupt, R..    IEEE Transactions on Dielectrics and Electrical
Insulation  (2004),  11(5),  763-784. 

[273] Modification of electrical properties and performance of EVA and PP insulation through
nanostructure by organophilic silicates.    
Montanari, Gian Carlo; Fabiani, Davide; Palmieri, Fabrizio; Kaempfer, Dirk; Thomann, Ralf;
Muelhaupt, Rolf.    IEEE Transactions on Dielectrics and Electrical Insulation  (2004),  11(5),  754-762. 


Nanomaterials: Opportunities and risks. Market and trends.    
Muelhaupt, Rolf.    Kunststoffe  (2004),  94(8),  76-80,82-85,87-88.

PAT77
Dendritic polymer films as protein-rejecting coatings.    
Haag, Rainer; Siegers, Conrad; Muelhaupt, Rolf.  (Albert-Ludwigs-Universitaet Freiburg, Germany).   
Ger. Offen.  (2004),     7 pp. DE  10311163  A1  20040923  Application: DE  2003-10311163 
20030312.  CAN 141:279158   

PAT76
Impact modified thermoplastic polyamide molding compositions.    
Warth, Holger; Vathauer, Marc; Mulhaupt, Rolf; Friedrich, Christian; Meincke, Olaf.  (Germany).    U.S.
Pat. Appl. Publ.  (2004),     8 pp.  CODEN: USXXCO  US  2004181005  A1  20040916  Patent  written
in English.    Application: US  2004-796525  20040309.  Priority: DE  2003-10310693  20030312. 
CAN 141:261516   

Synthesis of new cycloolefin copolymers based upon 1,3-cyclohexadiene.    
Heiser, D.; Muelhaupt, R..    Polymeric Materials: Science and Engineering  (2004),  91  554-555. 

Cobalt(II) perfluorooctanoate mediated atom transfer on radical polymerization and fluorous
biphase catalysis.    
Weiser, Marc-Stephan; Muelhaupt, Rolf.    Polymeric Materials: Science and Engineering  (2004),  91 
761-762.  CODEN: PMSEDG  ISSN: 0743-0515.  Journal; Computer Optical Disk  written in English.   
CAN 141:

Cobalt(II) perfluorooctanoate mediated atom transfer radical polymerisation and fluorous
biphase catalysis.    
Weiser, Marc Stephan; Mulhaupt, Rolf.    Abstracts of Papers, 228th ACS National Meeting,
Philadelphia, PA, United States, August 22-26, 2004  (2004),     PMSE-412.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 69FTZ8  Conference;

Synthesis of new cycloolefin copolymers based upon 1,3-cyclohexadiene.    
Heiser, Dirk; Mulhaupt, Rolf.    I Abstracts of Papers, 228th ACS National Meeting, Philadelphia, PA,
United States, August 22-26, 2004  (2004),     PMSE-302.  Publisher: American Chemical Society, 
Washington,

New amphiphilic conetworks from methacrylate-telechelic polydimethylsiloxane
bismacromonomers.    
Szabo L, Sandor; Ivan, Bela; Scherble, Jonas; Mulhaupt, Rolf.    Abstracts of Papers, 228th ACS
National Meeting, Philadelphia, PA, United States, August 22-26, 2004  (2004),     PMSE-268. 
Publisher: American Chemical Society,  Washington, D. C  CODEN: 69FTZ8 

On-line monitoring and fingerprint technology: New tools for the development of new catalysts
and polyolefin materials.    
Tuchbreiter, Arno; Marquardt, Juergen; Kappler, Bernd; Honerkamp, Josef; Muelhaupt, Rolf.      
Macromolecular Symposia  (2004),  213(Stereospecific Polymerization and Stereoregular Polymers), 
327-333. 

[272] High-performance epoxy hybrid nanocomposites containing organophilic layered
silicates and compatibilized liquid rubber.    
Froehlich, J.; Thomann, R.; Gryshchuk, O.; Karger-Kocsis, J.; Muelhaupt, R..    Journal of Applied
Polymer Science  (2004),  92(5),  3088-3096. 

PAT75
Silane coupling agent, process for the preparation of a silane coupling agent, use of said silane
coupling agent in a composite or on a substrate, nanoparticles and use thereof in a coating.    
Loontjens, Jacobus Antonius; Plum, Bartholomeus Johannes Margretha; Mulhaupt, Rolf; Maier,
Steffen.  (DSM IP Assets B.V., Neth.).    PCT Int. Appl.  (2004),     15 pp.  WO  2004046156  A1 
20040603  Application: WO  2003-NL787  20031110.  Priority: EP  2002-79918  20021120.  CAN
141:24533   

[271] Herman Staudinger and the origin of macromolecular chemistry.    
Muelhaupt, Rolf.    Angewandte Chemie, International Edition  (2004),  43(9),  1054-1063. 

[270] Non-metallocene catalysts for the styrene polymerization: isospecific group 4 metal
bis(phenolate) catalysts.    
Capacchione, Carmine; Proto, Antonio; Ebeling, Henner; Mulhaupt, Rolf; Moller, Klaus; Manivannan,
R.; Spaniol, Thomas P.; Okuda, Jun.    Journal of Molecular Catalysis A: Chemical  (2004),  213(1), 
137-140. 

PAT74
Preparing biocompatible polyurea, and use.    
Loontjens, Jacobus Antonius; Maier, Steffen; Muelhaupt, Rolf; Zimmermann, Joerg.  (DSM IP Assets
B.V., Neth.).    Eur. Pat. Appl.  (2004),     13 pp.  EP  1394191  A1  20040303  DApplication: EP  2002-
78540  20020828.  CAN 140:218270   

[269] Reactive core/shell type hyperbranched block copolyethers as new liquid rubbers for
epoxy toughening.    
Froehlich, Joerg; Kautz, Holger; Thomann, Ralf; Frey, Holger; Muelhaupt, Rolf.    Polymer  (2004), 
45(7),  2155-2164.

[268] The formation of poly(ester-urea) networks in the absence of isocyanate monomers.    
Zimmermann, Jorg; Loontjens, Ton; Scholtens, B. J. R.; Mulhaupt, Rolf.    Biomaterials  (2004), 
25(14),  2713-2719. 

[267] Synthesis and characterisation of anhydride-cured epoxy nanocomposites containing
layered silicates modified with phenolic alkylimidazolineamide cations.    
Froehlich, Joerg; Golombowski, Dietmar; Thomann, Ralf; Muelhaupt, Rolf.   Macromolecular Materials
and Engineering  (2004),  289(1),  13-19. 

[266] Biofunctional rapid prototyping for tissue-engineering applications: 3D bioplotting versus
3D printing.   
 Pfister, Andreas; Landers, Ruediger; Laib, Andres; Huebner, Ute; Schmelzeisen, Rainer; Muelhaupt,
Rolf.    Journal of Polymer Science, Part A: Polymer Chemistry  (2004),  42(3),  624-638. 

[265] Synthesis of reactive hyperbranched and star-like polyethers and their use for
toughening of vinylester-urethane hybrid resins.    
Karger-Kocsis, J.; Frohlich, J.; Gryshchuk, O.; Kautz, H.; Frey, H.; Mulhaupt, R..      Polymer  (2004), 
45(4),  1185-1195. 

2003


Electrical properties of polymer nanocomposites based upon organophilic layered silicates.    
Zilg, C.; Kaempfer, D.; Thomann, R.; Muelhaupt, R.; Montanari, G. C.    Annual Report - Conference
on Electrical Insulation and Dielectric Phenomena  (2003),     546-550.  C

[264] Poly(Methyl methacrylate)/Palladium Nanocomposites: Synthesis and Characterization of
the Morphological, Thermomechanical, and Thermal Properties.    
Aymonier, Cyril; Bortzmeyer, Denis; Thomann, Ralf; Muelhaupt, Rolf.    Chemistry of Materials  (2003), 
15(25),  4874-4878. 

[263] Carbonylbiscaprolactam: A versatile reagent for organic synthesis and isocyanate-free
urethane chemistry.    
Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Muelhaupt, Rolf.    Angewandte Chemie,
International Edition  (2003),  42(41),  5094-5097. 

[262] Real-time monitoring of ethene/1-hexene copolymerizations: determination of catalyst
activity, copolymer composition and copolymerization parameters.    
Kappler, Bernd; Tuchbreiter, Arno; Faller, Daniel; Liebetraut, Peter; Horbelt, Werner; Timmer, Jens;
Honerkamp, Josef; Mulhaupt, Rolf.    Polymer  (2003),  44(20),  6179-6186. 

[261] In situ formation and compounding of polyamide 12 by reactive extrusion.    
Wollny, A.; Nitz, H.; Faulhammer, H.; Hoogen, N.; Muelhaupt, R..    Journal of Applied Polymer
Science  (2003),  90(2),  344-351. 

Rubber nanocomposites: Morphology and mechanical properties of BR and SBR vulcanizates
reinforced by organophilic layered silicates.     Gummi, Fasern, Kunststoffe  (2003),  56(7),  444-
454. 

[260] Interpenetrating vinylester/epoxy resins modified with organophilic layered silicates.    
Karger-Kocsis, J.; Gryshchuk, O.; Frohlich, J.; Mulhaupt, R..    Composites Science and Technology 
(2003),  63(14),  2045-2054.

[259] Toughened epoxy hybrid nanocomposites containing both an organophilic layered
silicate filler and a compatibilized liquid rubber.    
Froehlich, Joerg; Thomann, Ralf; Muelhaupt, Rolf.    Macromolecules  (2003),  36(19),  7205-7211.

[258] Transport properties of organic vapors in nanocomposites of isotactic polypropylene.    
Gorrasi, Giuliana; Tammaro, Loredana; Tortora, Mariarosaria; Vittoria, Vittoria; Kaempfer, Dirk;
Reichert, Peter; Muelhaupt, Rolf.    Journal of Polymer Science, Part B: Polymer Physics  (2003), 
41(15),  1798-1805. 

[257] Anionic ring-opening polymerization of propylene oxide in the presence of phosphonium
catalysts at various temperatures.    
Rexin, Ornulf; Muelhaupt, Rolf.     Macromolecular Chemistry and Physics  (2003),  204(8),  1102-
1109. 

PAT73
Hyper-branched polymers as selective solvents for the separation of azeotropic mixtures or
mixtures having very similar boiling points.   
Arlt, Wolfgang; Seiler, Matthias; Sadowski, Gabriele; Frey, Holger; Kautz, Holger; Muelhaupt, Rolf. 
(Germany).    Ger. Offen.  (2003),     10 pp.  DE  10160518  A1  20030626  Patent  written in German.   
Application: DE  2001-10160518  20011204.  CAN 139:70957   

[256] Transport properties of organic vapors in nanocomposites of organophilic layered
silicate and syndiotactic polypropylene.     Gorrasi, Giuliana; Tortora, Mariarosaria; Vittoria, Vittoria;
Kaempfer, Dirk; Mulhaupt, Rolf.   Polymer  (2003),  44(13),  3679-3685. 

[255] Fiber spinning from poly(propylene)-organoclay nanocomposite.     Pavlikova, Silvia;
Thomann, Ralf; Reichert, Peter; Mulhaupt, Rolf; Marcincin, Anton; Borsig, Eberhard.   Journal of
Applied Polymer Science  (2003),  89(3),  604-611.  CODEN: JAPNAB  ISSN: 0021-8995. 

[254] Rheological evidence of modifications of polypropylene by gamma-irradiation.    
Schulze, Dirk; Trinkle, Stefan; Muelhaupt, Rolf; Friedrich, Christian.   Rheologica Acta  (2003),  42(3), 
251-258. 

[253] Linear and Nonlinear Rheological Properties of Self-Assembling Tectons in
Polypropylene Matrices.    
Fahrlaender, Michael; Fuchs, Konrad; Muelhaupt, Rolf; Friedrich, Christian.    I Macromolecules 
(2003),  36(10),  3749-3757. 

[252] Ancillary Ligand Effect on Single-Site Styrene Polymerization: Isospecificity of Group 4
Metal Bis(phenolate) Catalysts.    
Capacchione, Carmine; Proto, Antonio; Ebeling, Henner; Muelhaupt, Rolf; Moeller, Klaus; Spaniol,
Thomas P.; Okuda, Jun.    Journal of the American Chemical Society  (2003),  125(17),  4964-4965.  C

Catalytic polymerization and post polymerization catalysis fifty years after the discovery of
Ziegler's catalysts.   
 Mulhaupt, Rolf.    Macromolecular Chemistry and Physics  (2003),  204(2),  289-327.  CODEN:

The 60th anniversary of the first polymer journal ("Die Makromolekulare Chemie"): Moving to
new horizons.   
 Mulhaupt, Rolf; Meisel, Ingrid.    Macromolecular Chemistry and Physics  (2003),  204(2),  199-206. 
CODEN: MCHPES  ISSN: 1022-1352. 

[251] Synthesis and in vitro efficacy of acid-sensitive poly(ethylene glycol) paclitaxel
conjugates.     Rodrigues, Paula C. A.; Scheuermann, Karin; Stockmar, Cornelia; Maier, Gerhard;
Fiebig, Heinz H.; Unger, Clemens; Muelhaupt, Rolf; Kratz, Felix.    Bioorganic & Medicinal Chemistry
Letters  (2003),  13(3),  355-360. 

[250] Near infrared reflection spectroscopy: A versatile tool for rapid characterization of olefin
copolymers and high-throughput experiments.    
Tuchbreiter, Arno; Kappler, Bernd; Stockmann, Roger; Mulhaupt, Rolf; Honerkamp, Josef.   
Macromolecular Materials and Engineering  (2003),  288(1),  29-34.

Carbonylbiscaprolactam: a versatile reagent for the synthesis of reactive oligomers.    
Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Mulhaupt, Rolf.    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (2003),  44(1),  115-116. 

PAT72
Reactive system for the 3D printing.     Pfister, Andreas; Muelhaupt, Rolf; Landers, Ruediger; Walz,
Uwe.  (Germany).    Ger. Offen.  (2003),     16 pp.  DE  10158233  A1  20030313      Application: DE 
2001-10158233  20011123.  Priority: DE  2001-10140380  20010823.  CAN 138:223101 

[249] Mechanical properties of epoxy-based hybrid composites containing glass beads and
alpha,omega-oligo(butylmethacrylate)diol.    
Schroder, N.; Konczol, L.; Doll, W.; Mulhaupt, R..    Journal of Applied Polymer Science  (2003), 
88(4),  1040-1048. 

Carbonylbiscaprolactam: A versatile reagent for the synthesis of reactive oligomers.    
Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Mulhaupt, Rolf.   Abstracts of Papers, 225th
ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003  (2003),     POLY-077. 
Publisher: American Chemical Society,  Washington, D. C  CODEN: 69DSA4  Conference; Meeting
Abstract  written in English.   

[248] High-output polymer screening: Exploiting combinatorial chemistry and data mining tools
in catalyst and polymer development.    
Tuchbreiter, Arno; Marquardt, Jurgen; Kappler, Bernd; Honerkamp, Josef; Kristen, Marc O.; Mulhaupt,
Rolf.    FMacromolecular Rapid Communications  (2003),  24(1),  47-62.  C

[247] Titanium and zirconium complexes that contain a tridentate bis(phenolato) ligand of the
[OOO]-type.    
Reimer, Valentine; Spaniol, Thomas P.; Okuda, Jun; Ebeling, Henner; Tuchbreiter, Arno; Mulhaupt,
Rolf.    Inorganica Chimica Acta  (2003),  345  221-227. 

[246] Depth profiling of latex blends of fluorinated and fluorine-free acrylates with laser-
induced secondary mass spectrometry.    
Walz, Stefanie M.; Malner, Thomas E.; Mueller, Ulrich; Muelhaupt, Rolf.    Journal of Polymer Science,
Part B: Polymer Physics  (2003),  41(4),  360-367. 

PAT71
Production and use of coated swollen polymers.    
Muelhaupt, Rolf; John, Hendrik.  (Envision Technologies G.m.b.H., Germany).    Ger. Offen.  (2003),    
20 pp.  CODEN: GWXXBX  DE  10130968  A1  20030116  Patent  written in German.    Application:
DE  2001-10130968  20010627.  CAN 138:91466   

[245] Carbonylbiscaprolactam: a versatile reagent for organic synthesis and isocyanate-free
urethane chemistry.    
Maier Steffen; Loontjens Ton; Scholtens Boudewijn; Mulhaupt Rolf     Angewandte Chemie
(International ed. in English)  (2003 Oct 27),  42(41),  5094-7. 

[244] Synthesis and in vitro efficacy of acid-sensitive poly(ethylene glycol) paclitaxel
conjugates.     Rodrigues Paula; Scheuermann Karen; Stockmar Cornelia; Maier Gerhard; Fiebig
Heinz; Unger Clemens; Mulhaupt Rolf; Kratz Felix    Bioorganic & medicinal chemistry letters  (2003
Feb 10),  13(3),  355-60. 

[243] Ancillary ligand effect on single-site styrene polymerization: isospecificity of group 4
metal bis(phenolate) catalysts.     Capacchione Carmine; Proto Antonio; Ebeling Henner; Mulhaupt
Rolf; Moller Klaus; Spaniol Thomas P; Okuda Jun    Journal of the American Chemical Society  (2003
Apr 30),  125(17),  4964-5.  J

2002


The way to isocyanate-free polyurethane. Additive for tailor-made PUR applications.    
Loontjens, Ton; Scholtens, Boudewijn; Maier, Steffen; Mulhaupt, Rolf.    DSM Research,  Geleen, 
Neth.    Kunststoffe  (2002),  92(12),  83-86.  C

[242] Morphology of stereoblock polypropylene.    
Thomann, Ralf; Thomann, Yi; Mulhaupt, R.; Kressler, Jorg; Busse, Karsten; Lilge, Dieter; Chien,
James C. W.    Journal of Macromolecular Science, Physics  (2002), 

PAT70
Process for preparing polyether polyols in the presence of phosphonium cations.    
Rexin, Ornulf; Mulhaupt, Rolf.  (Bayer Aktiengesellschaft, Germany).    U.S.  (2002),     4 pp.  US 
6469218  B1  20021022  Patent  written in English.    Application: US  2002-136208  20020501. 
Priority: DE  2001-10121807  20010504.  CAN 137:311375   

High performance epoxy-layered silicate nanocomposites.    
Kornmann, X.; Thomann, R.; Mulhaupt, R.; Finter, J.; Berglund, L. A.   Polymer Engineering and
Science  (2002),  42(9),  1815-1826. 

[241] Synthesis of amine-cured, epoxy-layered silicate nanocomposites: the influence of the
silicate surface modification on the properties.    
Kornmann, Xavier; Thomann, Ralph; Mulhaupt, Rolf; Finter, Jurgen; Berglund, Lars.    Journal of
Applied Polymer Science  (2002),  86(10),  2643-2652.  CODEN: JAPNAB  ISSN: 0021-8995.  Journal 
written in English.    CAN 138:56650    AN 2002:779487

[240] Online monitoring of silicone network formation by means of in-situ mid-infrared
spectroscopy.    
Scherble, Jonas; Ivan, Bela; Mulhaupt, Rolf.     Macromolecular Chemistry and Physics  (2002), 
203(12),  1866-1871. 

PAT69
Production of oligomeric vinyl alcohol-vinyl ester copolymers.    
Zimmermann, Joerg; Muelhaupt, Rolf.  (Bayer Aktiengesellschaft, Germany).    PCT Int. Appl.  (2002),    
25 pp.  WO  2002074819  A1  20020926  Application: WO  2002-EP2318  20020304.  Priority: DE 
2001-10112365  20010315; DE  2001-10121806  20010504.  CAN 137:248137    AN 2002:736297   
CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 

PAT68
3D-plotting process for the layer by layer production of dental materials.    
Moszner, Norbert; Burgath, Armin; Muelhaupt, Rolf; Salz, Ulrich; Rheinberger, Volker; Landers,
Ruediger.  (Ivoclar Vivadent A.-G., Liechtenstein).    Eur. Pat. Appl.  (2002),     10 pp.  CODEN: EP 
1243231  A2  20020925  Application: EP  2002-1493  20020122.  Priority: DE  2001-10114290 
20010323.  CAN 137:237813   

PAT67
Manufacture of oligomeric vinyl acetate-vinyl alcohol copolymers as polyol components for
polyurethanes.    
Zimmermann, Joerg; Muelhaupt, Rolf.  (Bayer Ag, Germany).    Ger. Offen.  (2002),     10 pp.  DE 
10112365  A1  20020919  Application: DE  2001-10112365  20010315.  CAN 137:233090   

[239] Carboxylated and Sulfonated Poly(arylene-co-arylene sulfone)s: Thermostable
Polyelectrolytes for Fuel Cell Applications.    
Poppe, D.; Frey, H.; Kreuer, K. D.; Heinzel, A.; Muelhaupt, R..    Macromolecules  (2002),  35(21), 
7936-7941. 

[238] Rapid prototyping of scaffolds derived from thermoreversible hydrogels and tailored for
applications in tissue engineering.    
Landers, Rudiger; Hubner, Ute; Schmelzeisen, Rainer; Mulhaupt, Rolf.    Biomaterials  (2002),  23(23), 
4437-4447. 

PAT66
Production of polymerizable dental compositions.    
Klee, Joachim E.; Walz, Uwe; Facher, Andreas; Weber, Christoph; Muelhaupt, Rolf; Frey, Holger;
Mueh, Ekkehard.  (Dentsply Detrey G.m.b.H., Germany).    Ger. Offen.  (2002),     12 pp.  DE 
10101537  A1  20020808  Patent  written in German.    Application: DE  2001-10101537  20010115. 
CAN 137:155779   

[237] Fabrication of soft tissue engineering scaffolds by means of rapid prototyping
techniques.
Landers, R.; Pfister, A.; Huebner, U.; John, H.; Schmelzeisen, R.; Muelhaupt, R..    Journal of
Materials Science  (2002),  37(15),  3107-3116. 

[236] Preparation of partially hydrolyzed oligo(vinyl acetate) as polyol for polyurethane
formation.     Zimmermann, Jorg; Sunder, Alexander; Mulhaupt, Rolf.     Journal of Polymer Science,
Part A: Polymer Chemistry  (2002),  40(12),  2085-2092. 

PAT65
Rubber mixture with improved mechanical characteristics containing layered silicates.    
Herrmann, Wolfram; Muelhaupt, Rolf.  (Conitech Holding GmbH, Germany).    Eur. Pat. Appl.  (2002),    
16 pp.  EP  1211282  A1  20020605    Application: EP  2001-125099  20011023.  Priority: DE  2000-
10058297  20001129.  CAN 137:7341   

[235] Impact fracture and failure behavior of in-situ polymerized, ethylene/butyl acrylate rubber
toughened polyamide-12.    
Lievana, Emiliano; Wollny, Andreas; Mulhaupt, Rolf; Karger-Kocsis, Jozsef.    Macromolecular
Materials and Engineering  (2002),  287(4),  266-271. 

[234] Lysineurethanedimethacrylate - a novel generation of amino acid-based monomers for
bone cements and tissue repair.    
Muh, Ekkehard; Zimmermann, Jorg; Kneser, Ulrich; Marquardt, Jurgen; Mulhaupt, Rolf; Stark, Bjorn.   
Biomaterials  (2002),  23(14),  2849-2854. 

[233] Polyethylene Glycol Conjugates of Methotrexate Varying in Their Molecular Weight from
MW 750 to MW 40000: Synthesis, Characterization, and Structure-Activity Relationships in Vitro
and in Vivo.    
Riebeseel, Katja; Biedermann, Elfi; Loeser, Roland; Breiter, Norbert; Hanselmann, Ralf; Muelhaupt,
Rolf; Unger, Clemens; Kratz, Felix.    Bioconjugate Chemistry  (2002),  13(4),  773-785. 

[232] Melt compounding of syndiotactic polypropylene nanocomposites containing
organophilic layered silicates and in situ formed core/shell nanoparticles.    
Kaempfer, Dirk; Thomann, Ralf; Mulhaupt, Rolf.    Polymer  (2002),  43(10),  2909-2916. 

[231] Anionic ring-opening polymerization of propylene oxide in the presence of phosphonium
catalysts.    
Rexin, Ornulf; Mulhaupt, Rolf.    Journal of Polymer Science, Part A: Polymer Chemistry  (2002), 
40(7),  864-873. 

Anionic polymerization process of lactams.    
Hoogen, Nicola; Wollny, Andreas; Faulhammer, Heike; Muelhaupt, Rolf.  (ATOFINA, Fr.).    Eur. Pat.
Appl.  (2002),     13 pp.    EP  1191050  A1  20020327      Application: EP  2001-402251  20010829. 
Priority: FR  2000-12084  20000922.  CAN 136:263633   

Rapid polymer characterization and on-line reaction monitoring.    
Tuchbreiter, Arno; Muelhaupt, Rolf; Warmbold, Andreas; Liebetraut, Peter; Kappler, Bernd;
Honerkamp, Josef.    Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 
(2002),  43(1),  285-286. 

Rapid polymer characterization and on-line reaction monitoring.    
Tuchbreiter, Arno; Warmbold, Andreas; Mulhaupt, Rolf; Kappler, Bernd; Honerkamp, Josef.   
Abstracts of Papers, 223rd ACS National Meeting, Orlando, FL, United States, April 7-11, 2002 
(2002),     POLY-343.  Publisher: American Chemical Society,  Washington, D. C  CODEN: 69CKQP 
Conference; Meeting Abstract  written in English.    AN 2002:192191    CAPLUS   (Copyright 2005
ACS on SciFinder (R)) 

[230] Poly(ethene-co-norbornene) Obtained with a Constrained Geometry Catalyst. A Study of
Reaction Kinetics and Copolymer Properties.    
Thorshaug, Knut; Mendichi, Raniero; Boggioni, Laura; Tritto, Incoronata; Trinkle, Stefan; Friedrich,
Christian; Muelhaupt, Rolf.       Macromolecules  (2002),  35(8),  2903-2911.  CODEN: MAMOBX 
ISSN: 0024-9297.

[229] Novel hydrogels as supports for in vitro cell growth: poly(ethylene glycol)- and gelatin-
based (meth)acrylamidopeptide macromonomers.    
Zimmermann, Jorg; Bittner, Katharina; Stark, Bjorn; Mulhaupt, Rolf.    Biomaterials  (2002),  23(10), 
2127-2134. 

[228] Rapid prototyping of scaffolds derived from thermoreversible hydrogels and tailored for
applications in tissue engineering.    
Landers Rudiger; Hubner Ute; Schmelzeisen Rainer; Mulhaupt Rolf    Biomaterials  (2002 Dec), 
23(23),  4437-47. 

[227] Polyethylene glycol conjugates of methotrexate varying in their molecular weight from
MW 750 to MW 40000: synthesis, characterization, and structure-activity relationships in vitro
and in vivo.    
Riebeseel Katja; Biedermann Elfi; Loser Roland; Breiter Norbert; Hanselmann Ralf; Mulhaupt Rolf;
Unger Clemens; Kratz Felix    Bioconjugate chemistry  (2002 Jul-Aug),  13(4),  773-85. 


[226] Novel hydrogels as supports for in vitro cell growth: poly(ethylene glycol)- and gelatine-
based (meth)acrylamidopeptide macromonomers.    
Zimmermann Jorg; Bittner Katharina; Stark Bjorn; Mulhaupt Rolf    Biomaterials  (2002 May),  23(10), 
2127-34.  J

2001


[225] Acrylate-terminated macromonomers by Michael addition.    
Muh, Ekkehard; Weickmann, Hans; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.    IMacromolecular
Chemistry and Physics  (2001),  202(18),  3484-3489. 

[224] Influence of lignin type on the mechanical properties of lignin based compounds.    
Nitz, Hansjorg; Semke, Hinnerk; Mulhaupt, Rolf.   Macromolecular Materials and Engineering  (2001), 
286(12),  737-743. 

Customized lignin. Use as nontoxic biostabilizers.    
Nitz, Hansjorg; Semke, Hinnerk; Mulhaupt, Rolf; Abacherli, Alfred.   Kunststoffe  (2001),  91(11),  98-
101. 

[223] Organic-inorganic hybrid nanocomposites prepared by means of sol-gel condensation of
bismethacrylatesilanes in reactive diluents.    
Muh, Ekkehard; Frey, Holger; Klee, Joachim E.; Mulhaupt, Rolf.    Advanced Functional Materials 
(2001),  11(6),  425-429. 

Nanocomposites - on the way to application.    
Mulhaupt, Rolf; Engelhardt, Thomas; Schall, Norbert.    Kunststoffe  (2001),  91(10), 
178,180,182,184,186-188,190. 

Combinatorial chemistry for the development of new catalysts and polymeric materials:
prospects and challenges.    
Tuchbreiter, Arno; Kappler, Bernd; Honerkamp, Josef; Mulhaupt, Rolf.    DECHEMA Monographien 
(2001),  137(7th International Workshop on Polymer Reaction Engineering, 2001),  323-334. 

[222] Organic-inorganic hybrid networks by the sol-gel process and subsequent
photopolymerization.    
Muh, Ekkehard; Stieger, Markus; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.  Advanced
Functional Materials  (2001),  11(6),  425-429. 

[221] Combustion behavior of EVA/fluorohectorite nanocomposites.    
Zanetti, Marco; Camino, Giovanni; Mulhaupt, Rolf.    Polymer Degradation and Stability  (2001),  74(3), 
413-417. 

PAT64
Thermoplastically processable elastomer compositions from in-situ formed elastomer
components and their use.    
Rhoenisch, Thomas; Steffl, Udo; Muelhaupt, Rolf; Barghoorn, Peter.  (Rehau A.-G. & Co., Germany).   
Eur. Pat. Appl.  (2001),     10 pp.  EP  1152034  A1  20011107   Application: EP  2001-110549 
20010428.  Priority: DE  2000-10021478  20000503.  CAN 135:345688   

[220] Miscibility of Branched Ethene Homopolymers with Iso- and Syndiotactic Polypropenes.    
Marquardt, Juergen; Thomann, Ralf; Thomann, Yi; Heinemann, Johannes; Muelhaupt, Rolf.   
Macromolecules  (2001),  34(25, k),  8669-8674. 

[219] A novel route to alpha,omega-bis(acrylamidopeptide)-terminated oligo(ethylene oxide)
and hydrogels.     Zimmermann, Jorg; Mulhaupt, Rolf.    Macromolecular Bioscience  (2001),  1(7), 
290-297.  C

PAT63
Device and method for the production of three-dimensional objects.    
Muelhaupt,  Rolf; Landers,  Ruediger; John,  Hendrik.  (Envision Technologies Gmbh, Germany).   
PCT Int. Appl.  (2001),    WO  2001078968  A1  20011025  Application: WO  2000-EP12102 
20001201.  Priority: DE  2000-10018987  20000417.  AN 2001:776620   

[218] High-Throughput Evaluation of Olefin Copolymer Composition by Means of Attenuated
Total Reflection Fourier Transform Infrared Spectroscopy.    
Tuchbreiter, Arno; Marquardt, Juergen; Zimmermann, Joerg; Walter, Philipp; Muelhaupt, Rolf; Kappler,
Bernd; Faller, Daniel; Roths, Tobias; Honerkamp, Josef.    Journal of Combinatorial Chemistry  (2001), 
3(6),  598-603. 

[217] Influence of copolymer composition and curing on toughness of isotactic polypropene
blended together with metallocene-EPDM and ethene/propene/vinylcyclohexane terpolymers.    
Walter, Philipp; Mader, Dietmar; Mulhaupt, Rolf.    Macromolecular Materials and Engineering  (2001), 
286(7),  388-397.

The polyolefin challenges: catalyst and process design, tailor-made materials, high-throughput
development and data mining.    
Tuchbreiter, Arno; Mulhaupt, Rolf.    Macromolecular Symposia  (2001),  173(Conference on Insertion
Polymerization, 2000),  1-20. 

[216] Rubber nanocomposites: morphology and mechanical properties of BR and SBR
vulcanizates reinforced by organophilic layered silicates.    
Ganter, Markus; Gronski, Wolfram; Reichert, Peter; Mulhaupt, Rolf.    Rubber Chemistry and
Technology  (2001),  74(2),  221-235. 

[215] Meso- and Microscopic Behavior of Spherical Polymer Particles Assembling at the Air-
Water Interface.    
Wolert, Elizabeth; Setz, Stefan M.; Underhill, Royale S.; Duran, Randolph S.; Schappacher, Michel;
Deffieux, Alan; Hoelderle, Matthias; Muelhaupt, Rolf.    Langmuir  (2001),  17(18),  5671-5677. 

PAT62
Metal-containing complexes from glycidol polymers for hydrogenation catalysts.    
Mecking, Stefan; Muelhaupt, Rolf.  (Germany).    Ger. Offen.  (2001),     6 pp.  DE  10104070  A1 
20010802  Application: DE  2001-10104070  20010129.  Priority: DE  2000-10004043  20000131. 
CAN 135:138992   

[214] Bismethacrylate-Based Hybrid Monomers via Michael-Addition Reactions.    
Mueh, Ekkehard; Marquardt, Juergen; Klee, Joachim E.; Frey, Holger; Muelhaupt, Rolf.     
Macromolecules  (2001),  34(17),  5778-5785. 

Nanofillers based upon organophilic layered silicates.    
Zilg, Carsten; Dietsche, Frank; Hoffmann, Botho; Dietrich, Christoph; Mulhaupt, Rolf.   
Macromolecular Symposia  (2001),  169(Fillers and Filled Polymers),  65-77.  CODEN: MSYMEC 
ISSN: 1022-1360.

[213] Hyperbranched polyesters and their application in dental composites: monomers for low
shrinking composites.   
Klee, J. E.; Schneider, C.; Holter, D.; Burgath, A.; Frey, H.; Mulhaupt, R..    Polymers for Advanced
Technologies  (2001),  12(6),  346-354. 

[212] Morphology of the transparent IPN-like system PE: (BMA-co-S).    
Borsig, Eberhard; Thomann, Ralf; Fiedlerova, Agnesa; Mulhaupt, Rolf.    Journal of Applied Polymer
Science  (2001),  81(11),  2615-2620.  C

PAT61
Impact-resistant modified thermoplastic polymer mixtures on the basis of SO2 copolymers
with an aliphatic main chain.    
Queisser, Joachim; Barghoorn, Peter; McKee, Graham Edmund; Muelhaupt, Rolf; Schnell, Rupert. 
(BASF A.-G., Germany).    Ger. Offen.  (2001),     15 pp.    DE  19962841  A1  20010705  Patent 
written in German.    Application: DE  99-19962841  19991223.  CAN 135:93383    AN 2001:488515   
CAPLUS  

[211] Reactive extrusion of polycaprolactone compounds containing wood flour and lignin.   
Nitz, Hansjorg; Semke, Hinnerk; Landers, Rudiger; Mulhaupt, Rolf.    Journal of Applied Polymer
Science  (2001),  81(8),  1972-1984. 

[210] Long chain branched polypropene prepared by means of propene copolymerization with
1,7-octadiene using MAO-activated rac-Me2Si(2-Me-4-phenyl-Ind)2ZrCl2.    
Walter, Philipp; Trinkle, Stefan; Lilge, Dieter; Friedrich, Christian; Mulhaupt, Rolf.    Macromolecular
Materials and Engineering  (2001),  286(5),  309-315. 

PAT60
Aqueous dispersions of ethylene polymers, their use and their production by emulsion
polymerization using metal complexes.    
Kristen, Marc Oliver; Manders, Lambertus; Mecking, Stefan; Bauers, Florian M.; Muelhaupt, Rolf. 
(Basf Aktiengesellschaft, Germany).    PCT Int. Appl.  (2001),     55 pp.  WO  2001044325  A1 
20010621  D  Application: WO  2000-EP10244  20001018.  Priority: DE  99-19961340  19991217. 
CAN 135:46655   

PAT59
Procedure for the homogeneous catalytic production of high-branched amorphous
polyethylene with rubber properties.    
Heinemann, Johannes; Muelhaupt, Rolf; Queisser, Joachim; Luinstra, Gerrit; Gepraegs, Michael. 
(Basf A.-G., Germany).    Ger. Offen.  (2001),     16 pp. DE  19960123  A1  20010621  Application: DE 
99-19960123  19991213. 

[209] Influence of microstructure on properties of polymers with high glass transition
temperatures obtained by ring-opening metathesis polymerization of polycyclic hydrocarbons.    
Preishuber-Pflugl, Peter; Eder, Elisabeth; Stelzer, Franz; Reisinger, Harald; Mulhaupt, Rolf; Forsyth,
John; Perena, Jose M.    Macromolecular Chemistry and Physics  (2001),  202(7),  1130-1137. 

[208] Morphological stability of polypropylene nanocomposites.    
Reichert, Peter; Hoffmann, Botho; Bock, Thorsten; Thomann, Ralf; Mulhaupt, Rolf; Friedrich, Christian.   
Macromolecular Rapid Communications  (2001),  22(7),  519-523.

[207] Influence of zirconocene structure and propene content on melt rheology of polyethene
and ethene/propene copolymers.    
Walter, Philipp; Trinkle, Stefan; Mulhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (2001),  46(2-3), 
205-213. 

[206] Formation of CdS nanoclusters in phase-separated poly(2-hydroxyethyl methacrylate)-l-
polyisobutylene amphiphilic conetworks.    
Scherble, Jonas; Thomann, Ralf; Ivan, Bela; Mulhaupt, Rolf.    Journal of Polymer Science, Part B:
Polymer Physics  (2001),  39(12),  1429-1436. 

Correlations between chain branching, morphology development and polymer properties of
polyethenes.    
Walter, Philipp; Heinemann, Johannes; Ebeling, Henner; Mader, Dietmar; Trinkle, Stefan; Mulhaupt,
Rolf.    Organometallic Catalysts and Olefin Polymerization  (2001),     317-326.  Publisher: Springer-
Verlag,  Berlin, Germany  CODEN: 69BGVD  Conference; General Review  written in English.    CAN
135:318724   

[205] Carbohydrate analogue polymers by ring opening metathesis polymerisation (ROMP) and
subsequent catalytic dihydroxylation.    
Meier, Stefan; Stelzer, Franz; Reisinger, Harald; Haag, Rainer; Mecking, Stefan; Mulhaupt, Rolf.   
Chemical Communications (Cambridge, United Kingdom)  (2001),   (9),  855-856. 

Copolymerization of arylchlorides by nickel catalyzed coupling: novel polyelectrolytes.    
Poppe, D.; Frey, H.; Heinzel, A.; Mulhaupt, R..    Polymeric Materials Science and Engineering 
(2001),  84  333-334. 

Copolymerization of arylchlorides by nickel-catalyzed coupling: Novel polyelectrolytes.    
Poppe, Dirk; Frey, Holger; Heinzel, Angelika; Mulhaupt, Rolf.    Abstracts of Papers, 221st ACS
National Meeting, San Diego, CA, United States, April 1-5, 2001  (2001),     PMSE-189.  CODEN:
69FZD4  Journal;

[203] Thermal behavior of poly(propylene) layered silicate nanocomposites.    
Zanetti, Marco; Camino, Giovanni; Reichert, Peter; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (2001),  22(3),  176-180. 

[202] Influence of stereoirregularities on the formation of the gamma-phase in isotactic
polypropene.     Thomann, R.; Semke, H.; Maier, R.-D.; Thomann, Y.; Scherble, J.; Mulhaupt, R.;
Kressler, J.    Polymer  (2001),  42(10),  4597-4603. 

[201] Synthesis and thermal behavior of layered silicate-EVA nanocomposites.    
Zanetti, M.; Camino, G.; Thomann, R.; Mulhaupt, R..    Polymer  (2001),  42(10),  4501-4507. 

PAT58
Siloxane-containing macromonomers and dental composites thereof.    
Klee, Joachim E.; Walz, Uwe; Fiedler, Jurgen; Mulhaupt, Rolf; Frey, Holger; Muh, Ekkehardt. 
(Dentsply International Inc., USA).    PCT Int. Appl.  (2001),     30 pp.  WO  2001008639  A1 
20010208  Application: WO  2000-US20348  20000726.  Priority: US  99-146093  19990728.  CAN
134:152704   

PAT57
Nanocomposites containing organophilic layered silicates.   
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Vantico A.-G., Switz.).    PCT Int. Appl.  (2001),     21
pp.  WO  2001004205  A1  20010118  Designated States W: US.  Designated States RW: AT, BE,
CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE.  Patent  written in English.   
Application: WO  2000-EP6422  20000706.  Priority: CH  99-1288  19990713.  CAN 134:116625   


PAT56
Filler mixture for thermosetting resin to form nanocomposite with improved mech. properties.    
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Vantico A.-G., Switz.).    PCT Int. Appl.  (2001),     24
pp.  WO  2001004193  A1  20010118  Application: WO  2000-EP6424  20000706.  Priority: CH  99-
1289  19990713.  CAN 134:116623   

PAT55
Rubber-modified polymer mixtures, their production and their use.    
Gepraegs, Michael; Queisser, Joachim; Muelhaupt, Rolf; Schnell, R.  (BASF A.-G., Germany).    Ger.
Offen.  (2001),     8 pp.  DE  19931187  A1  20010111  Patent  written in German.    Application: DE 
99-19931187  19990707.  CAN 134:101637   

[200] High-throughput evaluation of olefin copolymer composition by means of attenuated total
reflection Fourier tranform infrared spectroscopy.    
Tuchbreiter A; Marquardt J; Zimmermann J; Walter P; Mulhaupt R; Kappler B; Faller D; Roths T;
Honerkamp J    Journal of combinatorial chemistry  (2001 Nov-Dec),  3(6),  598-603.  J

2000


 [199] Organic/inorganic hybrid materials and nanocomposites based upon layered silicates
modified with cyclic amidines.    
Zilg, Carsten; Thomann, Ralf; Baumert, Martin; Finter, Jurgen; Mulhaupt, Rolf.    Macromolecular
Rapid Communications  (2000),  21(17),  1214-1219. 

PAT54
Method for producing graft copolymers containing an elastic backbone.     Mulhaupt, Rolf;
Heinemann, Johannes; Baumert, Martin; Queisser, Joachim; Geprags, Michael.  (BASF A.-G.,
Germany).    PCT Int. Appl.  (2000),     43 pp.  WO  2000077060  A1  20001221  DPriority: DE  99-
19927347  19990616.  CAN 134:57145   

PAT53
Production of polysulfones with aliphatic main chain.    
Queisser, Joachim; Gepraegs, Michael; Erbes, Joerg; Baumert, Martin; Muelhaupt, Rolf.  (BASF A.-G.,
Germany).    Ger. Offen.  (2000),     8 pp.  DE  19926778  A1  20001214  Application: DE  99-
19926778  19990611.  CAN 134:42597    AN 2000:880628    CAPLUS   (Copyright 2005 ACS on
SciFinder (R)) 

[198] Desktop manufacturing of complex objects, prototypes and biomedical scaffolds by
means of computer-assisted design combined with computer-guided 3D plotting of polymers
and reactive oligomers.    
Landers, Rudiger; Mulhaupt, Rolf. Macromolecular Materials and Engineering  (2000),  282  17-21. 

[197] Rheology and processing of metallocene-based polyolefins.    
Friedrich, Chr.; Eckstein, A.; Stricker, F.; Mulhaupt, R..    Editor(s): Scheirs, John; Kaminsky, Walter.   
Metallocene-Based Polyolefins  (2000),  2  399-417.  Publisher: John Wiley & Sons Ltd.,  Chichester,
UK  CODEN: 69AHES  Conference; General Review  written in English.    CAN 134:208376  

[196] Influence of metallocene structures on molecular and supermolecular architectures of
polyolefins.    
Fischer, D.; Jungling, S.; Schneider, M. J.; Suhm, J.; Mulhaupt, R..    Editor(s): Scheirs, John;
Kaminsky, Walter.    Metallocene-Based Polyolefins  (2000),  1  103-117.  Publisher: John Wiley &
Sons Ltd.,  Chichester, UK  CODEN: 69AHES  Conference; General Review  written in English.    CAN
134:208144   

[195] The influence of silicate modification and compatibilizers on mechanical properties and
morphology of anhydride-cured epoxy nanocomposites.    
Zilg, Carsten; Thomann, Ralf; Finter, Jurgen; Mulhaupt, Rolf.    Macromolecular Materials and
Engineering  (2000),  280/281  41-46. 

PAT52
Synthesis of melamine-modified organophilic layered phyllosilicates in fabrication of
nanocomposites and molded polymer parts.   
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Vantico A.-G., Switz.).    PCT Int. Appl.  (2000),     32
pp.  CODEN: PIXXD2  WO  2000044669  A1  20000803  Designated States W: BR, CN, JP, KR, US. 
Designated States RW: AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE. 
Patent  written in German.    Application: WO  2000-EP480  20000122.  Priority: CH  99-160 
19990128.  CAN 133:122434   

[194] Development of acid-sensitive platinum(II) complexes with protein-binding properties.    
Schutte, M. T.; Mulhaupt, R.; Kratz, F.  Metal-Based Drugs  (2000),  7(2),  89-100. 

PAT51
Method for producing highly branched glycidol-based polyols.    
Sunder, Alexander; Mulhaupt, Rolf.  (Bayer Aktiengesellschaft, Germany).    PCT Int. Appl.  (2000),    
13 pp.  Application: WO  99-EP9773  19991210.  Priority: DE  98-19859300  19981222; DE  99-
19947631  19991004.  CAN 133:74520   

Hyperbranched polyglycerols by ring-opening multibranching polymerization.    
Sunder, A.; Frey, H.; Mulhaupt, R..    Macromolecular Symposia  (2000),  153(Recent Advances in
Ring Opening (Metathesis) Polymerization),  187-196. 

PAT50
Dental compositions containing polycyanoacrylates.     Klee, Joachim E.; Walz, Uwe; Mulhaupt,
Rolf.  (Dentsply International Inc., USA).    PCT Int. Appl.  (2000),     24 pp.  WO  2000033793  A1 
20000615  DApplication: WO  99-US29367  19991210.  Priority: US  98-111864  19981211.  CAN
133:48969    A

[193] Multi-arm star block copolymers based on ?-caprolactone with hyperbranched
polyglycerol core.    
Burgath, Armin; Sunder, Alexander; Neuner, Ingo; Mulhaupt, Rolf; Frey, Holger.    Macromolecular
Chemistry and Physics  (2000),  201(7),  792-797. 

Synthesis of methacrylated macromonomers for biocompatible hydrogels.    
Mulhaupt, Rolf; Zimmermann, Jorg.    Book of Abstracts, 219th ACS National Meeting, San Francisco,
CA, March 26-30, 2000  (2000),    

Bismethacrylate-based hybrid monomers for advanced dental composites.    
Muh, Ekkehard; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.   Book of Abstracts, 219th ACS
National Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-165.  Publisher: American
Chemical Society,  Washington, D. C 

Polypropylene nanocomposites based on organophilic-layered silicates.    
Reichert, Peter; Zilg, Carsten; Mulhaupt, Rolf.    Book of Abstracts, 219th ACS National Meeting, San
Francisco, CA, March 26-30, 2000  (2000),     PMSE-137.  Publisher: American Chemical Society, 
Washington, D. C  CODEN: 69CLAC  Conference;

Epoxy nanocomposites based on organophilic-layered silicates: Improving
toughness/stiffness/strength balance.    
Zilg, Carsten; Mulhaupt, Rolf; Thomann, Ralf; Finter, Jurgen.    Book of Abstracts, 219th ACS National
Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-136.  Publisher: American
Chemical Society,  Washington, D. C 

Morphology, mechanical properties, and mechanism of reinforcement of rubber
nanocomposites.    
Ganter, Markus; Reichert, Peter; Mulhaupt, Rolf; Gronski, Wolfram.    Book of Abstracts, 219th ACS
National Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-099.  Publisher: American
Chemical Society,  Washington,

Acrylic nanocomposites containing organoclay nanofillers: Morphology development,
properties, and fracture behavior.    
Mulhaupt, Rolf; Dietsche, Frank; Doell, Wilhelm; Thomann, Ralf.    Book of Abstracts, 219th ACS
National Meeting, San Francisco, CA, March 26-30, 2000  (2000),     PMSE-097.  Publisher: American
Chemical Society,  Washington, D. C 

Complex hyperbranched molecular architectures based on polyether polyols as versatile
alternative to dendrimers.    
Frey, Holger; Mulhaupt, Rolf; Sunder, Alexander.    Book of Abstracts, 219th ACS National Meeting,
San Francisco, CA, March 26-30, 2000  (2000),    

Morphologies and miscibilities of polypropene with random poly(ethene-co-1-butene).    
Thomann, Yi; Suhm, Jurgen; Thomann, Ralf; Maier, Ralf-Dieter; Mulhaupt, Rolf; Bar, Georg.   
Macromolecular Symposia  (2000),  149(6th European Symposium on Polymer Blends, 1999),  125-
129.

[192] Highly branched polyethylene graft copolymers prepared by means of migratory insertion
polymerization combined with TEMPO-mediated controlled radical polymerization.    
Baumert, Martin; Heinemann, Johannes; Thomann, Ralf; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (2000),  21(6),  271-276.

[191] Synthesis of poly(glycerol)-block-poly(methyl acrylate) multi-arm star polymers.    
Maier, Steffen; Sunder, Alexander; Frey, Holger; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (2000),  21(5),  226-230. 

[190] Influence of compatibilizers on the surface hardness, water uptake, and the mechanical
properties of poly(propylene) wood flour composites prepared by reactive extrusion.    
Nitz, Hansjorg; Reichert, Peter; Romling, Hartmut; Mulhaupt, Rolf.    Macromolecular Materials and
Engineering  (2000),  276/277  51-58. 

[189] Short and long chain branching of polyethene prepared by means of ethene
copolymerization with 1-eicosene using MAO activated Me2Si(Me4Cp)(NtBu)TiCl2.    
Walter, Philipp; Trinkle, Stefan; Suhm, Jurgen; Mader, Dietmar; Friedrich, Christian; Mulhaupt, Rolf.   
Macromolecular Chemistry and Physics  (2000),  201(5),  604-612.  C

PAT49
Polyolefin nanocomposites.    
Muelhaupt, Rolf; Heinemann, Johannes; Reichert, Peter; Gepraegs, Michael; Queisser, Joachim. 
(BASF A.-G., Germany).    Ger. Offen.  (2000),     20 pp.  DE  19846314  A1  20000413  Patent 
written in German.    Application: DE  98-19846314  19981008.  CAN 132:279669   

[188] Melt modification of poly(styrene-co-maleic anhydride) with alcohols in the presence of
1,3-Oxazolines.   
 Bruch, Matthias; Mader, Dietmar; Bauers, Florian; Loontjens, Ton; Mulhaupt, Journal of Polymer
Science, Part A: Polymer Chemistry  (2000),  38(8),  1222-1231. 

[187] Poly(propylene)/organoclay nanocomposite formation: influence of compatibilizer
functionality and organoclay modification.    
Reichert, Peter; Nitz, Hansjorg; Klinke, Stefan; Brandsch, Rainer; Thomann, Ralf; Mulhaupt, Rolf.   
Macromolecular Materials and Engineering  (2000),  275  8-17. 

[186] Toughening of epoxy resins modified with polyetherester block copolymers: the
influence of modifier molecular architecture on mechanical properties.    
Hofflin, F.; Konczol, L.; Doll, W.; Morawiec, J.; Mulhaupt, R..    Journal of Applied Polymer Science 
(2000),  76(5),  623-634.

Polypropylene nanocomposites based upon organophilic layered silicates.    
Reichert, Peter; Nitz, Hansjorg; Klinke, Stefan; Thomann, Ralf; Brandsch, Rainer; Zilg, Carsten;
Mulhaupt, Rolf.   Polymeric Materials Science and Engineering  (2000),  82  251-252. 

Epoxy nanocomposites based upon organophilic layered silicates: improving
toughness/stiffness/strength balance.    
Zilg, Carsten; Mulhaupt, Rolf; Thomann, Ralf; Finter, Jurgen.   Polymeric Materials Science and
Engineering  (2000),  82  249-250.  CODEN: PMSEDG  ISSN: 0743-0515. 

Morphology, mechanical properties and mechanism of reinforcement of rubber
nanocomposites.    
Ganter, Markus; Reichert, Peter; Mulhaupt, Rolf; Gronski, Wolfram.    Polymeric Materials Science and
Engineering  (2000),  82  228-229. 

Acrylic nanocomposites containing organoclay nanofillers: morphology development,
properties and fracture behavior.    
Dietsche, Frank; Thomann, Ralf; Doell, Wilhelm; Mulhaupt, Rolf.    Polymeric Materials Science and
Engineering  (2000),  82  222-223. 

Bismethacrylate-based hybrid monomers for advanced dental composites.    
Muh, Ekkehard; Klee, Joachim E.; Frey, Holger; Mulhaupt, Rolf.     Polymeric Materials Science and
Engineering  (2000),  82  99-100. 

[185] Relationship between morphology and mechanical properties of polypropylene/ethene-
co-butene binary blends with various butene contents.    
Mouzakis, D. E.; Mader, D.; Mulhaupt, R.; Karger-Kocsis, J.    Journal of Materials Science  (2000), 
35(5),  1219-1230.  CODEN: JMTSAS  ISSN: 0022-2461.  Journal  written in English.   

[184] Hyperbranched polyether polyols. A modular approach to complex polymer architectures.    
Sunder, Alexander; Mulhaupt, Rolf; Haag, Rainer; Frey, Holger.   Advanced Materials (Weinheim,
Germany)  (2000),  12(3),  235-239. 

[183] Influence of n-Alkyl Branches on Glass-Transition Temperatures of Branched
Polyethylenes Prepared by Means of Metallocene- and Palladium-Based Catalysts.    
Maeder, Dietmar; Heinemann, Johannes; Walter, Philipp; Muelhaupt, Rolf.    Macromolecules  (2000), 
33(4),  1254-1261. 

[182] Synthesis and Thermal Behavior of Esterified Aliphatic Hyperbranched Polyether Polyols.    
Sunder, Alexander; Bauer, Thorsten; Muelhaupt, Rolf; Frey, Holger.    Macromolecules  (2000),  33(4), 
1330-1337. 

[181] Chiral Hyperbranched Dendron Analogues.    
Sunder, Alexander; Muelhaupt, Rolf; Haag, Rainer; Frey, Holger.    Macromolecules  (2000),  33(2), 
253-254.  CODEN: MAMOBX  ISSN: 0024-9297.  J

[180] Functional Poly(ethylene oxide) Multiarm Star Polymers: Core-First Synthesis Using
Hyperbranched Polyglycerol Initiators.    
Knischka, Ralf; Lutz, Pierre J.; Sunder, Alexander; Muelhaupt, Rolf; Frey, Holger.    Macromolecules 
(2000),  33(2),  315-320.

[179] Hyperbranched Polyether-Polyols Based on Polyglycerol: Polarity Design by Block
Copolymerization with Propylene Oxide.    
Sunder, Alexander; Muelhaupt, Rolf; Frey, Holger.    Macromolecules  (2000),  33(2),  309-314. 

[178] Translucent acrylic nanocomposites containing anisotropic laminated nanoparticles
derived from intercalated layered silicates.    
Dietsche, Frank; Thomann, Yi; Thomann, Ralf; Mulhaupt, Rolf.    Journal of Applied Polymer Science 
(2000),  75(3),  396-405.  CODEN: JAPNAB  ISSN: 0021-8995.  Journal  written in English.    CAN
132:94279    AN 1999:785116    CAPLUS   (Copyright 2005 ACS

1999


[177] Transition metal catalyzed olefin, cycloolefin, and styrene polymerization.    
Okuda, Jun; Mulhaupt, Rolf.    Editor(s): Schlueter, A.-Dieter.    Materials Science and Technology 
(1999),  20(Synthesis of Polymers),  123-162.  Publisher: Wiley-VCH Verlag GmbH,  Weinheim,
Germany  CODEN: 58AMAL  Conference; General Review  written in English.   

Materials Week '98, Volume VIII: Symposium 10, Polymers; Symposium 14, Simulation of
Polymers.  (Werkstoffwoch '98 Band VIII Symposium 10 Polymere, Symposium 14 Simulation
Polymere) 
Michaeli, Walter; Mulhaupt, Rolf; Moller, Martin; Riedel, Hermann; Editors.    Germany.    (1999),    
273 pp.  Publisher: (Wiley-VCH,  Weinheim, Germany)  Book  written in German.    CAN 132:251869   

Branched bismethacrylates - a variable modular system for low-shrinkage matrix system.    
Klee, J. E.; Holter, D.; Frey, H.; Mulhaupt, R..    Dentsply GmbH,  Konstanz,  Germany.  Editor(s):
Michaeli, Walter.    Werkstoffwoche '98, Band VIII: Symposium 10, Polymere; Symposium 14,
Simulation Polymere, Munich, Sept., 1998  (1999),  Meeting Date 1998,     181-186.  Publisher: Wiley-
VCH Verlag GmbH,  Weinheim, Germany  C

Nickel(II) and palladium(II) complexes with 1,4-diaza-1,3-butadiene ligands as catalysts for
polymerization of ethene and 1-olefins.    
Schleis, Thomas; Heinemann, Johannes; Spaniol, Thomas P.; Mulhaupt, Rolf; Okuda, Jun.   
JEditor(s): Michaeli, Walter.    Werkstoffwoche '98, Band VIII: Symposium 10, Polymere; Symposium
14, Simulation Polymere, Munich, Sept., 1998  (1999),  Meeting Date 1998,     99-102.  Publisher:
Wiley-VCH Verlag GmbH,  Weinheim, Germany 

Fascinating transition metal catalysis: new polymer architectures in copolymers with polar
monomers.    
Heinemann, J.; Mulhaupt, R.; Brinkmann, P. H. P.; Luinstra, G. A.; Wursche, R.; Rieger, B.; Geprags,
M.   Editor(s): Michaeli, Walter.    Werkstoffwoche '98, Band VIII: Symposium 10, Polymere;
Symposium 14, Simulation Polymere, Munich, Sept., 1998  (1999),  Meeting Date 1998,     95-98. 
Publisher: Wiley-VCH Verlag GmbH,  Weinheim, Germany 

[176] Thermal properties and flammability of acrylic nanocomposites based upon organophilic
layered silicates.    
Dietsche, F.; Mulhaupt, R..   Polymer Bulletin (Berlin)  (1999),  43(4-5),  395-402. 

[175] Acid-sensitive polyethylene glycol conjugates of doxorubicin: preparation, in vitro
efficacy and intracellular distribution.    
Rodrigues, Paula C. A.; Beyer, Ulrich; Schumacher, Peter; Roth, Thomas; Fiebig, Heinz H.; Unger,
Clemens; Messori, Luigi; Orioli, PierLuigi; Paper, Dietrich H.; Mulhaupt, Rolf; Kratz, Felix.    Bioorganic
& Medicinal Chemistry  (1999),  7(11),  2517-2524. 

[174] Molecular nanocapsules based on amphiphilic hyperbranched polyglycerols.    
Sunder, Alexander; Kramer, Michael; Hanselmann, Ralf; Mulhaupt, Rolf; Frey, Holger.    Angewandte
Chemie, International Edition  (1999),  38(23),  3552-3555. 

[173] Novel polypropylene materials.    
Walter, Philipp; Mader, Dietmar; Reichert, Peter; Mulhaupt, Rolf.    Journal of Macromolecular
Science, Pure and Applied Chemistry  (1999),  A36(11),  1613-1639. 

PAT48
Liquid crystalline (meth)acrylate compounds, composition and method.    
Klee, Joachim E.; Frey, Holger; Holter, Dirk; Mulhaupt, Rolf.  (Dentsply G.m.b.H., Germany).    U.S. 
(1999),     23 pp., Cont.-in-part of U.S. Ser. No. 543,950, abandoned. US  5998499  A  19991207 
Patent  written in English.    Application: US  96-723443  19961007.  Priority: US  94-217998 
19940325; US  94-231535  19940422; US  95-543950  19951017.  CAN 132:15678   

[172] Nanostructure Formation via Association of Tectons in Amorphous Polymer Matrices.    
Fuchs, Konrad; Bauer, Thorsten; Thomann, Ralf; Wang, Chun; Friedrich, Christian; Muelhaupt, Rolf.   
IMacromolecules  (1999),  32(25),  8404-8412. 

[171] Energy transfer from phenanthrene to anthracene in a dye-labeled (ethylene-methyl
acrylate) copolymer.    
Liu, Ronghua; Moffitt, Matthew; Winnik, Mitchell A.; Heinemann, Johannes; Mulhaupt, Rolf.    Journal
of Polymer Science, Part A: Polymer Chemistry  (1999),  37(22),  4169-4175.  CODEN: J

[170] Hyperbranched polyether polyols with liquid crystalline properties.    
Sunder, Alexander; Quincy, Marie-France; Mulhaupt, Rolf; Frey, Holger.      Angewandte Chemie,
International Edition  (1999),  38(19),  2928-2930.  C

PAT47
Method for producing copolymers from functional olefinically unsaturated monomers and
nonpolar olefinically unsaturated compounds, and uses for the copolymers.    
Geprags, Michael; Mulhaupt, Rolf; Heinemann, Johannes.  (BASF Aktiengesellschaft, Germany).   
PCT Int. Appl.  (1999),     33 pp.  WO  9947569  A1  19990923  Priority: DE  98-19812124  19980319. 
CAN 131:258066   

[169] Combined ultramicrotomy for AFM and TEM using a novel sample holder.    
Thomann, Y.; Thomann, R.; Bar, G.; Ganter, M.; Machutta, B.; Mulhaupt, R..    Journal of Microscopy
(Oxford)  (1999),  195(2),  161-163.  CODEN: JMICAR  ISSN: 0022-2720.  J

[168] Influence of comonomer incorporation on morphology and thermal and mechanical
properties of blends based upon isotactic metallocene-polypropene and random ethene/1-
butene copolymers.    
Mader, Dietmar; Thomann, Yi; Suhm, Jurgen; Mulhaupt, Rolf.   Journal of Applied Polymer Science 
(1999),  74(4),  838-848. 

Transition metal catalyzed ethene homo- and copolymerization in the presence of exfoliated
organophilic layered silicates and polyolefin nanocomposite formation.    
Heinemann, Johannes; Reichert, Peter; Thomann, Ralf; Mulhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1999),  40(2),  788-789.  CODEN:
ACPPAY  ISSN: 0032-3934.  Journal  written in English.    C

The influence of n-alkyl branches on thermal properties of polyethylenes prepared by means of
metallocene- and palladium-based catalysts.    
Mader, Dietmar; Walter, Philipp; Heinemann, Johannes; Mulhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1999),  40(2),  719-720.  C

Synthesis of highly branched polyethylene graft copolymers by combination of palladium-
diazadiene catalyzed and tempomediated polymerization.    
Baumert, Martin; Heinemann, Johannes; Thomann, Ralf; Mulhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1999),  40(2),  466-467.  CODEN: A

PAT46
Organophilic phyllosilicates for filling polymeric materials.    
Zilg, Carsten; Mulhaupt, Rolf; Finter, Jurgen.  (Ciba Specialty Chemicals Holding Inc., Switz.).    PCT
Int. Appl.  (1999),     59 pp.  WO  9942518  A2  19990826  DPriority: CH  98-408  19980220.  CAN
131:171089    AN 1999:549317   

Synthesis of highly branched polyethylene graft copolymers by combination of palladium
diazadiene catalyzed and TEMPO-mediated polymerization.    
Mulhaupt, Rolf; Baumert, Martin; Heinemann, Johannes; Thomann, Ralf.    Book of Abstracts, 218th
ACS National Meeting, New Orleans, Aug. 22-26  (1999),     POLY-519.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 67ZJA5  Conference; Meeting Abstract  written in
English.   

Transition-metal-catalyzed ethene homo- and copolymerization in the presence of exfoliated
organophilic layered silicates and polyolefin nanocomposite formation.    
Mulhaupt, Rolf; Heinemann, Johannes; Reichert, Peter; Thomann, Ralf.     Book of Abstracts, 218th
ACS National Meeting, New Orleans, Aug. 22-26  (1999),     POLY-180.  Publisher: American
Chemical Society,  Washington,

Influence of -alkyl branches on thermal properties of polyethylenes prepared by means of
metallocene- and palladium-based catalysts.    
Mulhaupt, Rolf; Mader, Dietmar; Walter, Philipp; Heinemann, Johannes.    Book of Abstracts, 218th
ACS National Meeting, New Orleans, Aug. 22-26  (1999),     POLY-124.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 67ZJA5  Conference; Meeting Abstract  written in
English.   

[167] Synthesis and characterization of polyesteramides derived from an oxazoline-functional
alcohol and dicarboxylic acid anhydrides.    
Bruch, Matthias; Burgath, Armin; Loontjens, Ton; Mulhaupt, Rolf.    Journal of Polymer Science, Part
A: Polymer Chemistry  (1999),  37(16),  3367-3376. 

[166] Polyolefin nanocomposites formed by melt compounding and transition metal-catalyzed
ethene homo- and copolymerization in the presence of layered silicates.    
Heinemann, Johannes; Reichert, Peter; Thomann, Ralf; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (1999),  20(8),  423-430. 

PAT45
Preparation of heterocyclic group-functionalized azo compounds as radical polymerization
initiators.    
Muelhaupt, Rolf; Baumert, Martin; Gepraegs, Michael.  (BASF A.-G., Germany).    Ger. Offen.  (1999),    
16 pp.  DE  19802335  A1  19990729  Patent  written in German.    Application: DE  98-19802335 
19980123.  CAN 131:144593   

[165] Impact-modified poly(styrene-co-acrylonitrile) blends containing both oxazoline-
functionalized poly(ethene-co-1-octene) elastomers and poly(styrene-co-maleic anhydride) as
compatibilizer.     Mader, Dietmar; Kressler, Jorg; Mulhaupt, Rolf.    Journal of Applied Polymer
Science  (1999),  73(9),  1685-1695.  C

Moving forces for new technologies. Polymers for the 21st Century.    
Mulhaupt, Rolf.   Plastverarbeiter  (1999),  50(5),  68-70,72,74,76,79-80,82,84,86.

[164] Controlled Synthesis of Hyperbranched Polyglycerols by Ring-Opening Multibranching
Polymerization.    
Sunder, Alexander; Hanselmann, Ralf; Frey, Holger; Muelhaupt, Rolf.    Macromolecules  (1999), 
32(13),  4240-4246. 

[163] Silsesquioxane-Based Amphiphiles.    
Knischka, Ralf; Dietsche, Frank; Hanselmann, Ralf; Frey, Holger; Muelhaupt, Rolf; Lutz, Pierre J.   
Langmuir  (1999),  15(14),  4752-4756. 

PAT44
Method for nucleation of crystallizable polymers.    
Roesch, Joachim; Muelhaupt, Rolf; Bauer, Thorsten.  (BASF A.-G., Germany).    Ger. Offen.  (1999),    
12 pp.  C DE  19750371  A1  19990520  Patent  written in German.    Application: DE  97-19750371 
19971114.  CAN 131:6018  

[162] Styrene-vinylferrocene random and block copolymers by TEMPO-mediated radical
polymerization.    
Baumert, Martin; Frohlich, Jorg; Stieger, Markus; Frey, Holger; Mulhaupt, Rolf; Plenio, Herbert.   
IMacromolecular Rapid Communications  (1999),  20(4),  203-209. 

Hermann Staudinger and the development of macromolecular chemistry.    
Mulhaupt, Rolf.    Freiburg/Br.,  Germany.    Nachrichten aus Chemie, Technik und Laboratorium 
(1999),  47(4),  413-414,416-418. 

Nucleation of metallocene polypropylene (mPP).    
Maier, Ralph-Dieter; Friedrich, Christian; Mulhaupt, Rolf.    Kunststoffe  (1999),  89(4),  89-90,92-94. 

A versatile route to hyperbranched polyglycerols and new branched polymer architectures.    
Sunder, A.; Frey, H.; Mulhaupt, R..    Polymeric Materials Science and Engineering  (1999),  80  203-
204. 

[161] Synthesis of Oxazoline-Terminated Polystyrene via Controlled-Radical Polymerization.    
Baumert, Martin; Zimmermann, Joerg; Scherble, Jonas; Muelhaupt, Rolf; Kressler, Joerg.   
Macromolecules  (1999),  32(8),  2503-2510. 

PAT43
Thermoplastic molding compositions based on polyesters and polycarbonates.    
Weber, Martin; Muelhaupt, Rolf.  (BASF A.-G., Germany).    Ger. Offen.  (1999),     16 pp.  DE 
19739686  A1  19990311 Application: DE  97-19739686  19970910.  CAN 130:238266   

[160] Morphology and toughness/stiffness balance of nanocomposites based upon anhydride-
cured epoxy resins and layered silicates.   
Zilg, Carsten; Muelhaupt, Rolf; Finter, Juergen.    Macromolecular Chemistry and Physics  (1999), 
200(3),  661-670.  CODEN:

[159] Monomers for low shrinking composites. Part 2. Synthesis of branched methacrylates
and their application in dental composites.   
Klee, Joachim E.; Neidhart, Frank; Flammersheim, Hans-Juergen; Muelhaupt, Rolf.    Macromolecular
Chemistry and Physics  (1999),  200(3),  517-523. 

[158] Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and
Tapping Mode Atomic Force Microscopy of Film Formation.    
Linemann, Reinhard F.; Malner, Thomas E.; Brandsch, Rainer; Bar, Georg; Ritter, Wolfgang;
Muelhaupt, Rolf.    Macromolecules  (1999),  32(6),  1715-1721. 

[157] Copolymerization of ethene with methyl acrylate and ethyl 10-undecenoate using a
cationic palladium diimine catalyst.    
Heinemann, Johannes; Muelhaupt, Rolf; Brinkmann, Peter; Luinstra, Gerrit.    Macromolecular
Chemistry and Physics  (1999),  200(2),  384-389.  C

A versatile route to hyperbranched polyglycerols and new branched polymer architectures.    
Sunder, A.; Frey, H.; Mulhaupt, R..    F Book of Abstracts, 217th ACS National Meeting, Anaheim,
Calif., March 21-25  (1999),     PMSE-234.  Publisher: American Chemical Society,  Washington, D. C 
CODEN: 67GHA6  Conference; Meeting Abstract  written in English.   

[156] Glass Transition Temperature Depression of Elastomers Blended with Poly(propene)s of
Different Stereoregularities.    
Maeder, Dietmar; Bruch, Matthias; Maier, Ralph-Dieter; Stricker, Florian; Muelhaupt, Rolf.   
Macromolecules  (1999),  32(4),  1252-1259. 

[155] Addition-fragmentation free radical polymerization in the presence of olefinic dithioethers
as chain transfer agents.    
Sunder, Alexander; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1999),  200(1),  58-
64. 

PAT42
Monodisperse dilatant polymer dispersions and their preparation.    
Rupaner, Robert; Horn, Frank M.; Richtering, Walter; Muelhaupt, Rolf.  (BASF A.-G., Germany).   
Ger. Offen.  (1999),     8 pp.  DE  19757669  A1  19990107  Application: DE  97-19757669  19971223. 
CAN 130:111035   

[154] Polyurethane nanocomposites containing laminated anisotropic nanoparticles derived
from organophilic layered silicates.    
Zilg, Carsten; Thomann, Ralf; Muelhaupt, Rolf; Finter, Juergen.    Advanced Materials (Weinheim,
Germany)  (1999),  11(1),  49-52.  CODEN: ADVMEW  ISSN: 0935-9648.  J

[153] Acid-sensitive polyethylene glycol conjugates of doxorubicin: preparation, in vitro
efficacy and intracellular distribution.   
Rodrigues P C; Beyer U; Schumacher P; Roth T; Fiebig H H; Unger C; Messori L; Orioli P; Paper D H;
Mulhaupt R; Kratz F    TBioorganic & medicinal chemistry  (1999 Nov),  7(11),  2517-24. 

[152] Combined ultramicrotomy for AFM and TEM using a novel sample holder.    
Thomann Y; Thomann R; Bar G; Ganter M; MacHutta B; Mulhaupt R    Journal of microscopy  (1999
Aug),  195 ( Pt 2) 161-3.  J.

1998


[151] Influence of glass bead fillers on phase transitions of syndiotactic polypropene.    
Stricker, F.; Maier, R.-D.; Bruch, M.; Thomann, R.; Mulhaupt, R..    Polymer  (1998),  Volume Date
1999,  40(8),  2077-2084. 

[151] Ni(II) and Pd(II) complexes of camphor-derived diazadiene ligands: steric bulk tuning and
ethylene polymerization.   
 Schleis, Thomas; Heinemann, Johannes; Spaniol, Thomas P.; Mulhaupt, Rolf; Okuda, Jun.  
Inorganic Chemistry Communications  (1998),  1(11),  431-434. 

[150] Branched macromonomers and their application in dental composites. Monomers for
low-shrinking composites. Part 3.    
Klee, Joachim E.; Walz, Uwe; Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf.    Angewandte
Makromolekulare Chemie  (1998),  260  71-75. 

Polymer and rubber nanocomposites based upon layered silicates.    
Zilg, Carsten; Reichert, Peter; Dietsche, Frank; Engelhardt, Thomas; Muelhaupt, Rolf.    Kunststoffe 
(1998),  88(10),  1812-1813,1916,1818,1820.  C

[149] Influence of morphology on the toughening mechanisms of polypropylene modified with
core-shell particles derived from thermoplastic elastomers.   
Kim, G. M.; Michler, G. H.; Gahleitner, M.; Mulhaupt, R..    Polymers for Advanced Technologies 
(1998),  9(10-11),  709-715.  CODEN: PADTE5  ISSN: 1042-7147. 

Determination of plateau moduli and entanglement molecular weights of polypropylenes of
different tacticity.   
Friedrich, Chr.; Eckstein, A.; Suhm, J.; Maier, R.-D.; Sassmannshausen, J.; Bochmann, M.; Mulhaupt,
R..    Editor(s): Emri, I.    Progress and Trends in Rheology V, Proceedings of the European Rheology
Conference, 5th, Portoroz, Slovenia, Sept. 6-11, 1998  (1998),     387.  Publisher: Steinkopff, 
Darmstadt, Germany  CODEN: 66TJA2  Conference  written in English.  

[148] Modification of epoxy resin with alpha,omega-oligo(butyl methacrylate)diols.    
Schroder, N.; Konczol, L.; Doll, W.; Mulhaupt, R..    Journal of Applied Polymer Science  (1998), 
70(4),  785-796.  CODEN: JAPNAB  ISSN: 0021-8995.  Journal  written in English.   

Comparison of isotactic and syndiotactic polypropylene as matrix materials of hybrid
composites.    
Stricker, F.; Mulhaupt, R..    Polymer Engineering and Science  (1998),  38(9),  1463-1470. 

[147]Two-Component Gelators and Nucleating Agents for Polypropylene Based upon
Supramolecular Assembly.    
Bauer, Thorsten; Thomann, Ralf; Muelhaupt, Rolf.   Macromolecules  (1998),  31(22),  7651-7658. 

PAT41
Low shrinking polymerizable dental material.    
Klee, Joachim E.; Walz, Uwe; Holter, Dirk; Burgath, Armin; Frey, Holger; Mulhaupt, Rolf.  (Dentsply
International Inc., USA).    PCT Int. Appl.  (1998),     20 pp.  WO  9836729  A2  19980827  DePriority:
US  97-38812  19970221; US  97-960955  19971030.  CAN 129:221217    A

[146] Hyperbranched carbosilane oxazoline-macromonomers. Polymerization and coupling to a
trimesic acid core.    
Lach, Christian; Hanselmann, Holger; Muelhaupt, Rolf.    Macromolecular Rapid Communications 
(1998),  19(9),  461-465.  CODEN: MRCOE3  ISSN: 1022-1336. 

[145] Ethylene polymerization catalysts based on nickel(II) 1,4-diazadiene complexes: the
influence of the 1,4-diazadiene backbone substituents on structure and reactivity.    
Schleis, Thomas; Spaniol, Thomas P.; Okuda, Jun; Heinemann, Johannes; Mulhaupt, Rolf.  
Germany.    Journal of Organometallic Chemistry  (1998),  569(1-2),  159-167.

[144] Influence of morphology on rheological and mechanical properties of SEBS-toughened,
glass-bead-filled isotactic polypropene.    
Stricker, F.; Friedrich, C.; Mulhaupt, R..    Journal of Applied Polymer Science  (1998),  69(12),  2499-
2506. 

Micromechanical deformation processes in PA12-layered silicate nanocomposite.    
Kim, G.-M.; Michler, G. H.; Reichert, P.; Kressler, J.; Mulhaupt, R..    Polymeric Materials Science and
Engineering  (1998),  79  178-179. 

Synthesis and characterization of oxazoline-terminated polymers via controlled radical
polymerization as intermediates for reactive processing.    
Baumert, Martin; Zimmermann, Jorg; Mulhaupt, Rolf.    Polymeric Materials Science and Engineering 
(1998),  79  5-6.

[143] Ambient-temperature liquid-crystalline bismethacrylates based on cholesterol.
Cholesteric and smectic thermosets.   
 Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.    Advanced Materials  (1998),  10(11), 
864-868. 

Synthesis, characterization and film formation of fluorine-containing polyacrylate dispersions
and their blends.    
Linemann, R.; Malner, T.; Brandsch, R.; Bar, G.; Mulhaupt, R..    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (1998),  39(2),  966-967.  CODEN: ACPPAY  ISSN:
0032-3934.  Journal  written in English.    CAN 129:261198   

Film formation study of fluorine-containing dispersions by atomic-force microscopy.    
Linemann, R.; Malner, T.; Brandsch, R.; Bar, G.; Mulhaupt, R..     Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (1998),  39(2),  952-953.  C

Film formation study of fluorine-containing dispersions by atomic-force and environmental
scanning electron microscopy.   
Brandsch, R.; Linemann, R.; Malner, T.; Bar, G.; Muelhaupt, R..   Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     POLY-512.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.   

Synthesis, characterization and film formation of fluorine-containing polyacrylate dispersions
and their blends.    
Bar, G.; Linemann, R.; Malner, T.; Brandsch, R.; Muelhaupt, R..    Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     POLY-466.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.    AN
1998:528177   

Micromechanical deformation processes in PA 12-layered silicate nanocomposite.    
Kim, G. -M.; Michler, G. H.; Reichert, P.; Kressler, J.; Muelhaupt, R..    Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     PMSE-092.  Publisher: American Chemical
Society,  Washington, D. C  C

Synthesis and characterization of oxazoline-terminated polymers via controlled radical
polymerization as intermediates for reactive processing.    
Baumert, Martin; Zimmermann, Joerg; Muelhaupt, Rolf.    Book of Abstracts, 216th ACS National
Meeting, Boston, August 23-27  (1998),     PMSE-003.  Publisher: American Chemical Society, 
Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.    AN
1998:526944  

Nanostructure formation via supramolecular assembly of tectonics in a polymer matrix.    
Bauer, Thorsten; Muelhaupt, Rolf.    Book of Abstracts, 216th ACS National Meeting, Boston, August
23-27  (1998),     MACR-042.  Publisher: American Chemical Society,  Washington, D. C 

Polyurethane nanocomposites prepared from novel silsesquioxane polyols.    
Dietsche, Frank; Muelhaupt, Rolf.    Book of Abstracts, 216th ACS National Meeting, Boston, August
23-27  (1998),     MACR-041.  Publisher: American Chemical Society,  Washington, D. C  CODEN:
66KYA2  Conference; Meeting Abstract  written in English.   

Nonionic silsesquioxane based amphiphiles.    
Knischka, Ralf; Dietsche, Frank; Muelhaupt, Rolf; Frey, Holger.      Book of Abstracts, 216th ACS
National Meeting, Boston, August 23-27  (1998),     COLL-123.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 66KYA2  Conference; Meeting Abstract  written in English.    A

[142] Investigation of Morphologies of One- and Two-Phase Blends of Isotactic Poly(propene)
with Random Poly(ethene-co-1-butene).    
Thomann, Y.; Suhm, J.; Thomann, R.; Bar, G.; Maier, R.-D.; Muelhaupt, R..   Macromolecules  (1998), 
31(16),  5441-5449.  CODEN: MAMOBX  ISSN: 0024-9297.

[141] Comparison of N,N'-bidentate ligands in copper-catalyzed atom-transfer polymerization of
styrene.    
DiRenzo, Geraldine M.; Messerschmidt, Martin; Muelhaupt, Rolf.    Macromolecular Rapid
Communications  (1998),  19(7),  381-384.

[140] Propene polymerization with rac-Me2Si(2-methylbenz[e]ind)2ZrX2 [X = Cl, Me] using
different cation-generating reagents.    
Beck, Stefan; Brintzinger, H. H.; Suhm, Juergen; Muelhaupt, Rolf.    Macromolecular Rapid
Communications  (1998),  19(5),  235-239. 

[139] Synthesis and properties of polyaramides and poly(amide-imide)s containing 5,10-
dihydrophenazine units.    
Mikulla, Markus; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1998),  199(5),  795-
805. 

PAT40
Preparation of membrane-electrode units for polymer electrolyte fuel cells.    
Ledjeff-Hey, Konstantin; Nolte, Roland; Zerfass, Torsten; Frey, Holger; Muelhaupt, Rolf.  (Fraunhofer-
Gesellschaft zur Foerderung der angewandten Forschung e.V., Germany).    Ger. Offen.  (1998),     14
pp.  DE  19653484  A1  19980625  Application: DE  96-19653484  19961220.  CAN 129:97744   


[138] Fracture behavior of polypropylene/glass bead elastomer composites by using the
essential work-of-fracture method.    
Mouzakis, D. E.; Stricker, F.; Mulhaupt, R.; Karger-Kocsis, J.    Journal of Materials Science  (1998), 
33(10),  2551-2562. 

[137] Rubber-toughened cycloolefin copolymers.    
Stricker, Florian; Muelhaupt, Rolf.   Angewandte Makromolekulare Chemie  (1998),  256  101-104. 

[136] The influence of metallocene-based LLDPE on polypropene compounds in the presence
of SEBS and talcum.    
Stricker, Florian; Maier, Ralph-Dieter; Muelhaupt, Rolf.    Angewandte Makromolekulare Chemie 
(1998),  256  95-99. 

[135] Influence of rubber particle size on mechanical properties of polypropylene-SEBS blends.
Stricker, F.; Thomann, Y.; Mulhaupt, R..    Journal of Applied Polymer Science  (1998),  68(12),  1891-
1901. 

m-PP blends. Processing and properties of blends based on m-PP and ethylene copolymers.    
Stricker, Florian; Maier, Ralph Dieter; Thomann, Yi; Muelhaupt, Rolf.    Kunststoffe  (1998),  88(4), 
527-530.

Novel polyolefin materials via catalysis and reactive processing.    
Suhm, Juergen; Heinemann, Johannes; Woerner, Christof; Mueller, Philipp; Stricker, Florian; Kressler,
Joerg; Okuda, Jun; Muelhaupt, Rolf.    Macromolecular Symposia  (1998),  129(Modified Polyolefins
for Advanced Polymeric Materials),  1-28. 

[134] Influence of metallocene structures on ethene copolymerization with 1-butene and 1-
octene.
Suhm, J.; Schneider, M. J.; Mulhaupt, R..    Journal of Molecular Catalysis A: Chemical  (1998), 
128(1-3),  215-227. 

[133] New molecular and supermolecular polymer architectures via transition metal catalyzed
alkene polymerization.    
Suhm, Jurgen; Heinemann, Johannes; Thomann, Yi; Thomann, Ralf; Maier, Ralph-dieter; Schleis,
Thomas; Okuda, Jun; Kressler, Jorg; Mulhaupt, Rolf.    Journal of Materials Chemistry  (1998),  8(3), 
553-563.  C

[132] Crystallization of syndiotactic poly(propene-co-octene).    
Thomann, Ralf; Kressler, Jorg; Mulhaupt, R..      Polymer  (1998),  39(10),  1907-1915.  C

[131] Vapor-induced crystallization of syndiotactic random copolymers of styrene with 4-n-
butylstyrene.    
Thomann, Ralf; Thomann, Yi; Sernetz, Friedrich G.; Muelhaupt, Rolf; Kressler, Joerg.    Polymer
Bulletin (Berlin)  (1998),  40(2-3),  313-319. 

[130] Nanocomposites based on a synthetic layer silicate and polyamide-12.    
Reichert, P.; Kressler, J.; Thomann, R.; Muelhaupt, R.; Stoeppelmann, G.    Acta Polymerica  (1998), 
49(2-3),  116-123. 

[129] Micromechanical deformation processes in toughened PP/PA/SEBS-g-MA blends
prepared by reactive processing.    
Kim, G. M.; Michler, G. H.; Roesch, J.; Muelhaupt, R..    IActa Polymerica  (1998),  49(2-3),  88-95. 
CODEN: ACPODY  I

[128] Microstructure and pressure-volume-temperature properties of ethene/1-octene random
copolymers.    
Suhm, J.; Maier, R. D.; Kressler, J.; Muelhaupt, R..    Acta Polymerica  (1998),  49(2-3),  80-87. 

Oxazoline compounds for thermoplastic polymers stabilized against heat, oxidation, and light.    
Steinmann, Alfred; Mulhaupt, Rolf.  (Ciba Specialty Chemicals Holding Inc., Switz.).    Eur. Pat. Appl. 
(1998),     52 pp.  EP  816346  A1  19980107  Application: EP  97-810391  19970619.  Priority: CH 
96-1631  19960628.  CAN 128:128745    AN 1998:116089   

[127] Determination of Plateau Moduli and Entanglement Molecular Weights of Isotactic,
Syndiotactic, and Atactic Polypropylenes Synthesized with Metallocene Catalysts.    
Eckstein, A.; Suhm, J.; Friedrich, C.; Maier, R.-D.; Sassmannshausen, J.; Bochmann, M.; Muelhaupt,
R..    Macromolecules  (1998),  31(4),  1335-1340. 

[126] Studies on reactions of oxazoline functionalized polymer particles.    
Schafer, Rudiger; Holderle, Matthias; Mulhaupt, Rolf.    Polymer  (1998),  39(6-7),  1259-1268. 
CODEN: POLMAG  ISSN: 0032-3861.  Journal  written in English.    C

[125] 1,3-Oxazoline intermediates in reactive processing applications: 3. Bis (1,3-oxazolin-2-yl)-
terminated oligotetrahydrofuran liquid rubbers and preparation of the corresponding
segmented copolyether ester amides.    
Worner, Christof; Muller, Philipp; Mulhaupt, Rolf.    I   Polymer  (1998),  39(3),  611-620.  CODEN:

[124] Synthesis of two maleimide derivatives of cis-configurated platinum(II) complexes for the
preparation of chemoimmunoconjugates.    
Schutte, Mark Thomas; Schumacher, Peter; Unger, Clemens; Mulhaupt, Rolf; Kratz, Felix.       
Inorganica Chimica Acta  (1998),  267(1),  133-136. 

1997


[123]Synthesis and Crystallization of Syndiotactic Random Copolymers of Styrene and p-n-
Butylstyrene and of Syndiotactic Poly(p-n-butylstyrene).    
Thomann, Ralf; Sernetz, Friedrich G.; Heinemann, Johannes; Steinmann, Sandra; Muelhaupt, Rolf;
Kressler, Joerg.    Macromolecules  (1997),  30(26),  8401-8409. 

[122] Fuzzy set approach for fitting a continuous response surface in adhesion formulation.    
Setz, Stefan; Semling, Marcus; Mulhaupt, Rolf.    Journal of Chemometrics  (1997),  11(5),  403-418. 

[121] Carbosilane Dendrimers with Perfluoroalkyl End Groups. Core-Shell Macromolecules with
Generation-Dependent Order.    
Lorenz, Klaus; Frey, Holger; Stuehn, Bernd; Muelhaupt, Rolf.    Macromolecules  (1997),  30(22), 
6860-6868. 

[120] Toughened poly(butylene terephthalate)s and blends prepared by simultaneous chain
extension, interfacial coupling, and dynamic vulcanization using oxazoline intermediates.    
Worner, Christof; Muller, Philipp; Mulhaupt, Rolf.    Journal of Applied Polymer Science  (1997),  66(4), 
633-642.  CODEN:

[119] Mechanical and thermal properties of syndiotactic polypropene filled with glass beads
and talcum.    
Stricker, F.; Bruch, M.; Mulhaupt, R..    Polymer  (1997),  38(21),  5347-5353.  CODEN: POLMAG 
ISSN: 0032-3861. 

[118] Carboxy-terminated homo- and copolymers of styrene using dicarboxylic acid-functional
azo initiator and 2,2,6,6-tetramethyl-1-piperidyloxyl (TEMPO).    
Baumert, Martin; Mulhaupt, Rolf. Macromolecular Rapid Communications  (1997),  18(9),  787-794. 

[117] Synthesis of fluorine-containing dispersions and an environmental scanning electron
microscope analysis of their morphology when applied to cotton fabrics.    
Linemann, Reinhard; Gorenberg, Arkadii; Bar, Georg; Cantow, Hans-Joachim; Mulhaupt, Rolf.   
Journal of Coatings Technology  (1997),  69(871),  77-81. 

[116] Nine-Membered Titanacyclic Complexes Based on an Ethylene-Bridged Bis(phenolato)
Ligand: Synthesis, Structure, and Olefin Polymerization Activity.    
Fokken, Stefan; Spaniol, Thomas P.; Okuda, Jun; Sernetz, Fritz G.; Muelhaupt, Rolf.   
Organometallics  (1997),  16(20),  4240-4242. 

PAT39
Manufacture of polymers containing oxazine groups.    
Weber, Martin; Muelhaupt, Rolf; Kressler, Joerg; Mueller, Philipp; Schaefer, Ruediger.  (BASF A.-G.,
Germany).    Eur. Pat. Appl.  (1997),     9 pp.  EP  791606  A2  19970827  CAN 127:221177  

PAT38
Alkylalkoxysilyl-1,3-oxazolines, and their use.    
Muenzenberg, Joerg; Muelhaupt, Rolf; Mueller, Philipp.  (Degussa Aktiengesellschaft, Germany).   
Eur. Pat. Appl.  (1997),     13 pp.  EP  791598  A2  19970827  Designated States R: BE, DE, FR, GB,
IT.  Patent  written in German.    Application: EP  97-102559  19970218.  Priority: DE  96-19606413 
19960221.  CAN 127:251949   

Progress in controlled polymerization and design of novel polymer architectures.    
Baumert, Martin; Frey, Holger; Holderle, Matthias; Kressler, Jorg; Sernetz, Friedrich G.; Mulhaupt,
Rolf.   Macromolecular Symposia  (1997),  121  53-74.

Hyperbranched polyallyisilanes bearing oxazoline groups as versatile building blocks for new
polymer architectures.    
Lach, Christian; Frey, Holger; Mulhaupt, Rolf.    Polymeric Materials Science and Engineering  (1997), 
77  199.  CODEN: PMSEDG  ISSN: 0743-0515.  Journal  written in English.    CAN 127:234651   

Branched bismethacrylates based on bis-GMA - a systematic route to low shrinkage
composites.    
Holter, Dirk; Frey, Holger; Mulhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division
of Polymer Chemistry)  (1997),  38(2),  84-85. 

[115] Metallocene-catalyzed ethene/styrene co- and terpolymerization with olefinic
termonomers.     Sernetz, Friedrich G.; Mulhaupt, Rolf.   Journal of Polymer Science, Part A: Polymer
Chemistry  (1997),  35(13),  2549-2560.

[114] Synthesis and characterization of oxazoline-functional polymer particles by free radical
nonaqueous dispersion polymerization.    
Holderle, Matthias; Bar, Georg; Mulhaupt, Rolf.    Journal of Polymer Science, Part A: Polymer
Chemistry  (1997),  35(13),  2539-2548. 

[113] Polyester networks based upon epoxidized and maleated natural oils.    
Warth, Holger; Mulhaupt, Rolf; Hoffmann, Botho; Lawson, Sonya.   Angewandte Makromolekulare
Chemie  (1997),  249  79-92.  CODEN: ANMCBO  ISSN: 0003-3146. 

[112] Gas transport properties of soluble poly(phenylene sulfone imides).    
Xu, Z.-K.; Bohning, M.; Springer, J.; Glatz, F. P.; Mulhaupt, R..    Journal of Polymer Science, Part B:
Polymer Physics  (1997),  35(12),  1855-1868.  C

Branched bismethacrylates based on Bis-GMA - a systematic route to low shrinkage
composites.    
Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.    Book of Abstracts, 214th ACS
National Meeting, Las Vegas, NV, September 7-11  (1997),     POLY-009.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 64RNAO  Conference; Meeting Abstract  written in
English.    AN 1997:489151   

Hyperbranched polyallylsilanes bearing oxazoline groups as versatile building blocks for new
polymer architectures.    
Lach, Christian; Frey, Holger; Muelhaupt, Rolf.    Book of Abstracts, 214th ACS National Meeting, Las
Vegas, NV, September 7-11  (1997),     PMSE-224.  Publisher: American Chemical Society, 
Washington, D.

[111] Morphology and phase behavior of poly(methyl methacrylate)/poly(styrene-co-
acrylonitrile) blends monitored by FTIR microscopy.    
Schafer, Rudiger; Zimmermann, Jorg; Kressler, Jorg; Mulhaupt, Rolf.    Inst. Makromol. Chem.
Frieburger Materialforschungszentrum, Polymer  (1997),  38(15),  3745-3752.  CAN 127:82048   

[110] The interfacial reaction of modified poly(arylether sulfone)s and polyaramides.    
Mader, Dietmar; Coen, Martine Collaud; Kressler, Jorg; Mulhaupt, Rolf; Weber, Martin.   Journal of
Applied Polymer Science  (1997),  65(3),  567-579. 

[109] Viscoelastic properties of poly(ethylene-co-styrene) copolymers.    
Lobbrecht, A.; Friedrich, Chr.; Sernetz, F. G.; Mulhaupt, R..    Journal of Applied Polymer Science 
(1997),  65(2),  209-215. 

[108] Thermal Properties of the Homologous Series of 8-fold Alkyl-Substituted
Octasilsesquioxanes
Bolln, Carsten; Tsuchida, Akira; Frey, Holger; Muelhaupt, Rolf, Chemistry of Materials  (1997),  9(6), 
1475-1479. 

[107] Liquid crystalline acrylates or ?-substituted acrylates, curable dental compositions
containing these compounds, and methods for using these compositions.    
Klee, Joachem E.; Frey, Holger; Holter, Dirk; Mulhaupt, Rolf.  (Dentsply International, Inc., USA).   
PCT Int. Appl.  (1997),     60 pp.  WO  9714674  A1  19970424  Priority: US  95-543950  19951017;
US  96-723443  19961007.  CAN 126:344209  

[106] Aminofunctional linear low density polyethylene via metallocene-catalyzed ethene
copolymerization with N,N-bis(trimethylsilyl)-1-amino-10-undecene.    
Schneider, Martin Julius; Schafer, Rudiger; Mulhaupt, Rolf.    Polymer  (1997),  38(10),  2455-2459. 

PAT37
Preparation of functionalized copoly-m-phenylenes as solid electrolytes.    
Muelhaupt, Rolf; Frey, Holger; Zerfass, Torsten; Ledjeff-Hey, Konstantin; Nolte, Roland.  (Fraunhofer-
Gesellschaft zur Foerderung der Angewandten Forschung e.V., Germany).    Ger. Offen.  (1997),     14
pp.  DE  19535086  A1  19970327  Patent  written in German.    Application: DE  95-19535086 
19950921.  CAN 126:294405   

[105] Influence of Indenyl Ligand Substitution Pattern on Metallocene-Catalyzed Ethene
Copolymerization with 1-Octene.    
Schneider, Martin Julius; Suhm, Juergen; Muelhaupt, Rolf; Prosenc, Marc-Heinrich; Brintzinger, Hans-
Herbert.    Macromolecules  (1997),  30(11),  3164-3168. 

[104] Comparison of controlled radical styrene polymerizations in bulk and nonaqueous
dispersion.
Hoelderle, Matthias; Baumert, Martin; Muelhaupt, Rolf.    Macromolecules  (1997),  30(11),  3420-
3422. 

Trends in polymer chemistry 1996.     Frey, H.; Kressler, J.; Richtering, W.; Mulhaupt, R..   Acta
Polymerica  (1997),  48(4),  107-115.  C

[103] Ethene and Propene Copolymers Containing Silsesquioxane Side Groups.    
Tsuchida, Akira; Bolln, Carsten; Sernetz, Friedrich G.; Frey, Holger; Muelhaupt, Rolf.   
Macromolecules  (1997),  30(10),  2818-2824. 

[102] Copolymerization of ethene with styrene using different methylalumoxane activated half-
sandwich complexes.    
Sernetz, Friedrich G.; Mulhaupt, Rolf; Amor, Francisco; Eberle, Thomas; Okuda, Jun.   Journal of
Polymer Science, Part A: Polymer Chemistry  (1997),  35(8),  1571-1578. 

[101] The influence of stereoregularity on the miscibility of poly(propylene)s.    
Maier, Ralph-Dieter; Thomann, Ralf; Kressler, Jorg; Mulhaupt, Rolf; Rudolf, Bernd.    Journal of
Polymer Science, Part B: Polymer Physics  (1997),  35(7),  1135-1144. 

[100] Single crystals of syndiotactic poly[propene-co-(1-octene)] and syndiotactic polypropene
crystallized in bulk.    
Thomann, Ralf; Kressler, Jorg; Mulhaupt, Rolf.    Macromolecular Chemistry and Physics  (1997), 
198(4),  1271-1279. 

[99] Influence of indenyl ligand substitution pattern on metallocene-catalyzed propene
copolymerization with 1-octene.    
Schneider, Martin Julius; Mulhaupt, Rolf.    Macromolecular Chemistry and Physics  (1997),  198(4), 
1121-1129. 

Organosilicon 1,3-oxazolines: reactive silicone liquid rubbers and silane coupling agents
tailored for reactive processing application and nanocomposite formation.    
Mueller, Philipp; Woerner, Christof; Schaefer, Ruediger; Muelhaupt, Rolf.   Polymeric Materials
Science and Engineering  (1997),  76  51-52. 

Polymer nanoparticles with new architectures prepared via non-aqueous dispersion
copolymerization of oxazoline-functional methacrylates.    
Holderle, Matthias; Bruch, Matthias; Schaefer, Ruediger; Muelhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1997),  38(1),  479-480. 

[98] Gas transport properties of poly (phenylene thioether imide)s.    
Xu, Z.-K.; Boehning, M.; Schultze, J. D.; Li, G.-T.; Springer, J.; Glatz, F. P.; Muelhaupt, R..   Polymer 
(1997),  38(7),  1573-1580.  C

[97] Thermoplastic cellulose acetate and cellulose acetate compounds prepared by reactive
processing.    
Warth, Holger; Mulhaupt, Rolf; Schatzle, Joachim.    Journal of Applied Polymer Science  (1997), 
64(2),  231-242.  CODEN:

PAT36
2-Oxazolinyl group-terminated polymers and oligomers for use as compatibilizers.    
Roesch, Joachim; Mueller, Hans-Joachim; Hoehn, Arthur; Muelhaupt, Rolf; Woerner, Christof.  (BASF
A.-G., Germany).    Eur. Pat. Appl.  (1997),     10 pp.   EP  757062  A2  19970205  Application: EP  96-
111813  19960723.  Priority: DE  95-19528192  19950801.  CAN 126:199964   

[96] Hyperbranched polycarbosilane macromonomers bearing oxazoline functionalities.    
Lach, Christian; Muller, Philipp; Frey, Holger; Mulhaupt, Rolf.    Macromolecular Rapid
Communications  (1997),  18(3),  253-260.  C

[95] Temperature rising elution fractionation of a random ethene/styrene copolymer.    
Thomann, Yi; Sernetz, Friedrich G.; Thomann, Ralf; Kressler, Jorg; Mulhaupt, Rolf.    Macromolecular
Chemistry and Physics  (1997),  198(3),  739-748. 

[94]Copolymerization of Ethene with Styrene Using Methylaluminoxane-Activated
Bis(phenolate) Complexes.    
Sernetz, Friedrich G.; Muelhaupt, Rolf; Fokken, Stefan; Okuda, Jun.    Macromolecules  (1997),  30(6), 
1562-1569.

[93] Temperature dependence of copolymerization parameters in ethene/1-octene
copolymerization using homogeneous rac-Me2Si(2-MeBenz[e]Ind)2ZrCl2/MAO catalyst.    
Suhm, J.; Schneider, M. J.; Muelhaupt, R..   Journal of Polymer Science, Part A: Polymer Chemistry 
(1997),  35(4),  735-740.  C

Polymer nanoparticles with new architectures prepared via non-aqueous dispersion
copolymerization of oxazoline-functional methacrylates.    
Hoelderle, Matthias; Bruch, Matthias; Schaefer, Ruediger; Muelhaupt, Rolf.    Book of Abstracts, 213th
ACS National Meeting, San Francisco, April 13-17  (1997),     POLY-206.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 64AOAA  Conference; Meeting Abstract  written in
English.    AN 1997:164131   

Organosilicon 1,3-oxazolines: Reactive silicone liquid rubbers and silane coupling agents
tailored for reactive processing application and nanocomposite formation.    
Mueller, P.; Woerner, C.; Schaefer, R.; Muelhaupt, R..    Book of Abstracts, 213th ACS National
Meeting, San Francisco, April 13-17  (1997),     PMSE-031.  Publisher: American Chemical Society, 
Washington, D.

[92] Comparison of the viscoelastic properties of syndio- and isotactic polypropylenes.    
Eckstein, A.; Friedrich, C.; Lobbrecht, A.; Spitz, R.; Muelhaupt, R..   Acta Polymerica  (1997),  48(1/2), 
41-46.  CODEN: ACPODY  ISSN: 0323-7648. 

[91] Gas transport properties of highly fluorinated polyamideimides.    
Xu, Z.-K.; Boehning, M.; Springer, J.; Steinhauser, N.; Muelhaupt, R..    Polymer  (1997),  38(3),  581-
588.  CODEN:

[90] Homo-, co-, and terpolymerization of 1,5-hexadiene using a methyl aluminoxane-activated
mono-Cp-amido-complex.    
Sernetz, F. G.; Muelhaupt, R.; Waymouth, R. M.    Polymer Bulletin (Berlin)  (1997),  38(2),  141-148. 

[89] Propene homo- and copolymerization using homogeneous and supported metallocene
catalysts based on Me2Si(2-Me-Benz[e]Ind)2ZrCl2.    
Juengling, Stephan; Koltzenburg, Sebastian; Muelhaupt, Rolf.   Journal of Polymer Science, Part A:
Polymer Chemistry  (1997),  35(1),  1-8. 

1996


Starch and dextrins in emulsion copolymerization.    
Boediger, M.; Demharter, S.; Muelhaupt, R..    Freiburger Materialforschungszentrum und Institut fur
Makromolekulare,  Chemie der Albert-Ludwigs Universitat,  Freiburg i.Br.,  Germany.  Editor(s): Van
Bekkum, Herman; Roeper, Harald; Voragen, Fons.    Carbohydrates as Organic Raw Materials III,
developed from a Workshop, Wageningen, Nov. 28-29, 1994  (1996),  Meeting Date 1994,     141-154. 
Publisher: VCH,  Weinheim, Germany 

PAT35
Functionalized polymers, block copolymers, graft copolymers of norbornene-type polycyclic
monomers and polymer blends and alloys containing them.    
Rhodes, Larry F.; Goodall, Brian L.; Mulhaupt, Rolf; Shick, Robert A.; Benedikt, George M.;
Jayaraman, Sai Kumar; Soby, Lynn M.; Mc Intosh, Lester H., III.  (B.F. Goodrich Company, USA).   
PCT Int. Appl.  (1996),     90 pp.  WO  9637528  A1  19961128  Application: WO  96-US6521 
19960520.  Priority: US  95-450648  19950525.  CAN 126:118327   

Controlled architectures and property synergisms of polypropene/polyamide 6 blends
prepared via reactive processing.    
Roesch, Joachim; Muelhaupt, Rolf; Michler, G. H.    Macromolecular Symposia  (1996),  112(Fifth
European Symposium on Polymer Blends, 1996),  141-150.  C

Toughened polypropylene-polyamide 6 blends prepared by reactive blending.    
Roesch, J.; Muelhaupt, R..    Advances in Chemistry Series  (1996),  252(Toughened Plastics II),  291-
302.

Compatibilized, segmented liquid rubbers as epoxy-toughening agents.   
 Muelhaupt, R.; Buchholz, U.    Advances in Chemistry Series  (1996),  252(Toughened Plastics II), 
75-94.   

[88] Influence of thermoplastic elastomers on mechanical properties and morphologies of
isotactic polypropene/glass bead hybrid composites.    
Stricker, F.; Muelhaupt, R..    Journal of Applied Polymer Science  (1996),  62(11),  1799-1806.  C

[87] On the gamma-phase of isotactic polypropylene.    
Thomann, Ralf; Wang, Chun; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecules  (1996),  29(26), 
8425-8434. 

[86] Mono- and Multilayers of Mesogen-Substituted Carbosilane Dendrimers on Mica.    
Coen, Martine Collaud; Lorenz, Klaus; Kressler, Joerg; Frey, Holger; Muelhaupt, Rolf.  
Macromolecules  (1996),  29(25),  8069-8076.

[85] Novel materials through stereocomplexation.    
Brizzolara, Davide; Cantow, Hans Joachim; Muelhaupt, Rolf; Domb, Abraham J.   Journal of
Computer-Aided Materials Design  (1996),  3(1-3, Modeling of Industrial Materials),  341-350. 

Silicon-based thermoset resins.    
Muelhaupt, R..    Editor(s): Kricheldorf, Hans R.    Silicon in Polymer Synthesis  (1996),     458-468. 
Publisher: Springer,  Berlin, Germany  C

[84] Liquid Crystalline Thermosets Based on Branched Bismethacrylates.    
Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.; Macromolecules  (1996),  29(22), 
7003-7011. 

Engineering of new supermolecular structures defined by the chain architectures of
polypropylenes and their blends.    
Kressler, Joerg; Thomann, Ralf; Muelhaupt, Rolf.    Annual Technical Conference - Society of Plastics
Engineers  (1996),  54th(Vol. 2),  2289-2293.

[83] Morphology and phase behavior of blends of syndiotactic and isotactic polypropylene: 2.
Differential scanning calorimetry, light transmission measurements, and PVT measurements.    
Thomann, Ralf; Kressler, Joerg; Rudolf, Bernd; Muelhaupt, Rolf.    Polymer  (1996),  37(13),  2635-
2640.

[82]  Morphology and phase behavior of blends of syndiotactic and isotactic polypropylene: 1.
X-ray scattering, light microscopy, atomic force microscopy, and scanning electron
microscopy.
Thomann, Ralf; Kressler, Joerg; Setz, Stefan; Wang, Chun; Muelhaupt, Rolf.    Polymer  (1996), 
37(13),  2627-2634.

Innovation for plastics through metallocene catalysis.     Muelhaupt, Rolf.    Gummi, Fasern,
Kunststoffe  (1996),  49(5),  394-403. 

[81] Utilization of renewable resources. Possibilities and limits.    
Muelhaupt, R..    Chimia  (1996),  50(5),  191-198. 

[80] A mesogen-functionalized carbosilane dendrimer. A dendritic liquid crystalline polymer.
Lorenz, Klaus; Hoelter, Dirk; Stuehn, Bernd; Muelhaupt, Rolf; Frey, Holger.   Advanced Materials
(Weinheim, Germany)  (1996),  8(5),  414-16. 

[79] Comparison of thermal and microwave-activated polymerization of epsilon-caprolactone
with titanium tetrabutylate as catalyst.    
Albert, Philipp; Warth, Holger; Muelhaupt, Rolf; Janda, Ralf.    Macromolecular Chemistry and Physics 
(1996),  197(5),  1633-1641. 

PAT34
Manufacture of oligomers and polymers of aminoalkenes.    
Fischer, David; Langhauser, Franz; Kerth, Juergen; Schweier, Guenther; Muelhaupt, Rolf; Schneider,
Martin.  (BASF A.-G., Germany).    Ger. Offen.  (1996),     10 pp.  CODEN: GWXXBX  DE  4433481 
A1  19960321  Patent  written in German.    Application: DE  94-4433481  19940920.  CAN
124:290597  

Mesogen-functionalized carbosilane dendrimers-dendritic liquid crystalline polymers.    
Frey, Holger; Lorenz, Klaus; Hoelter, Dirk; Muelhaupt, Rolf.   Polymer Preprints (American Chemical
Society, Division of Polymer Chemistry)  (1996),  37(1),  758-9. 

Branched LC bismethacrylates.     Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf.    Polymer Preprints
(American Chemical Society, Division of Polymer Chemistry)  (1996),  37(1),  756-7.  CODEN:
ACPPAY  ISSN: 0032-3934.  Journal  written in English.   

Controlled polypropylene crystallization via metallocene-catalyzed propene polymerization and
stereoisomer blend formation.    
Thomann, R.; Kressler, J.; Fischer, D.; Juengling, S.; Muelhaupt, R..    Polymer Preprints (American
Chemical Society, Division of Polymer Chemistry)  (1996),  37(1),  269-70.

FTIR spectroscopic studies on the interfacial reactions of oxazoline-functionalized polymers.    
Schaefer, R.; Kressler, J.; Muelhaupt, R..    Acta Polymerica  (1996),  47(4),  170-6. 

[78] Trends in polymer chemistry 1995.    
Frey, H.; Kressler, J.; Richtering, W.; Muelhaupt, R..    Acta Polymerica  (1996),  47(4),  131-40. 

Interpenetrating networks containing dispersed silicone micro- and nanophases.    
Buchholz, U.; Muelhaupt, R..    IPolymeric Materials Science and Engineering  (1996),  74  339-40. 
CODEN: PMSEDG  ISSN: 0743-0515.

Mesogen-functionalized carbosilane dendrimers - dendritic liquid crystalline polymers.    
Frey, Holger; Lorenz, Klaus; Hoelter, Dirk; Muelhaupt, Rolf.   Book of Abstracts, 211th ACS National
Meeting, New Orleans, LA, March 24-28  (1996),     POLY-280.  Publisher: American Chemical
Society,  Washington, D. C  CODEN: 62PIAJ  Conference; Meeting Abstract  written in English.    AN
1996:222015    CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 


Branched LC bismethacrylates.    
Hoelter, Dirk; Frey, Holger; Muelhaupt, Rolf; Klee, Joachim E.    Book of Abstracts, 211th ACS
National Meeting, New Orleans, LA, March 24-28  (1996),     POLY-279.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 62PIAJ  Conference; Meeting Abstract  written in
English.    AN 1996:222014    CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 


Controlled polypropene crystallization via metallocene-catalyzed propene polymerization and
stereoisomer blend formation.    
Juengling, S.; Fischer, D.; Thomann, R.; Kressler, J.; Muelhaupt, Rolf.   Book of Abstracts, 211th ACS
National Meeting, New Orleans, LA, March 24-28  (1996),     POLY-278.  Publisher: American
Chemical Society,  Washington, D. C  CODEN: 62PIAJ  Conference; Meeting Abstract  written in
English.    AN 1996:222013    CAPLUS   (Copyright 2005 ACS on SciFinder (R)) 

Interpentrating networks containing dispersed silicone micro- and nanophases.    
Buchholz, U.; Muelhaupt, R..    Book of Abstracts, 211th ACS National Meeting, New Orleans, LA,
March 24-28  (1996),     PMSE-201.  Publisher: American Chemical Society,  Washington, D. C 
CODEN: 62PIAJ  Conference; Meeting Abstract  written in English.   

[78] Compatibilized polypropylene hybrid composites: influence of elastomeric interlayers on
mechanical properties and nucleation behavior.    
Stricker, Florian; Muelhaupt, Rolf.   High Performance Polymers  (1996),  8(1),  97-108. 

[77] Syntheses of mono(1,3-oxazolin-2-yl)-terminated oligopropene macromonomers and novel
polymers containing oligopropene side chains.    
Woerner, Christof; Roesch, Joachim; Hoehn, Arthur; Muelhaupt, Rolf.    Polymer Bulletin (Berlin) 
(1996),  36(3),  303-9. 

[76] Synthesis and Photoinitiated Cationic Polymerization of 2-Methylene-7-phenyl-1,4,6,9-
tetraoxaspiro[4.4]nonane.    
Bolln, Carsten; Frey, Holger; Muelhaupt, Rolf.    Macromolecules  (1996),  29(9),  3111-16.  CODEN:
MAMOBX  ISSN: 0024-9297.  J

[75] Negative pressure effects during the isothermal crystallization of isotactic poly(propylene)
studied by light and atomic force microscopy.    
Thomann, Ralf; Wang, Chun; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecular Chemistry and
Physics  (1996),  197(3),  1085-91. 

[74] Influence of polymerization conditions on the copolymerization of styrene with ethylene
using Me2Si(Me4Cp)(N-tert-butyl)TiCl2/methylaluminoxane Ziegler-Natta catalysts.    
Sernetz, Friedrich G.; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1996),  197(3), 
1071-83. 

[73] Characterization of supra-molecular assemblies of N-(n-alkyl)-N'-D-maltosylsemicarbazone
adsorbates by atomic force microscopy.    
Craemer, K.; Demharter, S.; Muelhaupt, R.; Frey, H.; Magonov, S. N.; Tuzov, I.; Whangbo, M.-H.   
New Journal of Chemistry  (1996),  20(1),  5-11. 

[72] Transition metal catalysts for the polymerization of olefins. Part 2. Preparation of
stereoregular poly(1-olefins).    
Muelhaupt, Rolf; Rieger, Bernhard.    Chimia  (1996),  50(1-2),  10-19. 

Modification of catheter materials by coating with polymer layers containing silver.   
Coen, Martine Collaud; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecular Symposia  (1996), 
103(Polymers and Medicine),  109-17.  CODEN: MSYMEC  ISSN: 1022-1360. 

[71] Miscibility of Poly(sila-?-methylstyrene) with Polystyrene.    
Maier, Ralph-Dieter; Kressler, Joerg; Rudolf, Bernd; Reichart, Peter; Koopmann, Florian; Frey, Holger;
Muelhaupt, Rolf.    Macromolecules  (1996),  29(5),  1490-7.  C

Dendritic polyols based on carbosilanes - lipophilic dendrimers with hydrophilic skin.    
Frey, Holger; Lorenz, Klaus; Muelhaupt, Rolf.   Macromolecular Symposia  (1996),  102(9th Rolduc
Polymer Meeting, Smart Polymer Materials & Products, 1995),  19-26.  CODEN: MSYMEC  ISSN:
1022-1360.  Journal  written in English.    CAN 124:147038  

[70] Morphology and mechanical properties of blends of isotactic or syndiotactic
polypropylene with SEBS block copolymers.   
Setz, Stefan; Sticker, Florian; Kressler, Joerg; Duschek, Thomas; Muelhaupt, Rolf.    Journal of
Applied Polymer Science  (1996),  59(7),  1117-28.

[69] Modification of isotactic poly(propylene) by oxygen and helium plasma with reference to
thermo-oxidative stability.    
Bauer, Michael; Rembold, Manfred; Marti, Erwin; Schneider, Hans Adam; Muelhaupt, Rolf.   
Macromolecular Chemistry and Physics  (1996),  197(1),  61-82. 

1995


New high-performance polymers obtained from bis-acenaphthyls.    
Rusanov, A.L.; Mulhaupt, R..    A.N. Nesmeyanov Institute of Organo-Element Compounds, Russian
Academy of Sciences,  Moscow,  Russia.    Polymer Yearbook  (1995),  12  3-52. 

Preparation of functionalized materials by reactive extrusion.    
Roesch, Joachim; Warth, Holger; Stricker, Florian; Woerner, Christof; Muelhaupt, Rolf.    Germany.   
Aufbereiten von Polymeren mit Neuartigen Eigenschaften  (1995),     81-96.  Publisher: VDI-Verlag, 
Duesseldorf,

[68] Transition metal catalysts for olefin polymerization. Part 1. Low pressure manufacture of
polyethene.    
Muelhaupt, Rolf; Rieger, Bernhard.    Chimia  (1995),  49(12),  486-91.  Bibliographic Information

The influence of structural parameters on the glass temperature and compatibility of
poly(phenylene ether ketone)s.    
Schneider, H. A.; Glatz, F.; Muelhaupt, R..   New Polymeric Materials  (1995),  4(4),  289-99.  CCAN
124:118829    AN 1996:12579   

LC-dendrimers based on carbosilanarborols.    
Frey, Holger; Muelhaupt, Rolf; Lorenz, Klaus; Rapp, Uwe; Mayer-Posner, Franz J.    Polymeric
Materials Science and Engineering  (1995),  73  127-8. 

PAT33
In-situ encapsulation of fillers by polyesters in thermoplastic resins.    
Muelhaupt, Rolf; Roesch, Joachim; Barghoorn, Peter; Hopperdietzel, Siegfried; Poersch, Franz;
Weingber, Ekkehard; Klein, Herbert.  (Rehau A.-G. & Co., Germany).    Eur. Pat. Appl.  (1995),     9
pp.  EP  669368  A1  19950830  Application: EP  95-101526  19950204.  Priority: DE  94-4405745 
19940223.  CAN 123:342124   

LC-dendrimers based on carbosilanarborols.    
Frey, Holger; Muelhaupt, Rolf; Lorenz, Klaus; Rapp, Uwe; Mayer-Posner, Franz J.   Book of Abstracts,
210th ACS National Meeting, Chicago, IL, August 20-24  (1995),   (Pt. 2),  PMSE-066.  Publisher:
American Chemical Society,  Washington, D. C  CODEN: 61XGAC  Conference; Meeting Abstract 
written in English.  

Multiphase polypropenes prepared by reactive blending.    
Muelhaupt, Rolf; Stricker, Florian; Barghoorn, Peter; Roesch, Joachim.    Macromolecular Symposia 
(1995),  100(5th European Polymer Federation Symposium on Polymeric Materials, 1994),  149-54. 

[67] Morphology of syndiotactic polypropylene.   
Thomann, Ralf; Wang, Chun; Kressler, Joerg; Juengling, Stephan; Muelhaupt, Rolf.   Polymer  (1995), 
36(20),  3795-801. 

Dynamic fracture behavior of epoxy systems blended with block copolymers based on
polyetheresters.    
Hoefflin, F.; Boehme, W.; Muelhaupt, R..   ESIS Publication  (1995),  19(Impact and Dynamic Fracture
of Polymers and Composites),  181-90. 

The role of dormant sites in propene polymerization using methylaluminoxane activated
metallocene catalysts.    
Juergling, Stephen; Muelhaupt, Rolf; Stehling, Udo; Brintzinger, Hans-Herbert; Fischer, David;
Langhauser, Franz.    Macromolecular Symposia  (1995),  97  205-16. 

[66] Synthesis and gel formation of amphiphilic semicarbazones containing saccharide units.    
Demharter, S.; Frey, H.; Drechsler, M.; Muelhaupt, R..    Colloid and Polymer Science  (1995),  273(7), 
661-74. .    CAN 124:59894

[65] Modified syndiotactic polypropene. Propene-octene copolymers and blends with atactic
oligopropene.    
Juengling, Stephan; Muelhaupt, Rolf; Fischer, David; Langhauser, Franz.   Angewandte
Makromolekulare Chemie  (1995),  229  93-112. 

[64] Carbosilane-Based Dendritic Polyols.   
Lorenz, Klaus; Muelhaupt, Rolf; Frey, Holger; Rapp, Uwe; Mayer-Posner, Franz J.    Macromolecules 
(1995),  28(19),  6657-61. 

[63] Reaction calorimetric investigation of 1-olefin homo-and copolymerization using
homogeneous metallocene catalysts.    
Schneider, Martin J.; Muelhaupt, Rolf.      Journal of Molecular Catalysis A: Chemical  (1995),  101(1), 
11-16.

PAT33
Dihydrophenazine polymers.    
Kreuder, Willi; Muelhaupt, Rolf; Mikulla, Markus.  (Hoechst A.-G., Germany).    Ger. Offen.  (1995),    
19 pp.  DE  4325591  A1  19950202  Application: DE  93-4325591  19930730.  CAN 123:84343   

[62] The influence of methylalumoxane concentration on propene polymerization with
homogeneous metallocene-based Ziegler-Natta catalysts.    
Juengling, Stephan; Muelhaupt, Rolf.    Journal of Organometallic Chemistry  (1995),  497(1-2),  27-
32.

[61] Emulsion polymerization of styrene in the presence of carbohydrate-based amphiphiles.
[Erratum to document cited in CA123:33768].    
Demharter, Susanne; Richtering, Walter; Muelhaupt, Rolf.    Polymer Bulletin (Berlin)  (1995),  34(5/6), 
691-8.  CODEN: POBUDR  ISSN: 0170-0839.  Journal  written in English.   

[60] Formation of colloidal PMMA particles via free radical and group transfer dispersion
polymerization of methyl methacrylate and methyl methacrylate/ethylene glycol dimethacrylate.    
Hoelderle, M.; Muelhaupt, R..    Acta Polymerica  (1995),  46(3),  226-32. 

[59] Stereospecific olefin polymerization with chiral metallocene catalysts.    
Brintzinger, Hans H.; Fischer, David; Muelhaupt, Rolf; Rieger, Bernhard; Waymouth, Robert M.   
Angewandte Chemie, International Edition in English  (1995),  34(11),  1143-70. 

[58] FTIR Spectroscopy and Microscopy on the Interfacial Reaction and Interdiffusion of
Styrene/Maleic Anhydride and Bis(amine)-Terminated Poly(tetrahydrofuran).   
Schaefer, Ruediger; Kressler, Joerg; Neuber, Rolf; Muelhaupt, Rolf.    Macromolecules  (1995), 
28(14),  5037-42.  CODEN: MAMOBX  ISSN: 0024-9297.  J

Novel polyolefin materials and processes: Overview and prospects.    
Muelhaupt, Rolf.    Editor(s): Fink, Gerhard; Muelhaupt, Rolf; Brintzinger, Hans H.    Ziegler Catal. 
(1995),     35-55.  Publisher: Springer,  Berlin, Germany 

[57] 1,3-Oxazoline intermediates in reactive processing applications. 2. Multiphase polymer
blends via in-situ cationic melt phase polymerization of 2-phenyl-1,3-oxazoline.    
Mueller, Philipp; Woerner, Christof; Muelhaupt, Rolf.   Macromolecular Chemistry and Physics  (1995), 
196(6),  1929-36. 

[56] 1,3-Oxazoline intermediates in reactive processing applications. 1. Melt grafting of
poly(ethene-co-methacrylic acid) with 2-substituted 1,3-oxazolines.    
Mueller, Philipp; Werner, Christof; Muelhaupt, Rolf.    Macromolecular Chemistry and Physics  (1995), 
196(6),  1917-28.  C

[55] Deformation behavior of polypropylene/polyamide blends.    
Roesch, Joachim; Muelhaupt, Rolf.     Journal of Applied Polymer Science  (1995),  56(12),  1607-13. 

[54] Mechanical and morphological properties of elastomer-modified polypropylene/polyamide-
6 blends.     Roesch, Joachim; Muelhaupt, Rolf.   Journal of Applied Polymer Science  (1995),  56(12), 
1599-605.  CODEN: JAPNAB  ISSN: 0021-8995. 

Ziegler Catalysts: Recent Scientific Innovations and Technological Improvements.    
Fink, Gerhard; Muelhaupt, Rolf; Brintzinger, Hans H.; Editors.    Germany.    (1995),     511 pp. 
Publisher: (Springer,  Berlin, Germany)  Book 

[53] Propene polymerization using homogeneous MAO-activated metallocene catalysts:
Me2Si(benz[e]indenyl)2ZrCl2/MAO vs. Me2Si(2-Me-benz[e]indenyl)2ZrCl2/MAO.    
Juengling, Stephan; Muelhaupt, Rolf; Stehling, Udo; Brintzinger, Hans Herbert; Fischer, David;
Langhauser, Franz.   Journal of Polymer Science, Part A: Polymer Chemistry  (1995),  33(8),  1305-
17. 

[52] Interpenetrating polymer networks derived from epoxide-amine adducts in neither polymer
network.    
Klee, Joachim E.; Leube, Walter; Muelhaupt, Rolf.    Angewandte Makromolekulare Chemie  (1995), 
226  173-82. 

[51] Thermal polymerization and reactive blending of 2-(4-hydroxyphenyl)-1,3-oxazoline.   
 Woerner, C.; Mueller, P.; Muelhaupt, R..    Polymer Bulletin (Berlin)  (1995),  34(3),  301-8. 

[50] Anhydride-cured epoxy resins toughened with diol- and bis(4-hydroxybenzoate)-
terminated poly(tetrahydrofuran) liquid rubbers. Part II. Phase separation.    
Laeuger, J.; Albert, P.; Kressler, J.; Gronski, W.; Muelhaupt, R..    Acta Polymerica  (1995),  46(1),  74-
8.  C

[49] Anhydride-cured epoxy resins toughened with diol- and bis(4-hydroxybenzoate)-
terminated poly(tetrahydrofuran) liquid rubbers. Part I. Morphology and blend properties.    
Albert, P.; Laeuger, J.; Kressler, J.; Muelhaupt, R..    Acta Polymerica  (1995),  46(1),  68-73. 

[48] Transcrystallinity of thin films of isotactic polypropylene.    
Setz, Stefan; Schnell, Rupert; Thomann, Ralf; Kressler, Joerg; Muelhaupt, Rolf.    Macromolecular
Rapid Communications  (1995),  16(1),  81-7.  C

[47] Fullerene-End-Capped Polystyrenes. Monosubstituted Polymeric C60 Derivatives.    
Weis, Christine; Friedrich, Christian; Muelhaupt, Rolf; Frey, Holger.    Macromolecules  (1995),  28(1), 
403-5. 

1994


PAT32
Aqueous polymer dispersions for preparation of water vapor-permeable coatings on textiles.    
Moebus, Helmut; Bister, Erhard; Muelhaupt, Rolf.  (Rotta GmbH, Germany).    Ger. Offen.  (1994),     7
pp.  DE  4315269  A1  19941110  Application: DE  93-4315269  19930507.  CAN 122:292753 

Phase compatibilizers for polypropylene-polyamide 6 blends.    
Muelhaupt, R.; Roesch, J.    Freiburg/Br.,  Germany.    Kunststoffe  (1994),  84(9),  1153, 1155-6

[46] Progress in synthesis and application of segmented polymers.    
Muelhaupt, Rolf; Buchholz, Udo; Roesch, Joachim; Steinhauser, Norbert.    Angewandte
Makromolekulare Chemie  (1994),  223  47-60.  CODEN: ANMCBO  ISSN: 0003-3146. 

[45] Use of polystyrene-block-poly(ethylene oxide) as emulsifier in emulsion polymerization.    
Berger, Markus; Richtering, Walter; Muelhaupt, Rolf.   Polymer Bulletin (Berlin)  (1994),  33(5),  521-8. 

PAT31
Plasticized cellulose acetate, its manufacture, and its use in manufacturing filaments.    
Muelhaupt, Rolf; Schaetzle, Joachim; Warth, Holger.  (Rhone-Poulenc Rhodia AG, Germany).    Ger. 
(1994),     9 pp.  DE  4325352  C1  19940901  Patent  written in German.    Application: DE  93-
4325352  19930728.  CAN 122:136516   

[44] Preparation and properties of soluble polyamide imides containing
oligo(tetrafluoroethene) segments and application in gas separation.    
Steinhauser, Norbert; Muelhaupt, Rolf; Hohmann, Marcus; Springer, Juergen.    Polymers for
Advanced Technologies  (1994),  5(8),  438-43. 

[43] Preparation and properties of polyaramides derived from aromatic diamine-terminated
oligo(tetrafluoroethene)s.    
Steinhauser, N.; Muelhaupt, R..    High Performance Polymers  (1994),  6(2),  133-47. 

[42] Anisotropic dispersion polymerization of N-(4-aminobenzoyl)-caprolactam in polymer
melts.     Muelhaupt, Rolf; Roesch, Joachim.    Polymers for Advanced Technologies  (1994),  5(5), 
282-6. 

[41] Ultimate properties of epoxy resins modified with a polysiloxane-polycaprolactone block
copolymer.    
Konczol, L.; Doll, W.; Buchholz, U.; Mulhaupt, R..    Journal of Applied Polymer Science  (1994), 
54(6),  815-26.

[40] Synthesis of N-acylated derivatives of 5,10-dihydrophenazine.   
Mikulla, Markus; Muelhaupt, Rolf.   Chemische Berichte  (1994),  127(9),  1723-8. 

[39] The role of compatibilizers and elastomeric interlayers in glass-bead-reinforced
poly(propylene).    
Roesch, Joachim; Barghoorn, Peter; Muelhaupt, Rolf.   Macromolecular Rapid Communications 
(1994),  15(9),  691-6. 

[38] Preparation and properties of copolyamides-6,6F and copolyamides-4,8F containing
oligo(tetrafluoroethylene) segments.    
Steinhauser, Norbert; Muelhaupt, Rolf.   Macromolecular Chemistry and Physics  (1994),  195(9), 
3199-211.  C

[37] The role of core/shell-microparticle dispersions in polypropylene/polyamide-6 blends.    
Roesch, Joachim; Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (1994),  32(5-6),  697-704. 

[36] Living dispersion polymerization of styrene in the presence of polystyrene-block-poly(4-
trimethylsilylstyrene).    
Schneider, Michael; Muelhaupt, Rolf.     Polymer Bulletin (Berlin, Germany)  (1994),  32(5-6),  545-50. 

[35] Scanning force microscopy of oriented iso- and syndiotactic polypropylene films.    
Craemer, K.; Schneider, M.; Muelhaupt, R.; Cantow, H.-J.; Magonov, S. N.    Polymer Bulletin (Berlin,
Germany)  (1994),  32(5-6),  637-44. 

[34] Mechanical properties of organosolv-lignin-filled thermoplastics.     Roesch, Joachim;
Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (1994),  32(3),  361-5.  C

[33] Preparation and cure behavior of dimethacrylates containing oligo(tetrafluoroethene)
segments.    
Steinhauser, Norbert; Muelhaupt, Rolf.   Polymer Bulletin (Berlin, Germany)  (1994),  32(4),  403-10. 

[32] Influence of flexible oligo(tetrafluoroethene) segments on the glass temperature of
poly(aramide)s and poly(amide imide)s.    
Schneider, H. A.; Steinhauser, N.; Muelhaupt, R..    Polymer Bulletin (Berlin, Germany)  (1994),  32(3), 
339-46. 

[31] Gas permeabilities and permselectivities of amorphous segmented 6F poly(arylene
thioether imide)s and the corresponding poly(arylene sulfone imide)s.   
Glatz, F. P.; Muelhaupt, R.; Schultze, J. D.; Springer, J.    Journal of Membrane Science  (1994), 
90(1-2),  151-9.

[30] Preparation, cure behavior and properties of bis(2-oxazoline)s containing well-defined
oligo(tetrafluoroethylene) segments.     Steinhauser, Norbert; Muelhaupt, Rolf.    Macromolecular
Rapid Communications  (1994),  15(4),  365-72.

[29] The influence of regio- and stereoirregularities on the crystallization behavior of isotactic
poly(propylene)s prepared with homogeneous group IVa metallocene/methylaluminoxane
Ziegler-Natta catalysts.    
Fischer, David; Muelhaupt, Rolf.    Inst. Makromol. Chem.,  Macromolecular Chemistry and Physics 
(1994),  195(4),  1433-41. 

[28] ansa-Zirconocene Polymerization Catalysts with Anelated Ring Ligands - Effects on
Catalytic Activity and Polymer Chain Length.    
Stehling, Udo; Diebold, Josef; Kirsten, Robin; Roell, Werner; Brintzinger, Hans Herbert; Juengling,
Stephan; Muelhaupt, Rolf; Langhauser, Franz.    Organometallics  (1994),  13(3),  964-70.  CODEN:
ORGND7  ISSN: 0276-7333. 

1993


[27] Reactive blending of polypropylene/polyamide-6 in the presence of tailor-made succinic
anhydride-terminated oligo-propene compatibilizers.    
Muelhaupt, Rolf; Duschek, Thomas; Roesch, Joachim.    Polymers for Advanced Technologies 
(1993),  4(7),  465-74.

[26] Novel polypropene materials derived from vinylidene-terminated oligopropenes.    
Muelhaupt, Rolf; Duschek, Thomas; Fischer, David; Setz, Stefan.    Polymers for Advanced
Technologies  (1993),  4(7), 

Organic microcomposites via reactive processing.    
Muelhaupt, R.; Roesch, J.; Demharter, S.    Journal de Physique IV:  Proceedings  (1993),  3(C7, 3RD
EUROPEAN CONFERENCE ON ADVANCED MATERIALS AND PROCESSES, 1993, VOL. 2), 
1519-24.  CODEN: JPICEI  ISSN: 1155-4339. 

Reinforcement of polyurethane by in-situ particle precipitation.    
Krenceski, Mary. A.; Cantow, H. -J.; Mulhaupt, R..     Polymeric Materials Science and Engineering 
(1993),  70  356-7. 

Toughened polypropylene/polyamide blends prepared by reactive blending.    
Roesch, Joachim; Muelhaupt, Rolf.    Polymeric Materials Science and Engineering  (1993),  70  193. 

Compatibilized liquid rubbers as epoxy toughening agents.    
Muelhaupt, Rolf; Buchholz, Udo.   Polymeric Materials Science and Engineering  (1993),  70  4. 

Donor- and acceptor-modified metallocene-based homogeneous Ziegler-Natta catalysts.    
Fischer, David; Juengling, Stephan; Muelhaupt, Rolf.   Macromolecular Symposia  (1993), 
66(Advances in Olefin, Cycloolefin and Diolefin Polymerization),  191-202. 

[25] Semi-interpenetrating networks of sulfur-containing bismaleimides.    
Glatz, F. P.; Muelhaupt, R..   High Performance Polymers  (1993),  5(4),  297-305. 

[24] Syntheses and blend behavior of poly(phenylene thioether ether ketones) (PTEKs) and
poly(phenylene sulfone ether ketones) (PSEKs).   
Glatz, F P.; Muelhaupt, R..    High Performance Polymers  (1993),  5(3),  219-28. 

[23] Preparation, cure behavior and properties of bismaleimides containing well defined
oligo(phenylene sulfide) segments.    
Glatz, F P.; Muelhaupt, R..    High Performance Polymers  (1993),  5(3),  213-18.

New building blocks for melt adhesives.    
Muelhaupt, Rolf; Setz, Stefan; Elster, Clemens; Honerkamp, Josef.    Adhaesion--Kleben & Dichten 
(1993),  37(11),  26, 28-30.  CAN 121:59031    AN 1994:459031    C

[22] Cooperative effects in binuclear zirconocenes: their synthesis and use as catalyst in
propene polymerization.    
Juengling, Stephan; Muelhaupt, Rolf; Plenio, Herbert.    Journal of Organometallic Chemistry  (1993), 
460(2),  191-5.  CODEN: JORCAI  ISSN: 0022-328X. 

PAT30
Catalyst system for polymerization of C2-10 olefins.    
Langhauser, Franz; Lux, Martin; Muelhaupt, Rolf; Fischer, David.  (BASF A.-G., Germany).    Ger.
Offen.  (1993),     10 pp.  DE  4203753  A1  19930812  Application: DE  92-4203753  19920210.  CAN
120:165219    AN 1994:165219   

Modified polysulfones as membrane electrolytes.    
Nolte, R.; Ledjeff, K.; Bauer, M.; Muelhaupt, R., BHR Group Conference Series Publication  (1993), 
3(Effective Membrane Processes--New Perspectives),  381-5. 

[21] Syntheses and properties of soluble poly(arylene thioether imides) and the corresponding
poly(arylene sulfone imides).    
Glatz, Frank P.; Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany)  (1993),  31(2),  137-43. 

New generations of polyolefin materials.    
Muelhaupt, Rolf.   Nachrichten aus Chemie, Technik und Laboratorium  (1993),  41(12),  1341-6,
1348, 1351. 

PAT29
Elastomeric polymer alloys, their preparation and use.    
Muelhaupt, Rolf; Demharter, Susanne; Hopperdietzel, Siegfried; Weinberg, Ekkehard; Klein, Herbert. 
(Rehau AG und Co., Germany).    Ger.  (1993),     6 pp. DE  4205428  C1  19930527  CAN
120:109275   

[20] Anisotropic polyaramide/polyol dispersions - new components for the preparation of
polyurethane microcomposites.    
Demharter, Susanne; Roesch, Joachim; Muelhaupt, Rolf.    Polymer Bulletin (Berlin, Germany) 
(1993),  31(4),  421-8. 

[19] Polymers from renewable resources: polyester resins and blends based upon anhydride-
cured epoxidized soybean oil.   
Roesch, Joachim; Muelhaupt, Rolf.   Polymer Bulletin (Berlin, Germany)  (1993),  31(6),  679-85. 

[18] Polynitrile- and polyamine-functionalized poly(trimethylenimine) dendrimers.    
Woerner, Christof; Muelhaupt, Rolf.    Angewandte Chemie  (1993),  105(9),  1367-70 (See also
Angew. Chem., Int. Ed. Engl., 1993, 32(9), 1306-8).  C

[17] Partially sulfonated poly(arylene ether sulfone) - a versatile proton conducting membrane
material for modern energy conversion technologies.    
Nolte, R.; Ledjeff, K.; Bauer, M.; Muelhaupt, R..    Journal of Membrane Science  (1993),  83(2),  211-
20. 

[16] Syntheses and thermal properties of aromatic and semi-aromatic poly(thioether amides)
containing oligo(thio-1,4-phenylene) segments.    
Glatz, Frank P.; Muelhaupt, Rolf.    Inst. Makromol. Chem.,  Albert-Ludwigs Univ.,  Freiburg, 
Germany.    Polymer Bulletin (Berlin, Germany)  (1993),  31(2),  129-36. 

PAT28
Blends of olefin polymers and in-situ-prepared polyesters.    
Muelhaupt, Rolf; Roesch, Joachim; Hopperdietzel, Siegfried; Weinberg, Ekkehard; Klein, Herbert. 
(Rehau AG und Co., Germany).    Eur. Pat. Appl.  (1993),     7 pp.  EP  535526  A1  19930407 
Priority: DE  91-4132671  19911001.  CAN 119:251360   

[15] Synthesis of polymer electrolytes with high ion conductivity using experimental design of
multicomponent polymer systems.    
Schneider, Martin J.; Elster, Clemens; Muelhaupt, Rolf; Honerkamp, Josef; Nolte, Roland; Wittwer,
Volker; Ledjeff, Konstantin.    Industrial & Engineering Chemistry Research  (1993),  32(12),  3128-34. 

[14] Comparison of maleic anhydride-grafted polypropylene with maleic anhydride-grafted
polystyrene-block-poly(ethene-co-but-1-ene)-block-polystyrene as blend compatibilizers of
polypropylene/polyamide-6 blends.   
Roesch, Joachim; Muelhaupt, Rolf.    Makromolekulare Chemie, Rapid Communications  (1993), 
14(8),  503-9. 

1992


Syntheses and gas permeabilities of soluble polyimides containing well-defined
oligo(phenylene)(sulfide) and oligo(phenylenesulfone) segments.    
Muelhaupt, R.; Glatz, F. P.; Schultz, J. D.; Springer, J.    Polymer Preprints (American Chemical
Society, Division of Polymer Chemistry)  (1992),  33(1),  203-4. 

Polyamide microcomposites via in-situ polymerization of activated p-aminobenzoic acid.    
Roesch, Joachim; Muelhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division of
Polymer Chemistry)  (1992),  33(1),  370-1. 

Branched polysiloxane block copolymers as epoxy toughening agents.    
Buchholz, Udo; Muelhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division of Polymer
Chemistry)  (1992),  33(1),  205-6.  CO

Polypropylene block and graft copolymers via vinylidene-terminated propene oligomers.    
Duschek, Thomas; Muelhaupt, Rolf.    Polymer Preprints (American Chemical Society, Division of
Polymer Chemistry)  (1992),  33(1),  170-1. 

PAT27
Polymer alloys prepared in situ and their preparation and use.     Muelhaupt, Rolf; Roesch,
Joachim; Hopperdietzel, Siegfried; Weinberg, Ekkehard; Klein, Herbert.  (Rehau AG und Co.,
Germany).    Eur. Pat. Appl.  (1992),     9 pp.  EP  518062  A1  19921216  Priority: DE  91-4119146 
19910611.  CAN 119:9822 

 

1991


PAT26
Functional polypropylene blend compatibilizers.    
Muelhaupt, Rolf; Duschek, Thomas; Rieger, Bernhard.   Macromolecular Symposia  (1991),  48-
49(Eur. Polym. Fed. Symp. Polym. Mater., 3rd, 1990),  317-32. 

[13] Reversible and irreversible deactivation of propene polymerization using homogeneous
Cp2ZrCl2/methylaluminoxane Ziegler-Natta catalysts.     Fischer, David; Muelhaupt, Rolf.    Freib.
Materialforschungszent.,  Albert-Ludwigs Univ.,  Freiburg/Br.,  Germany.    Journal of Organometallic
Chemistry  (1991),  417(1-2),  C7-C11. 

[12] (Trialkylsiloxy)dialkylaluminum dimers.    
Mulhaupt, Rolf; Calabrese, Joseph; Ittel, Steven D.    Organometallics  (1991),  10(9),  3403-6. 

PAT25
Iminosilanes as coupling agents.    
Parrinello, Giovanni; Muelhaupt, Rolf.  (Ciba-Geigy A.-G., Switz.).    Eur. Pat. Appl.  (1991),     17 pp. 
EP  414640  A2  19910227  Priority: CH  89-3069  19890824.  CAN 115:115736 

PAT24
Couplers for polyurethanes.    
Parrinello, Giovanni; Simon, Hubert; Muelhaupt, Rolf.  (Ciba-Geigy A.-G., Switz.).    Eur. Pat. Appl. 
(1991),     31 pp.  EP  406160  A2  19910102  Priority: CH  89-2203  19890613.  CAN 114:248568   

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